Synergism by coassembly at the origin of ion selectivity in liquid-liquid extraction

Langmuir

Volumn 28, Issue 31, 2012, Pages 11319-11328

  Dourdain, S ^a   Hofmeister, I ^a   Pecheur, O ^a   Dufreche J F ^a   Turgis, R ^a   Leydier, A ^a   Jestin, J ^b   Testard, F ^c   Pellet Rostaing, S ^a   Zemb, T ^a  

^a DIF   (France)

^b CEA SACLAY   (France)

^c CNRS UMR 3299   (France)

Author keywords

[No Author keywords available]

Indexed keywords

DISTRIBUTION COEFFICIENT; FREE-ENERGY DIFFERENCE; ION SELECTIVITY; LIQUID-LIQUID EXTRACTION; MIXED AGGREGATES; SOLVENT PHASE; SYNERGISTIC MECHANISM;

FREE ENERGY; IONS; PHASE DIAGRAMS;

AGGREGATES;

EID: 84864691292     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la301733r     Document Type: Article

References (62)

1. Rydberg, J.; Cox, M.; Musikas, C.; Choppin, G. R. Solvent Extraction Principles and Practice; CRC Press: Boca Raton, FL, 2004.
2. Barnes, J. E.; Setchfield, J. H.; Williams, G. O. R. Solvent extraction with di(2-ethylhexyl)phosphoric acid; A correlation between selectivity and the structure of the complex J. Inorg. Nucl. Chem. 1976, 38 (5) 1065-1067
3. Osseo-Asare, K. Aggregation, reversed micelles, and microemulsions in liquid-liquid extraction: the tri- n-butyl phosphate-diluent-water-electrolyte system Adv. Colloid Interface Sci. 1991, 37, 123-173
4. Sarmoria, C.; Puvvada, S.; Blankschtein, D. Prediction of critical micelle concentrations of non ideal binary surfactant mixtures Langmuir 1992, 8, 2690-2697
5. Bergstroem, M.; Eriksson, J. C. A theoretical analysis of synergistic effects in mixed surfactant systems Langmuir 2000, 16, 7173-7181
6. Tanford, C. The Hydrophobic Effect, 2 nd ed.; Krieger: Malabar, FL, 1991.
7. Hurst, F. J.; Crouse, D. J.; Brown, K. B. Recovery of uranium from wet-process phosphoric acid Ind. Eng. Chem. Process Des. Dev. 1972, 11, 122-128
8. McReady, W. L.; Wethington, J. A.; Hurst, F. J. Uranium extraction from Florida phosphates Nucl. Technol. 1981, 53, 344-353
9. Hurst, F. J. The Recovery of uranium from phosphoric acid; International Atomic Energy Authority, Vienna TEC DOC 1989, 533
10. Hurst, F. J.; Crouse, D. J.; Brown, K. B. Report ORNL-TM 2522 1969, not supplied.
11. Bunus, F. T.; Domocos, V. C.; Dimitrescu, P. J. Synergic extraction of uranium from phosphate solutions with di-(2-ethylhexyl) phosphoric acid and tri- n -octylphosphine oxide Inorg. Nucl. Chem. 1978, 40, 117-121
12. Bunus, F. T.; Miu, I.; Dimitrescu, P. J. Simultaneous recovery and separation of uranium and rare earths from phosphoric acid in a one-cycle extraction-stripping process Hydrometallurgy 1994, 35, 375-389
13. Dahdouh, A.; Shlewit, H.; Khorfan, S.; Koudsi, Y. Study of factors affecting uranium stripping from DEHMA/TOPO solvent by factorial design J. Radioanal. Nucl. Chem. 1997, 221, 183-187
14. Rawajfeh, K. M.; Al-Matar, A. K. Uranium extraction from purified wet process Jordanian phosphoric acid: A development study Hydrometallurgy 2000, 56, 309-322
15. Baes, C. F. Synergistic effects in organophosphate extraction systems Nucl. Sci. Eng. 1963, 16, 405-411
16. Dyrssen, D.; Kuca, L. The Extraction of Uranium (VI) with DBP in the Presence of TBP. The "Synergic" Effect: Substitution or Addition? Acta Chem. Scand. 1960, 14, 1945-1956
17. Kennedy, J. AERE Report C/M. Harwell 1958, not supplied.
18. Irving, H. M.; Eddington, D. N. Synergic effects in solvent extraction of divalent cobalt zinc and copper J. Inorg. Nucl. Chem. 1965, 27, 1359-1363
19. Healy, T. V. Synergism in the solvent extraction of di-valent, tri-valent, and tetra-valent metal ions. 1. Synergic effects of different phosphate esters J. Inorg. Nucl. Chem. 1961, 19, 314-327
20. Gupta, C. K.; Gupta, G.; Singh, H. Uranium Resource Processing, Secondary Resources; Springer: Berlin; 2003.
