Influence of the nanoparticle type on the thermal decomposition of the green starch/poly(vinyl alcohol)/montmorillonite nanocomposites

Journal of Thermal Analysis and Calorimetry

Volumn 111, Issue 3, 2013, Pages 1903-1919

  Nistor, Manuela Tatiana ^a   Vasile, Cornelia ^a  

^a PETRU PONI INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Romania)

Author keywords

Decomposition; FT IR; Mechanism; MS; Nanocomposites; TG

Indexed keywords

CONTROLLED TEMPERATURE; DEGRADATION MECHANISM; DEGRADATION PRODUCTS; FT-IR; MS; STARCH DEGRADATION; TG; VOLATILE COMPOUNDS;

CLAY MINERALS; DECOMPOSITION; DEGRADATION; FILLERS; INFRARED SPECTROSCOPY; MASS SPECTROMETRY; MECHANISMS; THERMOGRAVIMETRIC ANALYSIS; VOLATILE ORGANIC COMPOUNDS;

NANOCOMPOSITES;

EID: 84878575655     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-012-2731-6     Document Type: Article

References (57)

1. Pielichowski J, Pielichowski KJ. Application of thermal analysis for the investigation of polymer degradation processes. J Therm Anal Calorim. 1995;43:505-8.
2. Chai W-L, Chow J-D, Chen C-C, Chuang F-S, Lu W-C. Evaluation of the biodegradability of polyvinyl alcohol/starch blends: a methodological comparison of environmentally friendly materials. J Polym Environ. 2009;17:71-82.
3. Patachia-Bodonea S. Blends based on poly(vinyl alcohol) and the products based on this polymers. Chap 8. In: Vasile C, Kulshereshtha AK, editors. Handbook of polymer blends and composites, vol. 4A. Shawbury: RAPRA Technology Ltd; 2003. p. 288-365.
4. Preechawong D, Peesan M, Rujiravanit R, Supaphol P. Preparation and properties of starch/poly(vinyl alcohol) composite foams. Macromol Symp. 2004;216:217-27.
5. Cinelli P, Chellini E, Gordon SH, Imam SH. Characteristics and degradation of hybrid composite films prepared from PVA, starch and lignocellulosics. Macromol Symp. 2003;197:143-56.
6. Park JS, Yang JH, Kim DH, Lee DH. Degradability of expanded starch/PVA blends prepared using calcium carbonate as the expanding inhibitor. J Appl Polym Sci. 2004;93:911-9.
7. Hashem MM, Kesting W, Hebeish AA, Abou-Zeid NY, Schollmeyer F. Characterization and application of poly(vinyl alcohol)/starch composite as a sizing agent. Angew Makromol Chem. 1996;242:149-63.
8. Sreedhar B, Sairam M, Chattopadhhyay DK, Syamala Rathnam PA, Mohan Rao DV. Thermal, mechanical, and surface characterization of starch-poly(vinyl alcohol) blends and borax-crosslinked films. J Appl Polym Sci. 2005;96:1313-22.
9. Follain N, Joly C, Dole P, Bliard C. Properties of starch based blends. Part 2. Influence of poly vinyl alcohol addition and photocrosslinking on starch based materials mechanical properties. Carbohydr Polym. 2005;60:185-92.
10. Liu Z, Feng Y, Yi X-S. Thermoplastic starch/PVA compounds: preparation, processing and properties. J Appl Polym Sci. 1999;74:2667-73.
11. Ali SS, Tang X, Alavi S, Faubion J. Structure and physical properties of starch/poly vinyl alcohol/sodium montmorillonite nanocomposite films. J Agric Food Chem. 2011;59(23):12384-95.
12. Tang X, Alavi S. Recent advances in starch, polyvinylalcohol based polymer blends, nanocomposites and their biodegradability. Carbohydr Polym. 2011;85:7-16.
13. He Y, Zhang Y. Thermoplastic starch/polyvinyl alcohol/montmorillonite nanocomposites. Chinese Journal of Applied Chemistry. 2011;07. doi: CNKI:SUN:YYHX.0.2011-07-005.
14. Gomes ME, Ribeiro AS, Malafaya PB, Reis RL, Cunha AM. A new approach based on injection moulding to produce biodegradable starch based polymeric scaffolds: morphology, mechanical and degradation behaviour. Biomaterials. 2001;22:883-8.
15. Vaz CM, Reis RL, Cunha AM. Degradation model of starch-EVOH plus HA composites. Mater Res Innovations. 2001;4:375-80.
