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84878488067
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There is no detailed report in the literature on the direct hydroformylation of acrolein; to our knowledge, all existing reports deal with the use of acetal-protected acrolein; see references [5,6].
-
There is no detailed report in the literature on the direct hydroformylation of acrolein; to our knowledge, all existing reports deal with the use of acetal-protected acrolein; see references [5, 6].
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39
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See for instance:
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See for instance:
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For the direct production of homologous alcohols from olefins, see:
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For the direct production of homologous alcohols from olefins, see:
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47
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For the initial design of the PomPom ligand, see:
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For the initial design of the PomPom ligand, see:
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I-phosphine complexes, see:
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I-phosphine complexes, see:
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iPr), and eventually characterized by X-ray diffraction, was indeed significantly different (97.2°).
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iPr), and eventually characterized by X-ray diffraction, was indeed significantly different (97.2°).
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2; see Ref.[18c].
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Only minor amounts of propanal and propanol (i.e., the hydrogenation products derived from 3) were observed in this case.
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Only minor amounts of propanal and propanol (i.e., the hydrogenation products derived from 3) were observed in this case.
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84878505666
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We have checked with the Rh-xantphos homogenous (in toluene) system that the results (conversion versus time) are not significantly affected by the stirring speed (over the range: 500-1000rpm), demonstrating that the reaction is not under mass transfer limitations.
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We have checked with the Rh-xantphos homogenous (in toluene) system that the results (conversion versus time) are not significantly affected by the stirring speed (over the range: 500-1000rpm), demonstrating that the reaction is not under mass transfer limitations.
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