Emulsion-templated hierarchically porous silica beads using silica nanoparticles as building blocks

Industrial and Engineering Chemistry Research

Volumn 44, Issue 23, 2005, Pages 8707-8714

  Zhang, Haifei ^a   Cooper, Andrew I ^a  

^a UNIVERSITY OF LIVERPOOL   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

COMPOSITE MATERIALS; POROUS MATERIALS; TITANIUM OXIDES;

COMPOSITE BEADS; SILICA NANOPARTICLES; SURFACE AREA;

SILICA;

NANOPARTICLE;

EID: 28444442660     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0502988     Document Type: Review

References (22)

1. Cameron, N. R.; Sherrington, D. C. High Internal Phase Emulsions (HIPEs) - Structure, Properties and Use in Polymer Preparation. Adv. Polym. Sci. 1996, 126, 163.
2. Ruckenstein, E. Concentrated Emulsion Polymerization. Adv. Polym. Sci. 1997, 127, 1.
3. Imhof, A.; Pine, D. J. Ordered Macroporous Materials by Emulsion Templating. Nature 1997, 389, 948.
4. Zhang, H.; Cooper, A. I. Synthesis of Monodisperse Emulsion-Templated Polymer Beads by Oil-in-Water-in-Oil (O/W/O) Sedimentation Polymerization. Chem. Mater. 2002, 14, 4017.
5. Ruckenstein, E.; Hong, L. Sedimentation Polymerization. Polymer 1995, 36, 2857.
6. Bhumgara, Z. Polyhipe Foam Materials as Filtration Media. Filtr. Sep. 1995, 32, 245.
7. Mercier, A.; Deleuze, H.; Maillard, B.; Mondain-Monval, O. Synthesis and Application of an Organotin Functionalised Highly Porous Emulsion-Derived Foam. Adv. Synth. Catal. 2002, 344, 33.
8. Chemin, A.; Mercier, A.; Deleuze, H.; Maillard, B.; Mondain-Monval, O. The Preparation and Use of PolyHIPE-Grafted Reactants to Reduce Alkyl Halides under Free-Radical Conditions. J. Chem. Soc., Perkin Trans. 1 2001, 366.
9. Busby, W.; Cameron, N. R.; Jahoda, C. A. B. Emulsion-derived (PolyHIPE) Foams Containing Poly(∈-caprolactone) as Matrixes for Tissue Engineering. Biomacromolecules 2001, 2, 154.
10. Zhang, H.; Hardy, G. C.; Rosseinsky, M. J.; Cooper, A. I. Uniform Emulsion-Templated Silica Beads with High Pore Volume and Hierarchical Porosity. Adv. Mater. 2003, 15, 78.
11. 2 Network Structures Using a Polymer Gel Coating Technique. Chem. Mater. 2001, 13, 1114.
12. Maekawa, H.; Esquena, J.; Bishop, S.; Solans, C.; Chmelka, B. E. Meso/Macroporous Inorganic Oxide Monoliths from Polymer Foams. Adv. Mater. 2003, 15, 591.
13. Zhang, H.; Hardy, G. C.; Khimyak, Y. Z.; Rosseinsky, M. J.; Cooper, A. I. Synthesis of Hierarchically Porous Silica and Metal Oxide Beads Using Emulsion-Templated Polymer Scaffolds. Chem. Mater. 2004, 16, 4245.
14. Zhang, B.; Davis, S. A.; Mann, S. Starch Gel Templating of Spongelike Macroporous Silicalite Monoliths and Mesoporous Films. Chem. Mater. 2002, 14, 1369.
15. Breulmann, M.; Davis, S. A.; Mann, S.; Hentze, H.; Antonietti, M. Polymer-Gel Templating of Porous Inorganic Macro-Structures Using Nanoparticle Building Blocks. Adv. Mater. 2000, 12, 502.
16. Shchukin, D. G.; Caruso, R. A. Template Synthesis of Porous Gold Microspheres. Chem. Commun. 2003, 1478.
17. Meldrum, F. C.; Seshadri, R. Porous Gold Structures through Templating by Echinoid Skeletal Plates. Chem. Commun. 2000, 29.
18. Zhang, H.; Hussain, I.; Brust, M.; Cooper, A. I. Emulsion-Templated Gold Beads Using Gold Nanoparticles as Building Blocks. Adv. Mater. 2004, 16, 27.
19. 2-in-Water Emulsions. J. Am. Chem. Soc. 2003, 125, 14473.
20. Shotton, D.; White, N. Confocal Scanning Microscopy: Three-Dimensional Biological Imaging. Trends Biochem. Sci. 1989, 14, 435.
21. Herold, D. M.; Das, I. J.; Stobbe, C. C.; Iyer, R. V.; Chapman, J. D. Gold Microspheres: a Selective Technique for Producing Biologically Effective Dose Enhancement. Int. J. Radiat. Biol. 2000, 76, 1357.
22. The gold nanoparticle solution was provided by Mr. I. Hussain.