16. Abd Alla SG, Nizam El-Din HM, El-Naggar AWM. Electron beam synthesis and characterization of poly(vinyl alcohol)/montmorillonite nanocomposites. J Appl Polym Sci. 2006;102:1129-38.
17. Dimonie D, Radovici C, Trandafir I, Pop SF, Dumitriu I, Fierascu R, Jecu L, Petrea C, Zaharia C, Coşerea R. Some aspects concerning the silicate delamination for obtaining polymeric bio-hybrids based on starch. Rev Roum Chim. 2011;56(7):685-90.
18. Dimonie D, Constantin R, Vasilievici G, Popescu M-C, Garea S. The dependence of the XRD morphology of some bionanocomposites on the silicate treatment. J Nanomater 2008. doi: 10.1155/2008/538421.
19. Dimonie D, Socoteanu R, Doncea S, Pop FS, Petre C, Dumitriu I, Fierascu R. The miscibility estimation of some nanocomposites based on starch. e-Polymers. 2011;090. http://www.e-polymers.org.
20. Greene-Kelly R. The differential thermal investigation of clays. London: Mineralogical Society (Great Britain); 1957.
21. Xie W, Gao Z, Liu K, Pan W-P, Vaia R, Hunter D, Singh A. Thermal characterization of organically-modified montmorillonite. Thermochim Acta. 2001;339(367-368):2979-90.
22. Zheng X, Wilkie CA. Flame retardancy of polystyrene nanocomposites based on an oligomeric organically-modified clay containing phosphate. Polym Degrad Stab. 2003;81:551-7.
23. Wan C, Qiao X, Zhang Y, Zhang Y. Effect of different clay treatment on morphology and mechanical properties of PVC-clay nanocomposites. Polym Testing. 2003;22:453-61.
24. Vasile C, Stoleriu A, Popescu M-C, Duncianu C, Kelnar I, Dimonie D. Morphology and thermal properties of some green starch/poly(vinyl alcohol)/montmorillonite nanocomposites. Cellul Chem Technol. 2008;42(9-10):549-68.
25. Bourbigot S, Gilman JW, Wilkie CA. Kinetic analysis of the thermal degradation of polystyrene-montmorillonite nanocomposite. Polym Degrad Stab. 2004;84:483-92.
26. Xie W, Gao ZM, Pan WP, Hunter D, Singh A, Vaia RA. Thermal degradation chemistry of alkyl quaternary ammonium montmorillonite. Chem Mater. 2001;13:2979-90.
27. Chang JH, Jang TG, Ihn KJ, Lee WK, Sur GS. Poly(vinyl alcohol) nanocomposites with different clays: pristine clays and organoclays. J Appl Polym Sci. 2003;90:3208-14.
28. Peng Z, Kong LX, Li SD. Study on thermooxidative degradation of poly(vinyl alcohol)/silica nanocomposite prepared with SAM technique. J Metastable Nanocryst Mater. 2005;23:375.
29. Qin H, Zhang S, Zhao C, Yang M. Zero-order kinetics of the thermal degradation of polypropylene/clay nanocomposites. J Polym Sci B. 2005;43:3713-9.
30. Kumar S, Jog JP, Natarajan U. Preparation and characterization of poly(methylmethacrylate)-clay nanocomposites via melt intercalation: the effect of organoclay on the structure and thermal properties. J Appl Polym Sci. 2003;89:1186-94.
31. Lepoittevin B, Pantoustier N, Devalckenaere M, Alexandre M, Kubies D, Calberg C, Jerome R, Dubois P. Poly(epsiloncaprolactone)/clay nanocomposites by in situ intercalative polymerization catalyzed by dibutyltin dimethoxide. Macromolecules. 2002;35(22):8385-90.
32. Leszczyńska A, Njuguna J, Pielichowski K, Banerjee JR. Polymer/montmorillonite nanocomposites with improved thermal properties. Part I: factors influencing thermal stability and mechanisms of thermal stability improvement. Therm Acta. 2007;453(2):75-96.
33. Leszczyńska A, Njuguna J, Pielichowski K, Banerjee JR. Polymer/montmorillonite nanocomposites with improved thermal properties: part II. Thermal stability of montmorillonite nanocomposites based on different polymeric matrixes. Therm Acta. 2007;454:1-22.
34. Peng Z, Kong LX, Li S-D. Thermal properties and morphology of a poly(vinyl alcohol)/silica nanocomposite prepared with a self-assembled monolayer technique. J Appl Polym Sci. 2005;96:1436-42.
