Degree of vinylidene character of α-heteroatom-substituted vinylmagnesium chlorides: A DFT study to discern the role of the halogen atom in magnesium alkylidene carbenoid chemistry

Tetrahedron

Volumn 69, Issue 31, 2013, Pages 6371-6374

  Kimura, Tsutomu ^a   Satoh, Tsuyoshi ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

Alkylidene carbine; DFT calculations; Magnesium alkylidene carbenoid; NBO analysis; Sulfoxide magnesium exchange

Indexed keywords

CARBENOID; HALOGEN; HALOVINYLPHENYLSULFOXIDE; MAGNESIUM ALKYLIDENE CARBENOID; MAGNESIUM CHLORIDE; PHENYLVINYLSULFOXIDE; SULFOXIDE; UNCLASSIFIED DRUG; VINYLIDENE CHLORIDE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; PHYSICAL CHEMISTRY; PRIORITY JOURNAL;

EID: 84879206743     PISSN: 00404020     EISSN: 14645416     Source Type: Journal    
DOI: 10.1016/j.tet.2013.05.108     Document Type: Article

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