Role of conditioning on water uptake and hydraulic permeability of Nafion® membranes

Journal of Membrane Science

Volumn 279, Issue 1-2, 2006, Pages 521-528

  Evans, Christine E ^a   Noble, Richard D ^b   Nazeri Thompson, Sarah ^a,b   Nazeri, Brian ^a,b   Koval, Carl A ^a  

^a UNIVERSITY OF COLORADO   (United States)

^b UCB 450   (United States)

Author keywords

Ion exchange membranes; Ionomer membranes; Water transport

Indexed keywords

FUEL CELLS; HEAT TREATMENT; HYDRAULIC CONDUCTIVITY; IONOMERS; MECHANICAL PERMEABILITY; PRESSURE DISTRIBUTION; TRANSPORT PROPERTIES;

ALKALI SERIES; HYDRAULIC PERMEABILITY; IONOMER MEMBRANES; WATER TRANSPORT;

ION EXCHANGE MEMBRANES;

ANION; ELECTROLYTE; HYDROGEN; LITHIUM; POTASSIUM; SODIUM; SULFONIC ACID DERIVATIVE;

FUEL CELLS; HEAT TREATMENT; HYDRAULIC CONDUCTIVITY; ION EXCHANGE MEMBRANES; IONOMERS; MECHANICAL PERMEABILITY; PRESSURE DISTRIBUTION; TRANSPORT PROPERTIES;

ARTICLE; CATION EXCHANGE; HEAT TREATMENT; HYDRAULIC PERMEABILITY; ION EXCHANGE; MEMBRANE; PRIORITY JOURNAL; WATER CONTENT; WATER TRANSPORT;

EID: 33744522363     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2005.12.046     Document Type: Article

References (22)

1. ® perfluorinated membranes in fuel cells. J. Fluorine Chem. 125 (2004) 1211
2. Strathmann H. Electrodialysis and its application in the chemical process industry. Sep. Purif. Methods 14 (1985) 41
3. Mauritz K.A., and Moore R.B. State of understanding of Nafion. Chem. Rev. 104 (2004) 4535
4. Norman M.A., Evans C.E., Fuoco A.R., Noble R.D., and Koval C.A. Characterization of a membrane-based, electrochemically driven pumping system using aqueous electrolyte solutions. Anal. Chem. 77 (2005) 6374
5. Evans C.E., Noble R.D., and Koval C.A. A nonmechanical, membrane-based liquid pumping and pressurization system. Ind. Eng. Chem. Res. 45 (2006) 472
6. Steck A., and Yeager H.L. Water sorption and cation-exchange selectivity of a perfluorosulfonate ion-exchange polymer. Anal. Chem. 52 (1980) 1215
7. Berezina N.P., Timofeev S.V., and Kononenko N.A. Effect of conditioning techniques on perfluorinated sulphocationic membranes on their hydrophilic and electrotransport properties. J. Membr. Sci. 209 (2002) 509
8. Gierke T.D., and Hsu W.Y. The cluster-network model of ion clustering in perfluorosulfonated membranes. ACS Sym. Ser. 180 (1982) 217
9. Fabiani C., Scibona G., and Scuppa B. Correlations between electroosmotic coefficients and hydraulic permeability in Nafion membranes. J. Membr. Sci. 16 (1983) 51
10. + and alkali metal cations. J. Phys. Chem. B 106 (2002) 1267
11. Hashimoto T., Fujimura M., and Kawai H. Perfluorinated membranes. ACS Symp. Ser. 180 (1982) (Chapter 11)
12. Villaluenga J.P.G., Seoane B., Barragán V.M., and Ruíz-Bauzá C. Permeation of electrolyte water-methanol solutions through a Nafion membrane. J. Colloid Interface Sci. 268 (2003) 476
13. Ceynowa J. Pore model parameters of cation-exchange membranes. Angew. Makromol. Chem. 121 (1984) 97
14. K.S. Sportsman, The dehydration of nitric acid through Nafion ionomer membranes using high pressure membrane processes, Ph.D. Thesis, Chemical Engineering, Colorado School of Mines, Golden CO, 2002.
15. Pau P.C.F., Berg J.O., and McMillan W.G. Application of Stokes' law to ions in aqueous solution. J. Phys. Chem. 94 (1990) 2671
16. Meier F., and Eigenberger G. Transport properties for the modeling of water transport in ionomer membranes for PEM-fuel cells. Electrochim. Acta 49 (2004) 1731
17. Verbrugge M.W., and Hill R.F. Experimental and theoretical investigation of perfluorosulfonic acid membranes equilibrated with aqueous sulfuric acid solutions. J. Phys. Chem. 92 (1988) 6778
18. Palomo J., and Pintauro P.N. Competitive adsorption of quaternary ammonium and alkali metal cations into a Nafion cation-exchange membrane. J. Membr. Sci. 215 (2003) 103
19. Orfino F.P., and Holdcroft S. The morphology of Nafion: are ion clusters bridged by channels or single ionic sites?. J. New Mater. Electrochem. Syst. 3 (2000) 287
20. Verbrugge M.W., and Hill R.F. Transport phenomena in perfluorosulfonic acid membranes during the passage of current. J. Electrochem. Soc. 137 (1990) 1131
21. Mulder M. Basic Principles of Membrane Technology. second ed. (1996), Kluwer Academic Publishers, The Netherlands p. 218, 261
22. Wijmans J.G., and Baker R.W. The solution-diffusion model: a review. J. Membr. Sci. 107 (1995) 1