Kinetic study of solvent effects on the aminolysis of O-ethyl S-aryl dithiocarbonates

Journal of Physical Organic Chemistry

Volumn 25, Issue 11, 2012, Pages 989-993

  Millán, Daniela ^a   Santos, José G ^a   Castro, Enrique A ^a  

^a PONTIFICIA UNIVERSIDAD CATÓLICA DE CHILE   (Chile)

Author keywords

Aminolysis; Dithiocarbonates; Kinetics; Mechanism; Solvent effects

Indexed keywords

AMINOLYSIS; CONCERTED MECHANISM; DIPOLAR APROTIC SOLVENT; DITHIOCARBONATES; NUCLEOPHILIC SUBSTITUTION REACTIONS; SECONDARY ALICYCLIC; SOLVENT EFFECTS; WATER ETHANOL MIXTURES;

ALKALINITY; ENZYME KINETICS; MECHANISMS; ORGANIC SOLVENTS; RATE CONSTANTS; SUBSTITUTION REACTIONS;

SOLVENTS;

EID: 84879230347     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.2988     Document Type: Conference Paper

References (19)

1. C. Reichardt, Solvents and Solvent Effects in Organic Chemistry, 2nd edn., VCH Publishers, Orlando, FL, 1988, 139.
2. S. R. Reddy, P. Manikyamba, J. Chem. Sci. 2007, 119, 613-616.
3. M. H. Abraham, P. L. Grellier, J. Chem. Soc. Perkin Trans. 2 1976, 1735-1741.
4. R. A. McClelland, V. M. Kanagasabapathy, N. S. Banait, S. Steenken, J. Am. Chem. Soc. 1992, 114, 1816-1823.
5. I.-H. Um, H.-W. Yoon, J.-S. Lee, H.-J. Moon, D.-S. Kwon, J. Org. Chem. 1997, 62, 5939-5944.
6. K. K. Ghosh, M. L. Satnami, D. Sinha, J. Vaidya, J. Mol. Liq. 2005, 116, 55-60.
7. E. A. Castro, M. E. Aliaga, M. Cepeda, J. G. Santos, Int. J. Chem. Kinet. 2011, 43, 353-358.
8. E. A. Castro, J. G. Santos, P. R. Campodonico, R. Aguayo, D. Millan, Int. J. Chem. Kinet. 2011, 43, 687-693.
9. E. A. Castro, F. Ibáñez, M. Salas, J. G. Santos, P. Sepúlveda, J. Org. Chem. 1993, 58, 459-463.
10. E. A. Castro, M. Cubillos, G. Muñoz, J. G. Santos, Int. J. Chem. Kinet. 1994, 26, 571-575.
11. I. A. Koppel, V. A. Palm, Advances in linear free energy relationships (Eds: N. V. Chapman, J. Shorter), Plenum Press, New York, 1972, 222.
12. C. Reichardt, Chem. Rev. 1994, 94, 2319-2358.
13. J. Catalán, V. López, P. Pérez, R. Martin-Villamil, J. G. Rodriguez, Liebigs Ann. 1995, 241-252.
14. J. Catalán, C. Díaz, V. López, P. Pérez, J.-L. G. DePaz, J.-G. Rodriguez, Liebigs Ann. 1996, 1785-1794.
15. J. Catalán, C. Díaz, Liebigs Ann. 1997, 1941-1949.
16. A. Williams, E. Chystiuk, J. Am. Chem. Soc. 1987, 109, 3040-3046.
17. A. Williams, J. Am. Chem. Soc. 1989, 22, 387-392.
18. E. A. Castro, G. Muñoz, M. Salas, J. G. Santos, Int. J. Chem. Kinet. 1995, 27, 987-995.
19. E. A. Castro, M. Salas, J. G. Santos, P. Sepúlveda, J. Org. Chem. 1991, 56, 5324-5328.