Formation of ruthenium nanoparticles by the mixing of two reactive microemulsions

Industrial and Engineering Chemistry Research

Volumn 50, Issue 19, 2011, Pages 11445-11451

  Nandanwar, Sachin U ^a   Chakraborty, Mousumi ^a   Murthy, Z V P ^a  

^a SARDAR VALLABHBHAI NATIONAL INSTITUTE OF TECHNOLOGY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

INTERMICELLAR EXCHANGE; MOLAR RATIO; NUCLEATION AND GROWTH; OVERALL REACTIONS; PARTICLE AGGLOMERATIONS; PRECURSOR CONCENTRATION; R VALUE; RUTHENIUM CHLORIDES; RUTHENIUM NANOPARTICLES; SODIUM BOROHYDRATE; SURFACTANT CONCENTRATIONS;

CHLORINE COMPOUNDS; METAL NANOPARTICLES; MICROEMULSIONS; REACTION RATES; RUTHENIUM; SODIUM; SURFACE ACTIVE AGENTS; TRANSMISSION ELECTRON MICROSCOPY;

SYNTHESIS (CHEMICAL);

EID: 84860130235     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie201043v     Document Type: Article

References (28)

1. Xiong, L.; Manthiram, A. Catalytic activity of Pt-Ru alloys synthesized by a microemulsion method in direct methanol fuel cells. Solid State Ionics 2005, 176, 385.
2. Rojas, S.; Garcia-Garcia, F. J.; Jaras, S.; Martinez-Huerta, M. V.; Garcia Fierro, J. L.; Boutonnet, M. Preparation of carbon supported Pt and PtRu nanoparticles from microemulsion electrocatalysts for fuel cell applications. Appl. Catal., A 2005, 285, 24.
3. Rabelo de Moraes, I.; Jose da Silva, W.; Tronto, S.; Rosolen, J. M. Carbon fibers with cup-stacked-type structure: An advantageous support for Pt-Ru catalyst in methanol oxidation. J. Power Sources 2006, 160, 997.
4. Yan, S.; Qu, P.; Wang, H.; Tian, T.; Xiao, Z. Synthesis of Ru/ multiwalled carbon nanotubes by microemulsion for electrochemical supercapacitor. Mater. Res. Bull. 2008, 43, 2818.
5. Bonet, F.; Delmas, V.; Grugeon, S.; Herrera Urbina, R.; Silvert, P.-Y.; Tekaia-Elhsissen, K. Synthesis of monodisperse Au, Pt, Pd, Ru and Ir nanoparticles in ethylene glycol. Nanostruct. Mater. 1999, 11, 1277.
6. Yang, J.; Lee, J. Y.; Deivaraj, T. C.; Too, H.-P. Preparation and characterization of positively charged ruthenium nanoparticles. J. Colloid Interface Sci. 2004, 271, 308.
7. Takashi, T.; Hisashi, F. New method for facile synthesis of amphiphilic thiol-stabilized ruthenium nanoparticles and their redoxactive ruthenium nanocomposite. Langmuir 2005, 21, 12093.
8. Denicourt-Nowicki, A.; Ponchel, A.; Monflier, E.; Roucoux, A. Methylated cyclodextrins: An efficient protective agent in water for zerovalent ruthenium nanoparticles and a supramolecular shuttle in alkene and arene hydrogenation reactions. Dalton Trans. 2007, 5714.
9. Nowicki, A.; Le Boulaire, V.; Roucoux, A. Nanoheterogeneous catalytic hydrogenation of arenes: Evaluation of the surfactant-stabilized aqueous ruthenium(0) colloidal suspension. Adv. Synth. Catal. 2007, 349, 2326.
10. Debouttiere, P.-J.; Martinez, V.; Philippot, K.; Chaudret, B. An organometallic approach for the synthesis of water-soluble ruthenium and platinum nanoparticles. Dalton Trans. 2009, 10172.
