A SAXS study of aggregation in the synergistic TBP-HDBP solvent extraction system

Journal of Physical Chemistry B

Volumn 117, Issue 19, 2013, Pages 5916-5924

  Ellis, Ross J ^a   Anderson, Timothy L ^b   Antonio, Mark R ^a   Braatz, Alex ^b   Nilsson, Mikael ^b  

^a ARGONNE NATIONAL LABORATORY   (United States)

^b University of California at Irvine   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FOURIER TRANSFORMS; MORPHOLOGY; SOLUTIONS; SOLVENT EXTRACTION; TRICHLOROETHYLENE;

ACIDIC AQUEOUS SOLUTION; EXTRACTANT CONCENTRATION; GENERALIZED INDIRECT FOURIER TRANSFORMATION METHODS; LIQUID-LIQUID EXTRACTION; SMALL ANGLE X-RAY SCATTERING; SOLVENT EXTRACTION SYSTEM; SYNERGISTIC EXTRACTION; TRI-N-BUTYL PHOSPHATE;

AGGREGATES;

EID: 84878086978     PISSN: 15206106     EISSN: 15205207     Source Type: Journal    
DOI: 10.1021/jp401025e     Document Type: Article

References (68)

1. Grodowska, K.; Parczewski, A. Organic Solvents in the Pharmaceutical Industry Acta Pol. Pharm. 2010, 67, 3-12
2. Bernardis, F. L.; Grant, R. A.; Sherrington, D. C. A Review of Methods of Separation of the Platinum-Group Metals through their Chloro-Complexes React. Funct. Polym. 2005, 65, 205-217
3. Tasker, P. A.; Plieger, P. G.; West, L. C. In Comprehensive Coordination Chemistry II; Ward, M. D., Ed.; Elsevier Ltd.: New York, 2004; Vol. 9, pp 759-808.
4. Bautista, R. G. In Handbook on the Physics and Chemistry of Rare Earths; Gschneidner, K. A.; Eyring, L., Eds.; North-Holland: Amsterdam, The Netherlands, 1995; Vol. 21, pp 1-27.
5. Musikas, C.; Schulz, W. W.; Liljenzin, J.-O. In Solvent Extraction Principles and Practice, 2 nd ed.; Rydberg, J., Ed.; Marcel Dekker, Inc.: New York, 2004; pp 507-557.
6. Ramakrishna, V. V.; Patil, S. K. Synergic Extraction of Actinides Struct. Bonding (Berlin) 1984, 56, 35-90
7. Kolarik, Z. Interactions of Acidic Organophosphorus Extractants in the Organic Phase Solvent Extr. Rev. 1971, 1, 1-62
8. Kassierer, E. F.; Kertes, A. S. Displacement of Water in Synergic Extraction Systems J. Inorg. Nucl. Chem. 1972, 34, 778-780
9. Marcus, Y.; Kertes, A. S. Ion Exchange and Solvent Extraction of Metal Complexes; Wiley-Interscience: London, UK, 1969.
10. Irving, H.; Edgington, D. N. Synergic Effects in the Solvent Extraction of the Actinides. I. Uranium(VI) J. Inorg. Nucl. Chem. 1960, 15, 158-170
11. Irving, H. M. N. H. Synergism in the Solvent Extraction of Metal Chelates Solvent Extr. Chem., Proc. Int. Conf. 1967, 91-110
12. Zangen, M. Some Aspects of Synergism in Solvent Extraction. II. Some Di-, Tri-and Tetravalent Metal Ions J. Inorg. Nucl. Chem. 1963, 25, 1051-1063
13. Dyrssen, D.; Kuca, L. The Extraction of Uranium(VI) with DBP in the Presence of TBP. The Synergic Effect: Substitution or Addition? Acta Chem. Scand. 1960, 14, 1945-1956
14. Shmidt, O. V.; Zilberman, B. Y.; Fedorov, Y. S.; Palenik, Y. V.; Goletskii, N. D.; Stepanov, A. I. Effect of TBP on Extraction of REE and TPE from Nitric Acid Solutions with Dibutylphosphoric Acid and Its Zirconium Salt Radiochemistry (Moscow, Russ. Fed.) 2003, 45, 596-601
15. Hagstrom, I.; Spjuth, L.; Enarsson, A.; Liljenzin, J. O.; Skalberg, M.; Hudson, M. J.; Iveson, P. B.; Madic, C.; Cordier, P. Y.; Hill, C.; Francois, N. Synergistic Solvent Extraction of Trivalent Americium and Europium by 2-Bromodecanoic Acid and Neutral Nitrogen-Containing Reagents Solvent Extr. Ion Exch. 1999, 17, 221-242
