Benzene hydrogenation over highly active monodisperse Ru/γ-Al 2O3 nanocatalyst synthesized by (w/o) reverse microemulsion

Reaction Kinetics, Mechanisms and Catalysis

Volumn 108, Issue 2, 2013, Pages 473-489

  Nandanwar, S U ^a   Chakraborty, M ^a   Mukhopadhyay, S ^b   Shenoy, K T ^b  

^a SARDAR VALLABHBHAI NATIONAL INSTITUTE OF TECHNOLOGY   (India)

^b BHABHA ATOMIC RESEARCH CENTRE   (India)

Author keywords

Al2O 3; Hydrogenation of benzene; Microemulsion technique; Nanocatalyst; Ru nanoparticles

Indexed keywords

HYDROGEN CHEMISORPTION; HYDROGENATION OF BENZENE; HYDROGENATION REACTIONS; MICROEMULSION TECHNIQUE; NANO-CATALYST; REVERSE MICROEMULSION METHOD; RU NANOPARTICLES; RUTHENIUM NANOPARTICLES;

ACTIVATION ENERGY; ALUMINA; ALUMINUM; BENZENE; CATALYST POISONING; CYCLOHEXANE; HYDROGENATION; METAL NANOPARTICLES; MICROEMULSIONS; RUTHENIUM; SYNTHESIS (CHEMICAL); THERMOGRAVIMETRIC ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

CATALYST ACTIVITY;

EID: 84879688315     PISSN: 18785190     EISSN: 18785204     Source Type: Journal    
DOI: 10.1007/s11144-012-0526-1     Document Type: Article

References (34)

