메뉴 건너뛰기




Volumn 5, Issue 6, 2013, Pages 1562-1569

Rhodium-Catalyzed Homogeneous and Aqueous Biphasic Hydroformylation of the Acrolein Acetal 2-Vinyl-5-Methyl-1,3-Dioxane

Author keywords

Homogeneous catalysis; Hydroformylation; Phosphanes; Rhodium

Indexed keywords

BIPHASIC CONDITIONS; BIPHASIC HYDROFORMYLATION; BRANCHED ALDEHYDES; DIPHOSPHINE LIGAND; HOMOGENEOUS CATALYSIS; HOMOGENEOUS CONDITIONS; PHOSPHANES; RHODIUM-CATALYZED HYDROFORMYLATION;

EID: 84878519318     PISSN: 18673880     EISSN: 18673899     Source Type: Journal    
DOI: 10.1002/cctc.201200630     Document Type: Article
Times cited : (9)

References (87)
  • 1
    • 84878521930 scopus 로고    scopus 로고
    • For leading review articles, see:
    • For leading review articles, see:
  • 2
    • 0004147148 scopus 로고    scopus 로고
    • P.W.N.M. vanLeeuwen, C. Claver), Kluwer, Dordrecht
    • Rhodium Catalysed Hydroformylation (Eds.: P.W.N.M. vanLeeuwen, C. Claver), Kluwer, Dordrecht, 2000;
    • (2000) Rhodium Catalysed Hydroformylation
  • 3
    • 33749030699 scopus 로고    scopus 로고
    • (Ed.: M. Beller) in Top. Organomet. Chem.
    • K.-D. Wiese, D. Obst (Ed.: M. Beller) in Top. Organomet. Chem. 2006, 18, 1-33;
    • (2006) , vol.18 , pp. 1-33
    • Wiese, K.-D.1    Obst, D.2
  • 4
    • 34347233398 scopus 로고    scopus 로고
    • (Ed.: M.J. Krische) in Top. Curr. Chem., For recent leading examples, see:
    • B. Breit (Ed.: M.J. Krische) in Top. Curr. Chem. 2007, 279, 139-172; For recent leading examples, see:
    • (2007) , vol.279 , pp. 139-172
    • Breit, B.1
  • 17
    • 84878516029 scopus 로고    scopus 로고
  • 21
    • 0038170742 scopus 로고    scopus 로고
    • (Eds.: P.W.N.M. vanLeeuwen, C. Claver), Kluwer, Dordrecht
    • J. Herwig, R. Fischer in Rhodium-Catalyzed Hydroformylation (Eds.: P.W.N.M. vanLeeuwen, C. Claver), Kluwer, Dordrecht, 2000, 189-202.
    • (2000) Rhodium-Catalyzed Hydroformylation , pp. 189-202
    • Herwig, J.1    Fischer, R.2
  • 22
    • 84878491854 scopus 로고    scopus 로고
  • 32
    • 84878480500 scopus 로고    scopus 로고
  • 33
    • 84878481750 scopus 로고
    • E.I. Du Pont deNemours and Co.) US Pat. 3929915
    • C. C. Cumbo, K. K. Bhatia (E.I. Du Pont deNemours and Co.) US Pat. 3929915, 1974;
    • (1974)
    • Cumbo, C.C.1    Bhatia, K.K.2
  • 34
    • 84878474599 scopus 로고
    • E.I. Du Pont deNemours and Co.) US Pat. 4024197
    • C. C. Cumbo, K. K. Bhatia (E.I. Du Pont deNemours and Co.) US Pat. 4024197, 1975;
    • (1975)
    • Cumbo, C.C.1    Bhatia, K.K.2
  • 38
    • 84878488067 scopus 로고    scopus 로고
    • There is no detailed report in the literature on the direct hydroformylation of acrolein; to our knowledge, all existing reports deal with the use of acetal-protected acrolein; see references [5,6].
    • There is no detailed report in the literature on the direct hydroformylation of acrolein; to our knowledge, all existing reports deal with the use of acetal-protected acrolein; see references [5, 6].
  • 39
    • 84878511167 scopus 로고    scopus 로고
    • See for instance:
    • See for instance:
  • 45
    • 84878511508 scopus 로고    scopus 로고
    • For the direct production of homologous alcohols from olefins, see:
    • For the direct production of homologous alcohols from olefins, see:
  • 48
    • 84878494602 scopus 로고    scopus 로고
  • 51
    • 4243744401 scopus 로고
    • For the initial design of the PNNP ligand, see