16. Hahn, H. T.; Wall, E. M. V. Complex Formation in the Dilute Uranyl Nitrate-Nitric Acid-Dibutyl Phosphoric Acid(DBP)-Tributyl Phosphate(TBP)-Amsco System J. Inorg. Nucl. Chem. 1964, 26, 191-202
17. Choppin, G. R.; Khankhasayev, M. K.; Plendl, H. S., Eds. Chemical Separations in Nuclear Waste Management: The State of the Art and a Look to the Future. (Papers presented at an International Workshop held in Prague, Sept 11, 2000); Battelle Press: Columbus, OH, 2002.
18. Fedorov, Y. S.; Zilberman, B. Y.; Kulikov, S. M.; Blazheva, I. V.; Mishin, E. N.; Wallwork, A. L.; Denniss, I. S.; May, I.; Hill, N. J. Uranium(VI) Extraction by TBP in the Presence of HDBP Solvent Extr. Ion Exch. 1999, 17, 243-257
19. May, I.; Taylor, R. J.; Wallwork, A. L.; Hastings, J. J.; Fedorov, Y. S.; Zilberman, B. Y.; Mishin, E. N.; Arkhipov, S. A.; Blazheva, I. V.; Poverkova, L. Y.; Livens, F. R.; Charnock, J. M. The Influence of Dibutylphosphate on Actinide Extraction by 30% Tributylphosphate Radiochim. Acta 2000, 88, 283-290
20. Liem, D. H. Synergistic Effect in the Extraction of Uranium-233(VI) by Dibutylphosphate (HDBP) in the Presence of Tributylphosphate (TBP) or Trioctylphosphine Oxide (TOPO) in Hexane and Carbon Tetrachloride Acta Chem. Scand. 1968, 22, 773-790
21. Liem, D. H.; Dryssen, D. Synergistic Effect on the Extraction of 233U(VI) by Dibutylphosphate (DBP) and Tributyl Phosphate (TBP) or Trioctylphosphene Oxide (TOPO) Acta Chem. Scand. 1966, 20, 272-274
22. Rydberg, J.; Musikas, C.; Choppin, G. R., Eds. Principles and Practices of Solvent Extraction; Marcel Dekker, Inc: New York, 1992.
23. Ellis, R. J.; Meridiano, Y.; Chiarizia, R.; Berthon, L.; Muller, J.; Couston, L.; Antonio, M. R. Periodic Behavior of Lanthanide Coordination within Reverse Micelles Chem.-Eur. J. 2013, 19, 2663-2675
24. Ekwall, P.; Stenius, P. In International Review of Science, Physical Chemistry, Series Two; Kerker, M., Ed.; Butterworth: London, UK, 1975; Vol. 7, pp 215-248.
25. Eicke, H.-F. Surfactants in Nonpolar Solvents: Aggregation and Micellization Top. Curr. Chem. 1980, 87, 85-145
26. Eicke, H. F. Aggregation in Surfactant Solutions: Formation and Properties of Micelles and Microemulsions Pure Appl. Chem. 1980, 52, 1349-1357
27. Eicke, H. F. Properties of Amphiphilic Electrolytes in Nonpolar Solvents Pure Appl. Chem. 1981, 53, 1417-1424
28. Eicke, H. F.; Markovic, Z. Temperature-Dependent Coalescence in Water-Oil Microemulsions and Phase Transitions to Lyotropic Mesophases J. Colloid Interface Sci. 1981, 79, 151-158
29. 3, TBP-n -Dodecane System Langmuir 2003, 19, 9592-9599
30. Nave, S.; Mandin, C.; Martinet, L.; Berthon, L.; Testard, F.; Madic, C.; Zemb, T. Supramolecular Organisation of Tri-n -Butyl Phosphate in Organic Diluent on Approaching Third Phase Transition Phys. Chem. Chem. Phys. 2004, 6, 799-808
31. Sharma, S. C.; Shrestha, R. G.; Shrestha, L. K.; Aramaki, K. Viscoelastic Wormlike Micelles in Mixed Nonionic Fluorocarbon Surfactants and Structural Transition Induced by Oils J. Phys. Chem. B 2009, 113, 1615-1622
32. Shrestha, L. K.; Shrestha, R. G.; Aramaki, K. Intrinsic Parameters for the Structure Control of Nonionic Reverse Micelles in Styrene: SAXS and Rheometry Studies Langmuir 2011, 27, 5862-5873