11. Yan, X.; Liu, H.; Liew, K. Y. Size control of polymer-stabilized ruthenium nanoparticles by polyol reduction. J. Mater. Chem. 2001, 11, 3387.
12. He, Y.; Vinodgopal, K.; Muthupandian, A.; Grieser, F. Sonochemical synthesis of ruthenium nanoparticles. Res. Chem. Intermed. 2006, 32, 709.
13. Motoyama, Y.; Takasaki, M.; Higashi, K.; Yoon, S. H.; Mochida, I.; Nagashima, H. Highly-dispersed and size-controlled ruthenium nanoparticles on carbon nanofibers: Preparation, characterization, and catalysis. Chem. Lett. 2006, 35, 876.
14. Nandanwar, S. U.; Chakraborty, M.; Mukhopadhyay, S.; Shenoy, K. T. Stability of ruthenium nanoparticles synthesized by solvothermal method. Cryst. Res. Technol. 2011, 46, 393.
15. Zhang, Y.; Yu, J.; Niu, H.; Liu, H. Synthesis of PVP-stabilized ruthenium colloids with low boiling point alcohols. J. Colloid Interface Sci. 2007, 313, 503.
16. 3. Mater. Res. Bull. 2008, 43, 3111.
17. Zhang, X.; Chan, K.-Y. Water-in-oil microemulsion synthesis of platinum-ruthenium nanoparticles, their characterization and electrocatalytic properties. Chem. Mater. 2003, 15, 451.
18. Capek, I. Preparation of metal nanoparticles in water-in-oil (w/o) microemulsions. Adv. Colloid Interface Sci. 2004, 110, 49.
19. Stubenrauch, C.; Wielputz, T.; Sottmann, T.; Roychowdhury, C.; DiSalvo, F. J. Microemulsions as templates for the synthesis of metallic nanoparticles. Colloids Surf., A 2008, 317, 328.
20. Ramesh Kumar, A.; Hota, G.; Mehra, A.; Khilar, K. C. Modeling of nanoparticles formation by mixing of two reactive microemulsions. AIChE J. 2004, 50, 1556.
21. Najjar, R.; Stubenrauch, C. Phase diagrams of microemulsions containing reducing agents and metal salts as bases for the synthesis of metallic nanoparticles. J. Colloid Interface Sci. 2009, 331, 214.
22. 2O/AOT/ heptane microemulsion. Mater. Chem. Phys. 2010, 121, 125.
23. Solanki, J. N.; Murthy, Z. V. P. Highly monodisperse and subnano silver particles synthesis via microemulsion technique. Colloids Surf., A 2010, 359, 31.
24. Ethayaraja, M.; Dutta, K.; Muthukumaran, D.; Bandyopadhyaya, R. Nanoparticle formation in water-in-oil microemulsions: Experiments, mechanism, and Monte Carlo simulation. Langmuir 2007, 23, 3418.
25. Natarajan, U.; Handique, K.; Mehra, A.; Bellaer, J. R.; Khiler, K. C. Ultrafine metal particle formation in reverse micellar system: Effect of intermicellar exchange on the formation of particle. Langmuir 1996, 12, 2670.
26. Flores, M. V.; Voutsas, E. C.; Spiliotis, N.; Eccleston, G. M.; Bell, G.; Tassios, G. P.; Halling, P. J. Critical micelle concentration of nonionic surfactants in organic solvents: Approximate prediction with UNIFAC. J. Colloid Interface Sci. 2001, 240, 277.
27. Zhang, W.; Qiao, X.; Chen, J. Synthesis of nanosilver colloidal particles in water/oil microemulsion. Colloids Surf., A 2007, 299, 22.
28. Zhang, W.; Qiao, X.; Chen, J. Synthesis of silver nanoparticles- Effects of concerned parameters in water/oil microemulsion. Mater. Sci. Eng., B 2007, 142, 1.