Hierarchical polymerized high internal phase emulsions synthesized from surfactant-stabilized emulsion templates

Langmuir

Volumn 29, Issue 20, 2013, Pages 5952-5961

  Wong, Ling L C ^a   Baiz Villafranca, Pedro M ^a   Menner, Angelika ^b   Bismarck, Alexander ^a,b  

^a IMPERIAL COLLEGE LONDON   (United Kingdom)

^b UNIVERSITY OF VIENNA   (Austria)

Author keywords

[No Author keywords available]

Indexed keywords

HIERARCHICAL POROUS; HIGH INTERNAL PHASE EMULSIONS; LOAD TRANSFER MECHANISM; MACROPOROUS POLYMERS; MECHANICAL PERFORMANCE; STRUCTURAL ELEMENTS; STRUCTURAL HIERARCHIES; SURFACTANT-STABILIZED;

ELASTIC MODULI; EMULSIFICATION; FINITE ELEMENT METHOD; POROUS MATERIALS; SURFACE ACTIVE AGENTS;

POLYMERS;

POLYMER; SURFACTANT;

ARTICLE; CHEMISTRY; EMULSION; PARTICLE SIZE; POLYMERIZATION; POROSITY; SURFACE PROPERTY; SYNTHESIS;

EMULSIONS; PARTICLE SIZE; POLYMERIZATION; POLYMERS; POROSITY; SURFACE PROPERTIES; SURFACE-ACTIVE AGENTS;

EID: 84878249612     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la3047643     Document Type: Article

References (48)