    • For the initial design of the PNNP ligand, see: R. P. Nielsen, H. H. Sisler, Inorg. Chem. 1963, 2, 753-760.
    • (1963) Inorg. Chem. , vol.2 , pp. 753-760
    • Nielsen, R.P.1    Sisler, H.H.2
  • 52
    • 84878497639 scopus 로고    scopus 로고
    • For the initial design of the PomPom ligand, see:
    • For the initial design of the PomPom ligand, see:
  • 56
    • 84878515145 scopus 로고    scopus 로고
    • I-phosphine complexes, see:
    • I-phosphine complexes, see:
  • 63
    • 84878497718 scopus 로고    scopus 로고
    • iPr), and eventually characterized by X-ray diffraction, was indeed significantly different (97.2°).
    • iPr), and eventually characterized by X-ray diffraction, was indeed significantly different (97.2°).
  • 64
    • 84878475754 scopus 로고    scopus 로고
  • 65
    • 33645456932 scopus 로고    scopus 로고
    • Eds.: B. Cornils, W.A. Herrmann), VCH, Weinheim
    • Aqueous-Phase Organometallic Catalysis (Eds.: B. Cornils, W.A. Herrmann), VCH, Weinheim, 2004;
    • (2004) Aqueous-Phase Organometallic Catalysis
  • 66
    • 53849148487 scopus 로고    scopus 로고
    • in (Eds.: B. Cornils, W.A. Herrmann, I.T. Horvath, W. Leitner, S. Mecking, H. Olivier-Bourbigou, D. Vogt), Wiley-VCH, Weinheim
    • E. Monflier, in Multiphase Homogeneous Catalysis, Vol.1 (Eds.: B. Cornils, W.A. Herrmann, I.T. Horvath, W. Leitner, S. Mecking, H. Olivier-Bourbigou, D. Vogt), Wiley-VCH, Weinheim, 2005, pp.179-183;
    • (2005) Multiphase Homogeneous Catalysis, Vol.1 , pp. 179-183
    • Monflier, E.1
  • 69
    • 84878473411 scopus 로고    scopus 로고
  • 73
    • 84878498040 scopus 로고    scopus 로고
  • 78
    • 84878478543 scopus 로고    scopus 로고
    • 2; see Ref.[18c].
    • 2; see Ref.[18c].
  • 79
    • 84878480793 scopus 로고    scopus 로고
    • Only minor amounts of propanal and propanol (i.e., the hydrogenation products derived from 3) were observed in this case.
    • Only minor amounts of propanal and propanol (i.e., the hydrogenation products derived from 3) were observed in this case.
  • 80
    • 84878505666 scopus 로고
    • E.I. Du Pont deNemours and Co.) US Pat. 4024159
    • M. L. Peterson (E.I. Du Pont deNemours and Co.) US Pat. 4024159, 1974.
    • (1974)
    • Peterson, M.L.1
  • 81
    • 84878517982 scopus 로고    scopus 로고
    • We have checked with the Rh-xantphos homogenous (in toluene) system that the results (conversion versus time) are not significantly affected by the stirring speed (over the range: 500-1000rpm), demonstrating that the reaction is not under mass transfer limitations.
    • We have checked with the Rh-xantphos homogenous (in toluene) system that the results (conversion versus time) are not significantly affected by the stirring speed (over the range: 500-1000rpm), demonstrating that the reaction is not under mass transfer limitations.
  • 82
    • 84878504249 scopus 로고    scopus 로고
  • 84
    • 84878500757 scopus 로고    scopus 로고
    • SHELXS-97, Program for the Determination of Crystal Structures, University of Goettingen (Germany)
    • G.M. Sheldrick, SHELXS-97, Program for the Determination of Crystal Structures, University of Goettingen (Germany), 1997;
    • (1997)
    • Sheldrick, G.M.1
  • 85
    • 84878504679 scopus 로고    scopus 로고
    • SHELXL-97, Program for the Refinement of Crystal Structures, University of Goettingen (Germany)
    • G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, University of Goettingen (Germany), 1997;
    • (1997)
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.