Gas phase oxidation of monoethanolamine (MEA) with oh radical and ozone: Kinetics, products, and particles

Environmental Science and Technology

Volumn 47, Issue 12, 2013, Pages 6377-6383

  Borduas, Nadine ^a   Abbatt, Jonathan P D ^a   Murphy, Jennifer G ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON CAPTURE AND STORAGE; CHEMICAL IONIZATION MASS SPECTROMETRY; GAS PHASE OXIDATION; HYDROXYL RADICALS; KINETICS OF OXIDATION; OXIDATION PRODUCTS; PROTON-TRANSFER REACTION MASS SPECTROMETRIES; RATE COEFFICIENTS;

CARBON CAPTURE; CARBON DIOXIDE; CHARGE TRANSFER; ENVIRONMENTAL IMPACT; EXPERIMENTS; FREE RADICALS; KINETICS; MASS SPECTROMETRY; OXIDATION; OZONE;

ETHANOLAMINES;

ETHANOLAMINE; FORMAMIDE; HYDROGEN PEROXIDE; HYDROXYL RADICAL; ISOCYANATE; OZONE;

CARBON SEQUESTRATION; COMBUSTION; EXPERIMENTAL STUDY; FREE RADICAL; INDUSTRIAL EMISSION; IONIZATION; OXIDATION; SOLVENT;

ARTICLE; FRAGMENTATION REACTION; INFRARED SPECTROSCOPY; IONIZATION; MASS FRAGMENTOGRAPHY; MASS SPECTROMETRY; OXIDATION; OXIDATION KINETICS; PHOTOLYSIS; PHOTOOXIDATION; POLYMERIZATION; PROTON TRANSPORT; REACTION TIME; ROOM TEMPERATURE; SMOG; ULTRAVIOLET B RADIATION;

ETHANOLAMINE; HYDROXYL RADICAL; KINETICS; MASS SPECTROMETRY; NITROGEN; OZONE;

EID: 84879209214     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es401282j     Document Type: Article

References (40)