1. Lee, K.-Y.; Wong, L. L. C.; Blaker, J. J.; Hodgkinson, J.; Bismarck, A. Bio-based macroporous polymer nanocomposites made by mechanical frothing of acrylated and epoxidised soybean oil Green Chem. 2011, 13, 3117-3123
2. Barron, B. G.; Dunlap, J. R. Air frothed polyurethane foams. U.S. Patent 3,821,130, May 18, 1973.
3. Evans, A.; Edward, J.; Harris, A. J. A method of producing an expanded foamed material and components and apparatus for use in such a method. WO Patent 98/42775, Jan 19, 2000.
4. Cai, Q.; Yang, J.; Bei, J.; Wang, S. A novel porous cells scaffold made of polylactide-dextran blend by combining phase-separation and particle-leaching techniques Biomaterials 2002, 23 (23) 4483-4492
5. Nam, Y. S.; Park, T. G. Porous biodegradable polymeric scaffolds prepared by thermally induced phase separation J. Biomed. Mater. Res., Part A 1999, 47 (1) 8-17
6. Kumar, V.; Suh, N. P. A process for making microcellular thermoplastic parts Polym. Eng. Sci. 1990, 30 (20) 1323-1329
7. Goel, S. K.; Beckman, E. J. Generation of microcellular polymeric foams using supercritical carbon dioxide. I: Effect of pressure and temperature on nucleation Polym. Eng. Sci. 1994, 34 (14) 1137-1147
8. Cooper, A. I. Polymer synthesis and processing using supercritical carbon dioxide J. Mater. Chem. 2000, 10 (2) 207-234
9. Carn, F.; Colin, A.; Achard, M.-F.; Deleuze, H.; Sellier, E.; Birot, M.; Backov, R. Inorganic monoliths hierarchically textured via concentrated direct emulsion and micellar templates J. Mater. Chem. 2004, 14 (9) 1370-1376
10. Zhao, C.; Danish, E.; Cameron, N. R.; Kataky, R. Emulsion-templated porous materials (PolyHIPEs) for selective ion and molecular recognition and transport: Applications in electrochemical sensing J. Mater. Chem. 2007, 17 (23) 2446-2453
11. Zhang, H.; Hardy, G. C.; Rosseinsky, M. J.; Cooper, A. I. Uniform emulsion-templated silica beads with high pore volume and hierarchical porosity Adv. Mater. 2003, 15 (1) 78-81
12. Carnachan, R. J.; Bokhari, M.; Przyborski, S. A.; Cameron, N. R. Tailoring the morphology of emulsion-templated porous polymers Soft Matter 2006, 2 (7) 608-616
13. Mercier, A.; Deleuze, H.; Mondain-Monval, O. Preparation and functionalization of (vinyl)polystyrene polyHIPE: Short routes to binding functional groups through a dimethylene spacer React. Funct. Polym. 2000, 46 (1) 67-79
14. Akay, G.; Erhan, E.; Keskinler, B. Bioprocess intensification in flow-through monolithic microbioreactors with immobilized bacteria Biotechnol. Bioeng. 2005, 90 (2) 180-190
15. Ottens, M.; Leene, G.; Beenackers, A. A. C. M.; Cameron, N.; Sherrington, D. C. PolyHipe: A new polymeric support for heterogeneous catalytic reactions: Kinetics of hydration of cyclohexene in two- and three-phase systems over a strongly acidic sulfonated PolyHipe Ind. Eng. Chem. Res. 2000, 39 (2) 259-266
16. Bhumgara, Z. Polyhipe foam materials as filtration media Filtr. Sep. 1995, 32 (3) 245-251
17. Busby, W.; Cameron, N. R.; Jahoda, C. A. B. Emulsion-derived foams (PolyHIPEs) containing poly(ε-caprolactone) as matrixes for tissue engineering Biomacromolecules 2001, 2 (1) 154-164
18. Shirshova, N.; Bismarck, A. In-situ preparation of polymer scaffolds in retarded cement slurries: An emulsion templating approach for rapid, on-demand strength development Cem. Concr. Compos. 2012, 34 (3) 337-341
19. Shirshova, N.; Menner, A.; Funkhouser, G. P.; Bismarck, A. Polymerised high internal phase emulsion cement hybrids: Macroporous polymer scaffolds for setting cements Cem. Concr. Res. 2011, 41 (4) 443-450
20. Ikem, V. O.; Menner, A.; Bismarck, A.; Norman, L. R. Liquid Screen: A Novel Method To Produce an In-Situ Gravel Pack. DOI: http://dx.doi.org/10.2118/ 141256-PA.
21. Blaker, J.; Lee, K.-Y.; Li, X.; Menner, A.; Bismarck, A. Renewable nanocomposite polymer foams synthesized from Pickering emulsion templates Green Chem. 2009, 11 (9) 1321-1326
22. Colver, P. Cellular polymer monoliths made via Pickering high internal phase emulsions Chem. Mater. 2007, 19 (7) 1537-1539
23. Ikem, V. O.; Menner, A.; Bismarck, A. High internal phase emulsions stabilized solely by functionalized silica particles Angew. Chem., Int. Ed. 2008, 47 (43) 8277-8279
24. Menner, A.; Verdejo, R.; Shaffer, M.; Bismarck, A. Particle-stabilized surfactant-free medium internal phase emulsions as templates for porous nanocomposite materials: poly-Pickering-foams Langmuir 2007, 23 (5) 2398-2403
