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All photophysical experiments with macrocycles 1a-f and 2a-c were performed simultaneously with magnesium complexed into the center of AzaPc instead of zinc. The data confirmed validity of the results obtained for zinc derivatives (see the Supporting Information); however, no improvement in sensitivity was brought by magnesium derivatives
-
All photophysical experiments with macrocycles 1a-f and 2a-c were performed simultaneously with magnesium complexed into the center of AzaPc instead of zinc. The data confirmed validity of the results obtained for zinc derivatives (see the Supporting Information); however, no improvement in sensitivity was brought by magnesium derivatives.
-
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14
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84877851126
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The stepwise formation of 1:1 and 1:2 complexes of the sensors with K+ was not detected in either absorption or fluorescence spectra due to very small spectral differences between these two forms. Therefore, the KD values for K+ could not be properly determined
-
The stepwise formation of 1:1 and 1:2 complexes of the sensors with K+ was not detected in either absorption or fluorescence spectra due to very small spectral differences between these two forms. Therefore, the KD values for K+ could not be properly determined.
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pKa=ä2.5 was estimated by calculation using Advanced Chemistry Development (ACD/Labs) Software V8.14
-
pKa=ä2.5 was estimated by calculation using Advanced Chemistry Development (ACD/Labs) Software V8.14.
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