A unique frustrated Lewis pair pathway to remarkably stable borata-alkene systems

European Journal of Inorganic Chemistry

Volumn , Issue 19, 2013, Pages 3312-3315

  Yu, Jiangang ^a   Kehr, Gerald ^a   Daniliuc, Constantin G ^a   Erker, Gerhard ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Borata alkenes; Boron; Lewis acids; Lewis bases; Phosphorus

Indexed keywords

OLEFINS; PHOSPHORUS; PIERS; X RAY DIFFRACTION;

BORATA-ALKENE; FRUSTRATED LEWIS PAIRS; HYDROBORATION; HYDROBORATION REACTIONS; INTRAMOLECULAR CONJUGATE ADDITION; LEWIS ACID; LEWIS BASE; MINOR PRODUCTS; PHOSPHANES; X- RAY DIFFRACTIONS;

BORON;

EID: 84879427851     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201300520     Document Type: Article

References (42)

1. M. W. Rathke, R. Kow, J. Am. Chem. Soc. 1972, 94, 6854-6856.
2. A. J. Ashe, P. Shu, J. Am. Chem. Soc. 1971, 93, 1804-1805.
3. B. G. Ramsey, L. M. Isabelle, J. Org. Chem. 1981, 46, 179-182.
4. J. C. Sheldon, G. J. Currie, J. H. Bowie, J. Am. Chem. Soc. 1988, 110, 8266-8267.
5. J. Oomens, J. D. Steill, T. H. Morton, Inorg. Chem. 2010, 49, 6781-6783 see also
6. G. Müller, J. Brand, Organometallics 2003, 22, 1463-1467.
7. J. J. Eisch, Adv. Organomet. Chem. 1996, 39, 355-391.
8. P. P. Power, Chem. Rev. 1999, 99, 3463-3504.
9. M. Yamashita, K. Nozaki, Bull. Chem. Soc. Jpn. 2008, 81, 1377-1392.
10. C. Fedorchuk, M. Copsey, T. Chivers, Coord. Chem. Rev. 2007, 251, 897-924 see for a comparison
11. K. Ansorg, H. Braunschweig, C.-W. Chiu, B. Engels, D. Gamon, M. Hügel, T. Kupfer, K. Radacki, Angew. Chem. 2011, 123, 2885-2888;
12. Angew. Chem. Int. Ed. 2011, 50, 2833-2836.
13. G. Zweifel, H. Arzoumanian, Tetrahedron Lett. 1966, 7, 2535-2538.
14. R. Kow, M. W. Rathke, J. Am. Chem. Soc. 1973, 95, 2715-2716.
15. A. Pelter, G. Bugden, R. Rosser, Tetrahedron Lett. 1985, 26, 5097-5100 see for a comparison
16. H. Jäger, G. Hesse, Chem. Ber. 1962, 95, 345-349.
17. A. Haag, G. Hesse, Justus Liebigs Ann. Chem. 1971, 751, 95-108.
18. T. Tomioka, R. Sankranti, T. G. Vaughan, T. Maejima, T. Yanase, J. Org. Chem. 2011, 76, 8053-8058.
19. T. Tomioka, Y. Takahashi, T. Maejima, Org. Biomol. Chem. 2012, 10, 5113-5118.
20. R. A. Bartlett, P. P. Power, Organometallics 1986, 5, 1916-1917.
21. M. M. Olmstead, P. P. Power, K. J. Weese, R. J. Doedens, J. Am. Chem. Soc. 1987, 109, 2541-2542 see for a comparison
22. C.-W. Chiu, F. P. Gabbaï, Angew. Chem. 2007, 119, 7002-7005;
23. Angew. Chem. Int. Ed. 2007, 46, 6878-6881.
24. M. Pilz, J. Allwohn, R. Hunold, W. Massa, A. Berndt, Angew. Chem. 1988, 100, 1421-1422;
25. Angew. Chem. Int. Ed. Engl. 1988, 27, 1370-1372.
26. M. Pilz, J. Allwohn, P. Willershausen, W. Massa, A. Berndt, Angew. Chem. 1990, 102, 1085-1087;
27. Angew. Chem. Int. Ed. Engl. 1990, 29, 1030-1032.
28. See for a comparison:, A. H. Cowley, F. P. Gabbaï, C. J. Carrano, L. M. Mokry, M. R. Bond, G. Bertrand, Angew. Chem. 1994, 106, 584-586;
29. Angew. Chem. Int. Ed. Engl. 1994, 33, 578-580.
30. D. W. Stephan, G. Erker, Angew. Chem. 2010, 122, 50-81;
31. Angew. Chem. Int. Ed. 2010, 49, 46-76.
32. W. E. Piers, T. Chivers, Chem. Soc. Rev. 1997, 26, 345-354.
33. O. Ekkert, G. Kehr, R. Fröhlich, G. Erker, Chem. Commun. 2011, 47, 10482-10484.
34. O. Ekkert, G. Kehr, R. Fröhlich, G. Erker, J. Am. Chem. Soc. 2011, 133, 4610-4616.
35. G. Kehr, G. Erker, Chem. Commun. 2012, 48, 1839-1850.
36. C. Jiang, O. Blacque, H. Berke, Organometallics 2010, 29, 125-133.
37. C. Chen, G. Kehr, R. Fröhlich, G. Erker, J. Am. Chem. Soc. 2010, 132, 13594-13595.
38. C. Chen, T. Voss, R. Fröhlich, G. Kehr, G. Erker, Org. Lett. 2011, 13, 62-65.
39. J. Möbus, Q. Bonnin, K. Ueda, R. Fröhlich, K. Itami, G. Kehr, G. Erker, Angew. Chem. 2012, 124, 1990-1993;
40. Angew. Chem. Int. Ed. 2012, 51, 1954-1957.
41. B. Wrackmeyer, Coord. Chem. Rev. 1995, 145, 125-156.
42. B. Wrackmeyer, Heteroat. Chem. 2006, 17, 188-208.