25. Wong, L. L. C.; Ikem, V. O.; Menner, A.; Bismarck, A. Macroporous polymers with hierarchical pore structure from emulsion templates stabilized by both particles and surfactants Macromol. Rapid Commun. 2011, 32 (19) 1563-1568
26. Cameron, N. R.; Sherrington, D. C.; Albiston, L.; Gregory, D. P. Study of the formation of the open-cellular morphology of poly(styrene/divinylbenzene) polyHIPE materials by cryo-SEM Colloid Polym. Sci. 1996, 274 (6) 592-595
27. Cameron, N. R. High internal phase emulsion templating as a route to well-defined porous polymers Polymer 2005, 46 (5) 1439-1449
28. Cameron, N.; Sherrington, D. High Internal Phase Emulsions (HIPEs)-Structure, Properties and Use in Polymer Preparation; Springer: Berlin, Germany, 1996; Vol. 126, pp 163-214.
29. Hainey, P.; Huxham, I. M.; Rowatt, B.; Sherrington, D. C.; Tetley, L. Synthesis and ultrastructural studies of styrene-divinylbenzene Polyhipe polymers Macromolecules 1991, 24 (1) 117-121
30. Luo, Y.; Wang, A.-N.; Gao, X. Pushing the mechanical strength of PolyHIPEs up to the theoretical limit through living radical polymerization Soft Matter 2012, 8 (6) 1824-1830
31. Menner, A.; Haibach, K.; Powell, R.; Bismarck, A. Tough reinforced open porous polymer foams via concentrated emulsion templating Polymer 2006, 47 (22) 7628-7635
32. Haibach, K.; Menner, A.; Powell, R.; Bismarck, A. Tailoring mechanical properties of highly porous polymer foams: Silica particle reinforced polymer foams via emulsion templating Polymer 2006, 47 (13) 4513-4519
33. Menner, A.; Salgueiro, M.; Shaffer, M. S. P.; Bismarck, A. Nanocomposite foams obtained by polymerization of high internal phase emulsions J. Polym. Sci., Part A: Polym. Chem. 2008, 46 (16) 5708-5714
34. Wu, R.; Menner, A.; Bismarck, A. Tough interconnected polymerized medium and high internal phase emulsions reinforced by silica particles J. Polym. Sci., Part A: Polym. Chem. 2010, 48 (9) 1979-1989
35. Lépine, O.; Birot, M.; Deleuze, H. Elaboration of open-cell microcellular nanocomposites J. Polym. Sci., Part A: Polym. Chem. 2007, 45 (18) 4193-4203
36. Youssef, C.; Backov, R.; Treguer, M.; Birot, M.; Deleuze, H. Preparation of remarkably tough polyHIPE materials via polymerization of oil-in-water HIPEs involving 1-vinyl-5-aminotetrazole J. Polym. Sci., Part A: Polym. Chem. 2010, 48 (13) 2942-2947
37. Kovacic, S.; Jerabek, K.; Krajnc, P.; Slugovc, C. Ring opening metathesis polymerisation of emulsion templated dicyclopentadiene giving open porous materials with excellent mechanical properties Polym. Chem. 2012, 3 (2) 325-328
38. Lakes, R. Materials with structural hierarchy Nature 1993, 361 (6412) 511-515
39. Berman, G. S. Structural Steel Design and Construction; Greyhawk North America, LLC: Melville, NY, 2011; pp 13-37.
40. Carn, F.; Colin, A.; Achard, M. F.; Deleuze, H.; Sellier, E.; Birot, M.; Backov, R. Inorganic monoliths hierarchically textured via concentrated direct emulsion and micellar template J. Mater. Chem. 2004, 14, 1370-1376
41. Gross, A. F.; Nowak, A. P. Hierarchical carbon foams with independently tunable mesopore and macropore size distributions Langmuir 2010, 26 (13) 11378-11383
42. Li, Z.; Wei, X.; Ming, T.; Wang, J.; Ngai, T. Dual templating synthesis of hierarchical porous silica materials with three orders of length scale Chem. Commun. 2010, 46 (46) 8767-8769
43. Schwab, M. G.; Senkovska, I.; Rose, M.; Koch, M.; Pahnke, J.; Jonschker, G.; Kaskel, S. MOF@PolyHIPEs Adv. Eng. Mater. 2008, 10 (12) 1151-1155
44. Zhang, H.; Cooper, A. I. Emulsion-templated hierarchically porous silica beads using silica nanoparticles as building blocks Ind. Eng. Chem. Res. 2005, 44 (23) 8707-8714
45. Manley, S. S.; Graeber, N.; Grof, Z.; Menner, A.; Hewitt, G. F.; Stepanek, F.; Bismarck, A. New insights into the relationship between internal phase level of emulsion templates and gas-liquid permeability of interconnected macroporous polymers Soft Matter 2009, 5 (23) 4780-4787
46. Queslel, J. P.; Mark, J. E. Elasticity, Rubber-like; John Wiley and Sons, Inc.: Hoboken, NJ, 2002; p 221.
47. Rinde, J. A. Poisson's ratio for rigid plastic foams J. Appl. Polym. Sci. 1970, 14 (8) 1913-1926
48. Menner, A.; Bismarck, A. New evidence for the mechanism of the pore formation in polymerising high internal phase emulsions or why polyHIPEs have an interconnected pore network structure Macromol. Symp. 2006, 242 (1) 19-24