1. 2 catalysts performance for partial hydrogenation of benzene. Appl Surf Sci 254:6849-6853
2. Halligudi SB, Bajaj HC, Bhatt KN, Krishnaratnam M (1992) Hydrogenation of benzene to cyclohexane catalyzed by rhodium(I) complex supported on montmorillonite clay. React Kinet Catal Lett 48:547-552
3. 2 catalysts on the hydrogenation of benzene activity. Pol J Environ Stud 18:965-969
4. 3 catalysts prepared by conventional and sol-gel techniques. Appl Catal B 79:199-207
5. Chou P, Vannice MA (1987) Benzene hydrogenation over supported and unsupported palladium. J Catal 107:129-139
6. Lewandowska A, Monteverdi S, Bettahar M, Ziolek M (2002) MCM-41 mesoporous molecular sieves supported nickel - physico-chemical properties and catalytic activity in hydrogenation of benzene. J Mol Catal A Chem 188:85-95
7. 2-supported nickel catalysts synthesized by γ-radiolysis. Catal Today 113:157-165
8. 2-delta (x = 0.01, 0.02). Catal Lett 88:73-81
9. Zhang AM, Dong JL, Xu QH, Rhee HK, Li XL (2004) Palladium cluster filled in inner of carbon nanotubes and their catalytic properties in liquid phase benzene hydrogenation. Catal Today 93-95:347-352
10. Wojcieszak R, Zielinski M, Monteverdi S, Bettahar MM (2006) Study of nickel nanoparticles supported on activated carbon prepared by aqueous hydrazine reduction. J Colloid Interface Sci 299:238-248
11. 3 catalysts. Reac Kinet Mech Cat 107:127-139
12. Arun V, Sridevi N, Robinson PP, Manju S, Yusuff KKM (2009) Ni(II) and Ru(II) Schiff base complexes as catalysts for the reduction of benzene. J Mol Catal A Chem 304:191-198
13. Lu F, Liu J, Xu J (2008) Synthesis of chain-like Ru nanoparticle arrays and its catalytic activity for hydrogenation of phenol in aqueous media. Mater Chem Phys 108:369-374
14. Nowicki A, Zhang Y, Leger B, Rolland JP, Bricout H, Monflier E, Roucoux A (2006) Supramolecular shuttle and protective agent: a multiple role of methylated cyclodextrins in the chemoselective hydrogenation of benzene derivatives with ruthenium nanoparticles. Chem Commun 296-298. doi: 10.1039/b512838b
15. Ning JB, Xu J, Liu J, Lu F (2006) Selective hydrogenation of benzene to cyclohexane over colloidal ruthenium catalyst stabilized by silica. Catal Lett 109:175-180
16. Paulus UA, Endruschat U, Feldmeyer GJ, Schmidt TJ, Bonnemann H, Behm RJ (2000) New PtRu alloy colloids as precursors for fuel cell catalysts. J Catal 195:383-393
17. Liu MH, Yu WY, Liu HF, Zheng JM (1999) Preparation and characterization of polymer-stabilized ruthenium-platinum and ruthenium-palladium bimetallic colloids and their catalytic properties for hydrogenation of o-chloronitrobenzene. J Colloid Interface Sci 214:231-237
18. Yan S, Qu P, Wang H, Tian T, Xiao Z (2008) Synthesis of Ru/multiwalled carbon nanotubes by microemulsion for electrochemical supercapacitor. Mater Res Bull 43:2818-2824
19. Yang J, Lee JY, Deivaraj TC, Too HP (2004) Preparation and characterization of positively charged ruthenium nanoparticles. J Colloid Interface Sci 271:308-312
20. Nowicki A, Boulaire VL, Roucoux A (2007) Nanoheterogeneous catalytic hydrogenation of arenes: evaluation of the surfactant-stabilized aqueous ruthenium (0) colloidal suspension. Adv Synth Catal 349:2326-2330
21. Motoyama Y, Takasaki M, Higashi K, Yoon SH, Mochida I, Nagashima H (2006) Highly-dispersed and size-controlled ruthenium nanoparticles on carbon nanofibers: preparation, characterization, and catalysis. Chem Lett 35:876-877
22. Debouttiere PJ, Martinez V, Philippot K, Chaudret B (2009) An organometallic approach for the synthesis of water-soluble ruthenium and platinum nanoparticles. Dalton Trans 46:10172-10174
23. Nandanwar SU, Chakraborty M, Mukhopadhyay S, Shenoy KT (2011) Stability of ruthenium nanoparticles synthesized by solvothermal method. Cryst Res Technol 46:393-399
24. Yan X, Liu H, Liew KY (2001) Size control of polymer-stabilized ruthenium nanoparticles by polyol reduction. J Mater Chem 11:3387-3391
25. 3. Mater Res Bull 43:3111-3121
26. He Y, Vinodgopal K, Muthupandian A, Grieser F (2006) Sonochemical synthesis of ruthenium nanoparticles. Res Chem Intermed 32:709-715
27. Kim T, Kobayashi K, Nagai M (2007) Preparation and characterization of platinum-ruthenium bimetallic nanoparticles using reverse microemulsions for fuel cell catalyst. J Oleo Sci 56:553-562
28. Nandanwar SU, Chakraborty M, Murthy ZVP (2011) Formation of ruthenium nanoparticles by the mixing of two reactive microemulsions. Ind Eng Chem Res 50:11445-11451
29. Xiong L, Manthiram A (2005) Catalytic activity of Pt-Ru alloys synthesized by a microemulsion method in direct methanol fuel cells. Solid State Ion 176:385-392
30. Paul BK, Nandy D (2007) Dilution method study on the interfacial composition, thermodynamic properties and structural parameters of w/o microemulsions stabilized by 1-pentanol and surfactants in absence and presence of sodium chloride. J Colloid Interface Sci 316:751-761
31. Charinpanitkul T, Chanagul A, Dutta J, Rungsardthong U, Tanthapanichakoon W (2005) Effects of cosurfactant on ZnS nanoparticle synthesis in microemulsion. Sci Technol Adv Mater 6:266-271
32. Boricha AB, Mody HM, Bajaj HC, Jasra RV (2006) Hydrogenation of benzene over ruthenium-exchanged montmorillonite in the presence of thiophene. Appl Clay Sci 31:120-125
33. 2+ ions in aqueous hydrazine II. Support effect. J Colloid Interface Sci 332:416-424
34. Struijk J, Angremond MD, Lucas-de Regt WJM, Scholten JJF (1992) Partial liquid phase hydrogenation of benzene to cyclohexane over ruthenium catalysts in the presence of an aqueous salt solution: I. Preparation, characterization of the catalyst and study of a number of process variables. Appl Catal A 83:263-295