1. Lepaumier, H.; da Silva, E. F.; Einbu, A.; Grimstvedt, A.; Knudsen, J. N.; Zahlsen, K.; Svendsen, H. F. Comparison of MEA degradation in pilot-scale with lab-scale experiments Energy Procedia 2011, 4, 1652-1659
2. 2 capture focusing on emissions from amine-based scrubbing solvents to air Environ. Sci. Technol. 2010, 44, 1496-1502
3. 2 with monoethanolamine solvent: Key considerations for solvent management and environmental impacts Environ. Sci. Technol. 2012, 46, 3643-3654
4. 2 capture in post-combustion Energy Procedia 2009, 1, 893-900
5. Puxty, G.; Rowland, R.; Allport, A.; Yang, Q.; Bown, M.; Burns, R.; Maeder, M.; Attalla, M. Carbon dioxide postcombustion capture: A novel screening study of the carbon dioxide absorption performance of 76 amines Environ. Sci. Technol. 2009, 43, 6427-6433
6. 2 Capture-Health and Environmental Impacts; The Bellona Foundation: Oslo, Norway, 2009.
7. 2 capture plant Int. J. Greenhouse Gas Control 2011, 5, 439-447
8. Ge, X.; Wexler, A. S.; Clegg, S. L. Atmospheric amines-Part I. A review Atmos. Environ. 2011, 45, 524-546
9. Karl, M.; Dye, C.; Schmidbauer, N.; Wisthaler, A.; Mikoviny, T.; D'Anna, B.; Müller, M.; Borrás, E.; Clemente, E.; Muñoz, A.; Porras, R.; Ródenas, M.; Vázquez, M.; Brauers, T. Study of OH-initiated degradation of 2-aminoethanol Atmos. Chem. Phys. 2012, 12, 1881-1901
10. Nielsen, C. J.; D'Anna, B.; Dye, C.; George, C.; Graus, M.; Hansel, A.; Karl, M.; King, S.; Musabila, M.; Müller, M.; Schmiedbauer, N.; Stenstrøm, Y.; Wisthaler, A. Atmospheric Degradation of Amines (ADA). Summary Report: Gas Phase Photo-Oxidation of 2-Aminoethanol (MEA), CLIMIT project no. 193438; CLIMIT-Programme for Power Generation with Carbon Capture and Storage, 2010.
11. Nielsen, C. J.; D'Anna, B.; Dye, C.; Graus, M.; Karl, M.; King, S.; Maguto, M. M.; Müller, M.; Schmidbauer, N.; Stenstrøm, Y.; Wisthaler, A.; Pedersen, S. Atmospheric chemistry of 2-aminoethanol (MEA) Energy Procedia 2011, 4, 2245-2252
12. Onel, L.; Blitz, M. A.; Seakins, P. W. Direct determination of the rate coefficient for the reaction of OH radicals with monoethanolamine (MEA) from 296 to 510 K J. Phys. Chem. Lett. 2012, 3, 853-856
13. De Gouw, J.; Warneke, C. Measurements of volatile organic compounds in the earth's atmosphere using proton-transfer-reaction mass spectrometry Mass Spectrom. Rev. 2007, 26, 223-257
14. Bertram, T. H.; Kimmel, J. R.; Crisp, T. A.; Ryder, O. S.; Yatavelli, R. L. N.; Thornton, J. A.; Cubison, M. J.; Gonin, M.; Worsnop, D. R. A field-deployable, chemical ionization time-of-flight mass spectrometer Atmos. Meas. Tech. 2011, 4, 1471-1479
15. Donahue, N. M.; Kroll, J. H.; Anderson, J. G.; Demerjian, K. L. Direct observation of OH production from the ozonolysis of olefins Geophys. Res. Lett. 1998, 25, 59-62
16. Kroll, J. H.; Clarke, J. S.; Donahue, N. M.; Anderson, J. G. Mechanism of HOx formation in the gas-phase ozone-alkene reaction. 1. Direct, pressure-dependent measurements of prompt OH yields J. Phys. Chem. A 2001, 105, 1554-1560
17. Lambe, A. T.; Zhang, J.; Sage, A. M.; Donahue, N. M. Controlled OH radical production via ozone-alkene reactions for use in aerosol aging studies Environ. Sci. Technol. 2007, 41, 2357-2363
18. Atkinson, R. Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds under atmospheric conditions Chem. Rev. 1986, 86, 69-201
19. Kramp, F.; Paulson, S. E. On the uncertainties in the rate coefficients for OH reactions with hydrocarbons, and the rate coefficients of the 1,3,5-trimethylbenzene and m-xylene reactions with OH radicals in the gas phase J. Phys. Chem. A 1998, 102, 2685-2690
20. VandenBoer, T. C.; Markovic, M. Z.; Petroff, A.; Czar, M. F.; Borduas, N.; Murphy, J. G. Ion chromatographic separation and quantitation of alkyl methylamines and ethylamines in atmospheric gas and particulate matter using preconcentration and suppressed conductivity detection J. Chromatogr., A 2012, 1252, 74-83