33. Shrestha, L. K.; Yamamoto, M.; Arima, S.; Aramaki, K. Charge-Free Reverse Wormlike Micelles in Nonaqueous Media Langmuir 2011, 27, 2340-2348
34. Gaonkar, A. G.; Neuman, R. D. Interfacial Activity, Extractant Selectivity, and Reversed Micellization in Hydrometallurgical Liquid/Liquid Extraction Systems J. Colloid Interface Sci. 1987, 119, 251-261
35. Neuman, R. D.; Zhou, N.; Wu, J.; Jones, M. A.; Gaonkar, A. G.; Park, S. J.; Agrawal, M. L. General Model for Aggregation of Metal-Extractant Complexes in Acidic Organophosphorus Solvent Extraction Systems Sep. Sci. Technol. 1990, 25, 1655-1674
36. Zhou, N. F.; Wu, J.; Sarathy, P. K.; Liu, F.; Neuman, R. D. Comparison of Aggregates Formed by Acidic Organophosphorous Extractants and Metals (Nickel and Cobalt) in Solvent Extraction Process Metall. 1992, 7A, 165-170
37. Ben, A. I.; Ober, R.; Nakache, E.; Williams, C. E. A Small Angle X-ray Scattering Investigation of the Structure of a Ternary Water-in-Oil Microemulsion Colloids Surf. 1992, 69, 87-97
38. Diamond, H.; Thiyagarajan, P.; Horwitz, E. P. Small Angle Neutron Scattering Studies of Praseodymium-CMPO Polymerization Solvent Extr. Ion Exch. 1990, 8, 503-513
39. Antonio, M. R.; Chiarizia, R.; Gannaz, B.; Berthon, L.; Zorz, N.; Hill, C.; Cote, G. Aggregation in Solvent Extraction Systems Containing a Malonamide, a Dialkylphosphoric Acid and Their Mixtures Sep. Sci. Technol. 2008, 43, 2572-2605
40. Gannaz, B.; Chiarizia, R.; Antonio, M. R.; Hill, C.; Cote, G. Extraction of Lanthanides(III) and Am(III) by Mixtures of Malonamide and Dialkylphosphoric Acid Solvent Extr. Ion Exch. 2007, 25, 313-337
41. Osseo-Asare, K. Aggregation, Reversed Micelles, and Microemulsions in Liquid-Liquid-Extraction-The Tri-Normal-Butyl Phosphate-Diluent-Water- Electrolyte System Adv. Colloid Interface Sci. 1991, 37, 123-173
42. Osseo-Asare, K. In Metal Separation Technologies Beyond 2000: Integrating Novel Chemistry with Processing; Liddell, K. C.; Chaiko, D. J., Eds.; Minerals, Metals & Materials Soc.: Warrendale, PA, 1999; pp 339-346.
43. 3/TBP-n -Dodecane System Sep. Sci. Technol. 2003, 38, 3313-3331
44. 3-TBP, n -Dodecane System Solvent Extr. Ion Exch. 2003, 21, 1-27
45. 3, TBP-n -Octane System with Baxter's ″Sticky Spheres″ Model Solvent Extr. Ion Exch. 2004, 22, 325-351
46. Chiarizia, R.; Jensen, M. P.; Rickert, P. G.; Kolarik, Z.; Borkowski, M.; Thiyagarajan, P. Extraction of Zirconium Nitrate by TBP in n -Octane: Influence of Cation Type on Third Phase Formation According to the "Sticky Spheres" Model Langmuir 2004, 20, 10798-10808
47. Erlinger, C.; Belloni, L.; Zemb, T.; Madic, C. Attractive Interactions Between Reverse Aggregates and Phase Separation in Concentrated Malonamide Extractant Solutions Langmuir 1999, 2290-2300
48. Putnam, C. D.; Hammel, M.; Hura, G. L.; Tainer, J. A. X-ray Solution Scattering (SAXS) Combined with Crystallography and Computation: Defining Accurate Macromolecular Structures, Conformations and Assemblies in Solution Q. Rev. Biophys. 2007, 40, 191-285
49. Chen, S. H. Small Angle Neutron Scattering Studies of the Structure and Interaction in Micellar and Microemulsion Systems Annu. Rev. Phys. Chem. 1986, 37, 351-399
50. Anderson, T. L.; B., A.; Ellis, R. J.; Antonio, M. R.; Nilsson, M. Synergistic Extraction of Dysprosium and Aggregate Formation in Solvent Extraction Systems Combining TBP and HDBP Solvent Extr. Ion Exch. 2013, 10.1080/07366299.2013.787023
