A Monovacant lacunary silicotungstate as an efficient heterogeneous catalyst for dehydration of primary amides to nitriles

ChemCatChem

Volumn 5, Issue 7, 2013, Pages 1725-1728

  Itagaki, Shintaro ^a   Kamata, Keigo ^a   Yamaguchi, Kazuya ^a   Mizuno, Noritaka ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

Dehydration; Heterogeneous catalysis; Nitriles; Polyoxometalate; Primary amides

Indexed keywords

EID: 84879716835     PISSN: 18673880     EISSN: 18673899     Source Type: Journal    
DOI: 10.1002/cctc.201300063     Document Type: Article

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61. +, respectively (FigureS6). Therefore, it is likely that I possesses (at least) one labile aqua ligand at the vacant site and that the aqua ligand was exchangeable with acetonitrile.
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68. 3 protons) and 11.75ppm (NH proton) with the formation of acetonitrile (FigureS7).