21. Wedian, F. Z.; Atkinson, D. B. Validation of the ozone + tetramethylethylene reaction using an atmospheric pressure flow reactor/ion trap mass spectrometer J. Atmos. Chem. 2010, 66, 65-80
22. Spirina, I. V.; Maslennikov, V. P.; Aleksandrov, Y. A.; Emel'yanov, B. V.; Demin, O. I. Reaction of monoethanolamine with hydrogen peroxide in aqueous solution J. Gen. Chem. USSR (Engl. Transl.) 1985, 55, 424-428
23. Gill, K. J.; Hites, R. A. Rate constants for the gas-phase reactions of the hydroxyl radical with isoprene, α-and β-pinene, and limonene as a function of temperature J. Phys. Chem. A 2002, 106, 2538-2544
24. Nielsen, C. J.; Herrmann, H.; Weller, C. Atmospheric chemistry and environmental impact of the use of amines in carbon capture and storage (CCS) Chem. Soc. Rev. 2012, 6684-6704
25. Kwok, E. S. C.; Atkinson, R. Estimation of hydroxyl radical reaction rate constants for gas-phase organic compounds using a structure-reactivity relationship: An update Atmos. Environ. 1995, 29, 1685-1695
26. Ohno, K.; Imai, K.; Harada, Y. Variations in reactivity of lone-pair electrons due to intramolecular hydrogen bonding as observed by Penning ionization electron spectroscopy J. Am. Chem. Soc. 1985, 107, 8078-8082
27. 3 with amines and related compounds Res. Chem. Intermed. 1994, 20, 303-320
28. Gai, Y.; Ge, M.; Wang, W. Rate constants for the gas phase reactions of ozone with diethylamine and triethylamine Acta Phys. Chim. Sin. 2010, 26, 1768-1772
29. Sengupta, S.; Indulkar, Y.; Kumar, A.; Dhanya, S.; Naik, P. D.; Bajaj, P. N. Kinetics of gas-phase reaction of OH with morpholine: An experimental and theoretical study J. Phys. Chem. A 2010, 114, 7709-7715
30. 2 J. Phys. Chem. A 2012, 116, 10980-10986
31. Ellenberger, M. R.; Dixon, D. A.; Farneth, W. E. Proton affinities and the site of protonation of enamines in the gas phase J. Am. Chem. Soc. 1981, 103, 5377-5382
32. Roberts, J. M.; Veres, P.; Warneke, C.; Neuman, J. A.; Washenfelder, R. A.; Brown, S. S.; Baasandorj, M.; Burkholder, J. B.; Burling, I. R.; Johnson, T. J.; Yokelson, R. J.; de Gouw, J. Measurement of HONO, HNCO, and other inorganic acids by negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS): Application to biomass burning emissions Atmos. Meas. Tech. 2010, 3, 981-990
33. Mladenović, M.; Lewerenz, M. Equilibrium structure and energetics of CHNO isomers: Steps towards ab initio rovibrational spectra of quasi-linear molecules Chem. Phys. 2008, 343, 129-140
34. Roberts, J. M.; Veres, P. R.; Cochran, A. K.; Warneke, C.; Burling, I. R.; Yokelson, R. J.; Lerner, B.; Gilman, J. B.; Kuster, W. C.; Fall, R.; de Gouw, J. Isocyanic acid in the atmosphere and its possible link to smoke-related health effects Proc. Natl. Acad. Sci. U. S. A. 2011, 108, 8966-8971
35. Barnes, I.; Solignac, G.; Mellouki, A.; Becker, K. H. Aspects of the atmospheric chemistry of amides ChemPhysChem 2010, 11, 3844-3857
36. Mascavage, L. M.; Sonnet, P. E.; Dalton, D. R. On the surface-catalyzed reaction between the gases 2,2-dimethylpropanal and methanamine. Formation of active-site imines J. Org. Chem. 2006, 71, 3435-3443
37. DeCarlo, P. F.; Kimmel, J. R.; Trimborn, A.; Northway, M. J.; Jayne, J. T.; Aiken, A. C.; Gonin, M.; Fuhrer, K.; Horvath, T.; Docherty, K. S.; Worsnop, D. R.; Jimenez, J. L. Field-deployable, high-resolution, time-of-flight aerosol mass spectrometer Anal. Chem. 2006, 78, 8281-8289
38. Ge, X.; Wexler, A. S.; Clegg, S. L. Atmospheric amines-Part II. Thermodynamic properties and gas/particle partitioning Atmos. Environ. 2011, 45, 561-577
39. Murphy, S. M.; Sorooshian, A.; Kroll, J. H.; Ng, N. L.; Chhabra, P.; Tong, C.; Surratt, J. D.; Knipping, E.; Flagan, R. C.; Seinfeld, J. H. Secondary aerosol formation from atmospheric reactions of aliphatic amines Atmos. Chem. Phys. 2007, 7, 2313-2337
40. Dawson, M. L.; Varner, M. E.; Perraud, V.; Ezell, M. J.; Gerber, R. B.; Finlayson-Pitts, B. J. Simplified mechanism for new particle formation from methanesulfonic acid, amines, and water via experiments and ab initio calculations Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 18719-18724