21. Nigond-Berthon, L. Thèse de l'université de Clermont-Ferrand-2 1992, not supplied.
22. Nave, S.; Mandin, C.; Martinet, L.; Berthon, L.; Testard, F.; Madic, C.; Zemb, T. Supramolecular organisation of tri- n -butyl phosphate in organic diluent on approaching third phase transition Phys. Chem. Chem. Phys. 2004, 6, 799-808
23. Israelachvili, J. N.; Mitchell, D. J.; Ninham, B. W. Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers J. Chem. Soc. - Faraday Trans. 2 1976, 72, 1525-1568
24. Wennerstrom, H.; Lindman, B. Micelles, physical-chemistry of surfactant association Phys. Rep.-Rev. Sect. Phys. Lett 1979, 52, 1-86
25. Eicke, H. F. Surfactants in nonpolar solvents. Aggregation and micellization Top. Curr. Chem. 1980, 87, 85-145
26. Chevalier, Y.; Zemb, T. The structure of micelles and microemulsions Rep. Prog. Phys. 1990, 53 (3) 279-371
27. Hyde, S. W. The Language of Shape; Elsevier: Amsterdam; 1997.
28. Wennerstrom, H.; Lindman, B. Water penetration into surfactant micelles J. Phys. Chem. 1979, 83, 2931-2932
29. Erlinger, C.; Belloni, L.; Zemb, T.; Madic, C. Attractive interactions between reverse aggregates and phase separation in concentrated malonamide extractant solutions Langmuir 1999, 15, 2290-2300
30. Erlinger, C.; Gazeau, D.; Zemb, T.; Madic, C.; Lefrançois, L.; Hebrant, M.; Tondre, C. Effect of nitric acid extraction on phase behavior, microstructure and interactions between primary aggregates in the system dimethyldibutyltetradecylmalonamide (DMDBTDMA) n -dodecane water: A phase analysis and small angle X-ray scattering (SAXS) characterisation study Solvent Extr. Ion Exch. 1998, 16, 707-738
31. Verdier-Erlinger, C. Thèse de l'université Paris XI; Report CEA-R-5834 1999, not supplied.
32. Chiarizia, R.; Jensen, M. P.; Borkowski, M.; Ferraro, J. R.; Thiyagarajan, P.; Littrell, K. C. Third phase formation revisited: The U(VI), HNO3-TBP, n -dodecane system Solvent Extr. Ion. Exch. 2003, 21, 1-27
33. Chiarizia, R.; Nash, K. L.; Jensen, M. P.; Thiyagarajan, P.; Littrell, K. C. Application of the Baxter model for hard spheres with surface adhesion to SANS data for the U(VI)-HNO3, TBP- n -dodecane system Langmuir 2003, 19, 9592-9599
34. Borkowski, M.; Chiarizia, R.; Jensen, M. P.; Ferraro, J. R.; Thiyagarajan, P.; Littrell, K. C. SANS study of third phase formation in the Th(IV)-HNO3/TBP- n -octane system Sep. Sci. Technol. 2003, 38, 3333-3351
35. Chiarizia, R.; Jensen, M. P.; Borkowski, M.; Thiyagarajan, P.; Littrell, K. C. Interpretation of third phase formation in the Th(IV)-HNO3, TBP- n -octane system with Baxter's "sticky spheres" model Solvent Extr. Ion. Exch. 2004, 22, 325-351
36. Chiarizia, R.; Jensen, M. P.; Rickert, P. G.; Kolarik, Z.; Borkowski, M.; Thiyagarajan, P. Extraction of zirconium nitrate by TBP in n -octane: Influence of cation type on third phase formation according to the "sticky spheres" model Langmuir 2004, 20, 10798-10808
37. Nave, S.; Modolo, G.; Madic, C.; Testard, F. Aggregation properties of N, N, N ′, N ′-tetraoctyl-3-oxapentanediamide (TODGA) in n -dodecane Solvent Extr. Ion Exch. 2004, 22, 527-551
38. Yaita, T.; Herlinger, A. W.; Thiyagarajan, P.; Jensen, M. P. Influence of extractant aggregation on the extraction of trivalent f-element cations by a tetraalkyldiglycolamide Solvent Extr. Ion Exch. 2004, 22, 553-571
39. Jensen, M. P.; Yaita, T.; Chiarizia, R. Reverse-micelle formation in the partitioning of trivalent f-element cations by biphasic systems containing a tetraalkyldiglycolamide Langmuir 2007, 23, 4765-4774
40. Berthon, L.; Martinet, L.; Testard, F.; Madic, C.; Zemb, T. Solvent penetration and sterical stabilization of reverse aggregates based on the DIAMEX process extracting molecules: Consequences for the third phase formation Solvent Extr. Ion. Exch. 2007, 25, 545-576
