NMR relaxometry study of the interaction of water with a nafion membrane under acid, sodium, and potassium forms. Evidence of two types of bound water

Journal of Physical Chemistry B

Volumn 117, Issue 21, 2013, Pages 6534-6540

  Xu, Feina ^a   Leclerc, Sébastien ^a   Canet, Daniel ^b,c  

^a NANCY UNIVERSITÉ   (France)

^b UNIVERSITÉ DE LORRAINE   (France)

^c CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

PHYSICAL CHEMISTRY; PHYSICS;

CHEMICAL TREATMENTS; INTERMOLECULAR CONTRIBUTIONS; MOLECULAR SCALE; NAFION MEMBRANE; NMR MEASUREMENTS; NMR RELAXOMETRY; PROTON RELAXATION; WATER BEHAVIOR;

PROTONS;

EID: 84878357178     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/jp311062h     Document Type: Article

References (27)

1. Zhang, H.; Shen, P. K. Recent Development of Polymer Electrolyte Membranes for Fuel Cells Chem. Rev. 2012, 112, 2780-2832
2. Mauritz, K. A.; Moore, R. B. State of Understanding of Nafion Chem. Rev. 2004, 104, 4535-4585
3. Hickner, M. A.; Ghassemi, H.; Kim, Y. S.; Einsla, B. R.; Mc Grath, J. E. Alternative Polymer Systems for Proton Exchange Membranes (PEMs) Chem. Rev. 2004, 104, 4587-4612
4. Costamagna, P.; Srinivasan, S. Quantum Jumps in the PEMFC Science and Technology from the 1960s to the Year 2000 Part I. Fundamental Scientific Aspects J. Power Sources 2001, 102, 242-252
5. Evans, C. E.; Noble, R. D.; Nazeri-Thompson, S.; Nazeri, B.; Koval, C. A. Role of Conditioning on Water Uptake and Hydraulic Permeability of Nafion Membranes J. Membr. Sci. 2006, 279, 521-528
6. Doyle, M.; Lewittes, M. E.; Roelofs, M. G.; Perusich, S. A.; Lowrey, R. E. Relationship between Ionic Conductivity of Perfluorinated Ionomeric Membranes and Nonaqueous Solvent Properties J. Membr. Sci. 2001, 184, 257-273
7. Gebel, G. Structural Evolution of Water Swollen Perfluorosulfonated Ionomers from Dry Membrane to Solution Polymer 2000, 41, 5829-5838
8. Gierke, T. D.; Munn, G. E.; Wilson, F. C. The Morphology in Nafion Perfluorinated Membrane Products, as Determined by Wide- and Small-Angle X-ray Studies J. Polym. Sci. 1981, 19, 1687-1704
9. Schmidt-Rohr, K.; Chen, Q. Parrallel Cylindrical Water Nanochannels in Nafion Fuel-Cell Membranes Nat. Mater. 2008, 7, 75-83
10. Tanner, T. E. Use of the Stimulated Echo in NMR Diffusion Studies J. Chem. Phys. 1970, 52, 2523-2526
11. Stejskal, E. O.; Tanner, J. E. Spin-Diffusion Measurements: Spin-Echoes in the Presence of a Time-Dependent Field Gradient J. Chem. Phys. 1965, 42, 288-292
12. Kimmich, R. Strange Kinetics, Porous Media, and NMR Chem. Phys. 2002, 284, 253-285
13. Bertini, I.; Fragai, M.; Luchinat, C.; Parigi, G. 1H NMRD Profiles of Diamagnetic Proteins: A Model-Free Analysis Magn. Reson. Chem. 2000, 38, 543-550
14. MacMillan, B.; Sharp, A. R.; Armstrong, R. L. An N.M.R. Investigation of the Dynamical Characteristics of Water Absorbed in Nafion Polymer 1999, 40, 2471-2480
15. Perrin, J.-C.; Lyonnard, S.; Guillermo, A.; Levitz, P. Water Dynamics in Ionomer Membranes by Field-Cycling NMR Relaxometry J. Phys. Chem. B 2006, 110, 5439-5444
16. MacMillan, B.; Sharp, A. R.; Armstrong, R. L. N.M.R. Relaxation in Nafion-The Low Temperature Regime Polymer 1999, 40, 2481-2485
17. 1H NMR: Self-Diffusion Measurements and Proton Quantization J. Membr. Sci. 2011, 371, 148-154
18. Stelar. www.stelar.it (2010).
19. Kimmich, R.; Anoardo, E. Field-Cycling NMR Relaxometry Prog. Nucl. Magn. Reson. Spectrosc. 2004, 44, 257-320
20. Kruk, D.; Herrmann, A.; Rössler, E. A. Field-Cycling NMR Relaxomertry of Viscous Liquids and Polymers Prog. Nucl. Magn. Reson. Spectrosc. 2012, 63, 33-64
21. Neves, L. A.; Sebastiao, P. J.; Coelhoso, I. M.; Crespo, J. G. Proton NMR Relaxometry Study of Nafion Membranes Modified with Ionic Liquid Cations J. Phys. Chem. B. 2011, 115, 8713-8723
22. Saito, M.; Arimura, N.; Hayamizu, K.; Okada, T. Mechanims of Ion and Water Transport in Perflurosulfonated Ionomer Membranes for Fuel Cells J. Phys. Chem. B. 2004, 108, 16064-16070
23. Perrin, J.-C. Multi-Scale Experimental Study of Water Dynamics in Ionomer Membranes Used in Fuel Cells. Ph.D. Thesis, Grenoble, France, 2006.
24. Koenig, S. H.; Schillinger, W. E. Nuclear Magnetic Relaxation Dispersion in Protein Solutions. I. Apotransferrin J. Bio. Chem. 1969, 244, 3283-3289
25. Lee, D. K.; Saito, T.; Benesi, A. J.; Hickner, M. A.; Allcock, H. R. Characterization of Water in Proton-Conducting Membranes by Deuterium NMR T1 Relaxation J. Phys. Chem. B 2011, 115, 776-783
26. Halle, B.; Johannesson, H.; Venu, K. Model-Free Analysis of Streched Relaxation Dispersions J. Magn. Reson. 1998, 135, 1-13
27. Steiner, E.; Bouguet-Bonnet, S.; Robert, A.; Canet, D. "Relaxometry" Experiments and Analysis of Dispersion Curves: An Illustrative Example of Toluene in Liquid and in Organolgel Phases Concepts Magn. Reson. Part A 2012, 40, 80-89