51. Dourdain, S.; Hofmeister, I.; Pecheur, O.; Dufreche, J. F.; Turgis, R.; Leydier, A.; Jestin, J.; Testard, F.; Pellet-Rostaing, S.; Zemb, T. Synergism by Coassembly at the Origin of Ion Selectivity in Liquid-Liquid Extraction Langmuir 2012, 28, 11319-11328
52. Partridge, J. A.; Jensen, R. C. Purification of Bis(2-Ethylhexyl) Hydrogen Phosphate by Precipitation of Copper(II) Bis(2-Ethylhexyl) Phosphate J. Inorg. Nucl. Chem. 1969, 31, 2587-2589
53. Seifert, S.; Winans, R. E.; Tiede, D. M.; Thiyagarajan, P. Design and Performance of a ASAXS (Anomalous Small Angle X-ray Scattering) Instrument at the Advanced Photon Source J. Appl. Crystallogr. 2000, 33, 782-784
54. Meridiano, Y.; Berthon, L.; Crozes, X.; Sorel, C.; Dannus, P.; Antonio, M. R.; Chiarizia, R.; Zemb, T. Aggregation in Organic Solutions of Malonamides: Consequences for Water Extraction Solvent Extr. Ion Exch. 2009, 27, 607-637
55. Guinier, A.; Fournet, G. Small-Angle Scattering of X-rays; Wiley: New York, 1955.
56. 5 Mixtures and Microemulsions with n -Octane J. Chem. Phys. 1999, 110, 10623-10632
57. Fritz, G.; Bergmann, A.; Glatter, O. Evaluation of Small-Angle Scattering Data of Charged Particles Using the Generalized Indirect Fourier Transformation Technique J. Chem. Phys. 2000, 113, 9733-9740
58. Glatter, O.; Fritz, G.; Lindner, H.; Brunner-Popela, J.; Mittelbach, R.; Strey, R.; Egelhaaf, S. U. Nonionic Micelles near the Critical Point: Micellar Growth and Attractive Interaction Langmuir 2000, 16, 8692-8701
59. Percus, J. K.; Yevick, G. J. Analysis of Classical Statistical Mechanics by Means of Collective Coordinates Phys. Rev. 1958, 110, 1-13
60. Chiarizia, R.; Briand, A.; Jensen, M. P.; Thiyagarajan, P. SANS Study of Reverse Micelles Formed upon the Extraction of Inorganic Acids by TBP in n -Octane Solvent Extr. Ion Exch. 2008, 26, 333-359
61. Barker, J. A.; Henderson, D. Perturbation Theory and Equation of State for Fluids. II. A Successful Theory of Liquids J. Chem. Phys. 1967, 47, 4714-4721
62. Fritz, G.; Glatter, O. Structure and Interaction in Dense Colloidal Systems: Evaluation of Scattering Data by the Generalized Indirect Fourier Transformation Method J. Phys.: Condens. Matter 2006, 18, S2403-S2419
63. Shrestha, L. K.; Sato, T.; Dulle, M.; Glatter, O.; Aramaki, K. Effect of Lipophilic Tail Architecture and Solvent Engineering on the Structure of Trehalose-Based Nonionic Surfactant Reverse Micelles J. Phys. Chem. B 2010, 114, 12008-12017
64. Glatter, O. In Neutrons, X-Rays and Light; Lindner, P.; Zemb, T., Eds.; Elsevier Science B.V.: Amsterdam, The Netherlands, 2002; pp 73-102.
65. Glatter, O. The Interpretation of Real-Space Information from Small-Angle Scattering Experiments J. Appl. Crystallogr. 1979, 12, 166-175
66. Osseo-Asare, K. Enhanced Solvent Extraction with Water-in-Oil Microemulsions Sep. Sci. Technol. 1988, 23, 1269-1284
67. du Preez, J. G. H.; Sumter, N. M.; Viviers, C.; Rohwer, H. E.; van Brecht, B. J. A. M. In Emerging Separation Technologies for Metals II; Bautista, R. G., Ed.; The Minerals, Metals & Materials Society: Warrendale, PA, 1996; pp 265-278.
68. Laing, M. In Coordination Chemistry. A Century of Progress; Kauffman, G. B., Ed.; ACS Symp. Series 565; American Chemical Society: Washington, DC, 1994; Vol. 565, pp 382-394.