41. Bauduin, P.; Testard, F.; Berthon, L.; Zemb, T. Relation between the hydrophile/hydrophobe ratio of malonamide extractants and the stability of the organic phase: investigation at high extractant concentrations Phys. Chem. Chem. Phys. 2007, 9, 3776-3785
42. Testard, F.; Bauduin, P.; Martinet, L.; Abedcassis, B.; Berthon, L.; Madic, C.; Zemb, T. Self-assembling properties of malonamide extractants used in separation processes Radiochim. Acta 2008, 96, 265-272
43. Zhou, N.; Wu, J. Review on aggregation of acid extractants in solvent extraction of metal ions: Remark on the general model Prog. Nat. Sci. 2003, 13 (1) 1-12
44. Neuman, R. D.; Jones, M. A.; Zhou, N. F. Photon correlation spectroscopy applied to hydrometallurgical solvent extraction systems Colloids Surf. 1990, 46 (1) 45-61
45. Leodidis, E. B.; Hatton, T. A. Amino acids in AOT reversed micelles. 1. Determination of interfacial partition coefficients using the phase-transfer method J. Phys. Chem. 1990, 94, 6400-6411
46. Scholten, L. C.; Timmermans, C. W. M. Natural radioactivity in phosphate fertilizers Fertil. Res. 1996, 43, 103-107
47. Zemb, T.; Tache, O.; Ne, F. A high-sensitivity pinhole camera for soft condensed matter J. Appl. Crystallogr. 2003, 36, 800-805
48. Harkins, W. E.; Brown, F. E. Determination of surface tension (free surface energy) and the weight of falling drops: The surface tension of water and benzene by the capillary height method J. Am. Chem. Soc. 1919, 41, 499-524
49. Degiorgio, V.; Corti, M.; Giglio, M. Light Scattering in Liquids and Macromolecular Solutions; Plenum Press: New York; 1980.
50. Zemb, T.; Drifford, M.; Hayoun, M.; Jehanno, A. Light scattering study of solutions of sodium octanoate micelles J. Phys. Chem. 1983, 87, 4524-4528
51. Gal, J.; Nikolic, R. M. The method of continuous variations applied to the extraction of metal ions with mixed solvents J. Inorg. Nucl. Chem. 1966, 28, 563-569
52. Hansen, J. P.; McDonald, I. R. Theory of simple liquids; Academic Press: New York, 1976.
53. Guinier, A.; Fournet, G. Small-Angle Scattering of X-rays; Wiley: New York, 1955.
54. Testard, F.; Zemb, T. Understanding solubilisation using principles of surfactant self-assembly as geometrical constraints C.R.A.S. Geosci. 2002, 334, 649-663
55. Vandegrift, G. F.; Horwitz, E. P. Interfacial activity of liquid-liquid extraction reagents 1. Dialkyl phosphorous based acids J. Inorg. Nucl. Chem. 1980, 42, 119-125
56. Kamenka, N.; Fabre, H.; Chorro, M. Influence of solubilization on conter ion binding to surfactant micelles from self-diffusion coefficients J. Chim. Phys. Phys.-Chim. Biol. 1977, 74, 510-512
57. Guilbaud, P.; Zemb, T. Solute-induced microstructural transition from weak aggregates towards a curved film of surface-active extractants Chem. Phys. Chem 2012, 13, 687-691
58. Kunz, W. Specific Ion Effects; World Scientific: River Edge, NJ, 2010.
59. Bauduin, P.; Testard, F.; Zemb, T. Solubilization in alkanes by alcohols as reverse hydrotropes or "Lipotropes" J. Phys. Chem. B 2008, 112, 12354-12360
60. Nichols, K. P.; Pompano, R. R.; Li, L.; Gelis, A. V.; Ismagilov, R. F. Toward mechanistic understanding of nuclear reprocessing chemistries by quantifying lanthanide solvent extraction kinetics via microfluidics with constant interfacial area and rapid mixing J. Am. Chem. Soc. 2011, 133, 15721-15729
61. Ricoul, F.; Dubois, M.; Belloni, L.; Zemb, T.; Rico-Lattes, I. Phase equilibria and equation of state of a mixed cationic surfactant glycolipid lamellar system Langmuir 1998, 14, 2645-2655
62. Dubois, M.; Zemb, T.; Fuller, N.; Rand, R. P.; Parsegian, V. A. Equation of state of a charged bilayer system: Measure of the entropy of the lamellar-lamellar transition in DDABr J. Chem. Phys. 1998, 108, 7855-7869