35. Gilman JW, VanderHart DL, Kashiwagi T. Thermal decomposition chemistry of poly(vinyl alcohol) char characterization and reactions with bismaleimides, Chap. 11. In: Fire and polymers II: materials and test for hazard prevention. Symposium Series, Vol. 599, August 21-26. Washington DC: American Chemical Society; 1994. p. 161-185.
36. Chen Y, Cao X, Chang PR, Huneault MA. Comparative study on the films of poly(vinyl alcohol)/pea starch nanocrystals and poly(vinyl alcohol)/native pea starch. Carbohydr Polym. 2008;73:8-17.
37. Zhang X, Golding J, Burger I. Thermal decomposition chemistry of starch studied by 13C high resolution solid-state NMR spectroscopy. Polymer. 2002;43(22):5791-6.
38. Mano JF, Koniarova D, Reis RL. Thermal properties of thermoplastic starch/synthetic polymer blends with potential biomedical applicability. J Mater Sci Mater Med. 2003;14:127-35.
39. Bryce DJ, Greenwood CT. The thermal degradation of starch part III. The formation of decomposition products from starch and related materials at temperatures between 175 C and 400 C. Die Starke. 1963;15(10):359-63.
40. Smith BC. Fundamentals of Fourier transform infrared spectroscopy. Boca Raton: CRC; 1996. p. 74-83.
41. Pascu M-C, Rusu V, Vasile C. Applications of the IR spectrometry in medicine and pharmacy. Iasi: Technopress; 2003. p. 422-9.
42. Gilman JW, Kashiwagi T, Vander Hart DL. Thermal decomposition chemistry of poly(vinyl alcohol). Char characterization and reactions with bismaleimides. In: Fire and polymers II: materials and test for hazard prevention. ACD Symposium Series, Vol. 599. Washington, DC: American Chemical Society; 1994.
43. Peng Z, Kong LX. A thermal degradation mechanism of polyvinyl alcohol/silica nanocomposites. Polym Degrad Stab. 2007;92:1061-71.
44. Liu X, Yu L, Liu H, Chen L, Li L. In situ thermal decomposition of starch with constant moisture in a sealed system. Polym Degrad Stab. 2008;93(1):260-2.
45. Wojciech C, Tomasik P. Starch radicals. Part I. Thermolysis of plain starch. Carbohydr Polym. 1996;31(4):205-10.
46. http://webbook.nist.gov/chemistry/. http://www.chemistry.ccsu.edu/ glagovich/teaching/316/ms%20(old)/ms.html.
47. Periadurai T, Vijayakumar CT, Balasubramanianv M. Thermal decomposition behavior of clay-phenolic nanocomposite prepared by in situ polymerization. Advanced materials nanotechnology particles, films and composites chapter 5: composite materials nanotechnology. 2011. p. 554-557.
48. Zhu J, Morgan AB, Lamelas FJ, Wilkie CA. Fire properties of polystyrene-clay nanocomposites. Chem Mater. 2001;13:3774.
49. Kotsilkova R, Petkova V, Pelovski Y. Thermal analysis of polymer-silicate nanocomposites. J Therm Anal Calorim. 2001;64:591-8.
50. Alexandre M, Dubois P. Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Mater Sci Eng, R. 2000;28:1-63.
51. Bourbigot S, Le Bras M, Da̧browski F, Gilman JW, Kashiwagi T. PA-6 clay nanocomposite hybrid as char forming agent in intumescent formulations. Fire Mater. 2000;24:201-8.
52. Zhu J, Wilkie CA. Thermal and fire studies on polystyrene-clay nanocomposites. Polym Int. 2000;49:1158-63.
53. Gilman JW, Jackson CL, Morgan AB, Harris R Jr, Manias E, Giannelis EP. Propylene and polystyrene nanocomposites. Chem Mater. 2000;12:1866-73.
54. Agag T, Takeichi T. Polybenzoxazine-montmorillonite hybrid nanocomposites: synthesis and characterization. Polymer. 2000;41:7083-90.
55. Levchik SV, Wilkie CA. In: Grand AF, Wilkie CA, editors. Fire retardancy of polymeric materials. New York: Marcel Dekker; 2000. p. 171-215.
56. Zanetti M, Bracco P, Costa L. Thermal degradation behavior of PE/clay nanocomposites. Polym Degrad Stab. 2004;85:657-65.
57. Jang BN, Wilkie CA. The thermal degradation of polystyrene nanocomposite. Polymer. 2005;46(9):3264-3274, 2933-2942, 46(23):9702-9713; 10678-10687.