Effects of repeat unit sequence distribution and residual catalyst on thermal degradation of poly(l-lactide/ε-caprolactone) statistical copolymers

Polymer Degradation and Stability

Volumn 98, Issue 7, 2013, Pages 1293-1299

  Fernandez J ^a   Etxeberria A ^b   Sarasua, J R ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

^b UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

Chain microstructure poly(lactide caprolactone); Pyrolisis; Residual metal content; Thermal degradation

Indexed keywords

BISMUTH SUBSALICYLATE; H NMR SPECTROSCOPY; LACTIDES; MICROSTRUCTURAL FEATURES; PYROLISIS; RESIDUAL METALS; SEQUENCE DISTRIBUTION; STATISTICAL COPOLYMERS;

CATALYSTS; DECOMPOSITION; MICROSTRUCTURAL EVOLUTION; PYROLYSIS; RING OPENING POLYMERIZATION; THERMOGRAVIMETRIC ANALYSIS; TIN;

COPOLYMERS;

EID: 84877815443     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2013.04.003     Document Type: Article

References (22)

1. A.P. Gupta, and V. Kumar New emerging trends in synthetic biodegradable polymers-polylactide: a critique European Polymer Journal 43 10 2007 4053 4074
2. R. Auras, B. Harte, and S. Selke An overview of polylactides as packaging materials Macromolecular Bioscience 4 2004 835 864
3. K. Pielichowski, and J. Njuguna Thermal degradation of polymeric materials 2005 Rapra Technology Limited Shawbury 1-85957-498-X
4. A. Larrañaga Effect bioactive glass particles on the thermal degradation behavior of medical polyesters Polymer Degradation and Stability 98 2013 751 758
5. K. Nalampang, R. Molloy, and W. Punyodom Synthesis and characterization of poly(L-lactide-co-ecaprolactone) copolymers: influence of sequential monomer addition on chain microstructure Polymers for Advanced Technologies 18 3 2007 240 248
6. O. Persenaire, M. Alexandre, P. Degée, and P. Dubois Biomacromolecules 2 1 2001 288 294
7. A. Draye, O. Persenaire, O. Brozek, J. Roda, T. Kosek, and Ph Dubois Thermogravimetric analysis of poly(ε-caprolactam) and poly[(ε- caprolactam)-co-(ε-caprolactone)] polymers Polymer 42 2001 8325 8332
8. Y. Aoyagi, K. Yamashita, and Y. Doi Polymer Degradation and Stability 76 1 2002 53 59
9. F.D. Kopinke, and K. Mackenzie Journal of Analytical and Applied Pyrolysis 40 41 1997 43 53
10. O. Wachsen, K. Platkowski, and K.-H. Reichert Thermal degradation of poly-L-lactide: studies on kinetics, modeling and melt stabilization Polymer Degradation and Stability 57 1997 87 94
11. G. Sivalingam, and G. Madras Thermal degradation of binary physical mixtures and copolymers of poly(ε-caprolactone), poly(D,L-lactide), poly(glycolide) Polymer Degradation and Stability 84 2004 393 398
12. F.D. Kopinke, M. Remmler, K. Mackenzie, M. Möder, and O. Wachsen Thermal decomposition of biodegradable polyesters-II. Poly(lactic acid) Polymer Degradation and Stability 53 1996 329 342
13. J. Fernández, A. Etxeberría, and J.R. Sarasua Synthesis, structure and properties of poly(L-lactide-co-ε-caprolactone) statistical copolymers Journal of The Mechanical Behavior of Biomedical Materials 9 2012 100 112
14. A. Södergard, and J.H. Näsman Melt stability study of various types of poly(L-lactide) Industrial and Engineering Chemistry Research 35 1996 732 735
15. H. Nishida, T. Mori, S. Hoshihara, Y. Fan, Y. Shirai, and T. Endo Effect of tin on poly(L-lactic acid) pyrolysis Polymer Degradation and Stability 81 2003 515 523
16. H.R. Kricheldorf, I. Kreiser-Saunders, and C. Boettcher Polylactones:31. Sn(II) octoate-initiated polymerization of L-lactide: a mechanistic study Polymer 36 1995 1253 1259
17. T. Mori, H. Nishida, Y. Shirai, and T. Endo Effects of chain end structures on pyrolysis of poly(L-lactic acid) containing tin atoms Polymer Degradation and Stability 84 2004 243 251
18. Fernandez J, Meaurio E, Chaos A, Etxeberria A, Alonso-Varona A, Sarasua JR. Synthesis and characterization of poly(L-lactide/ε-caprolactone) statistical copolymers with well resolved chain microstructures. Polymer. [Accepted for publication].
19. A. Kowalski, A. Duda, and S. Penczek Macromolecules 33 2000 7359 7370
20. J. Fernández, A. Etxeberria, J.M. Ugartemendia, S. Petisco, and J.R. Sarasua Effects of chain microstructures on mechanical behaviour and aging of poly(L-lactide-co-ε-caprolactone) biomedical thermoplastic elastomer Journal of Mechanical Behavior of Biomedical Materials 12 2012 29 38
21. I.R. Herbert Statistical analysis of copolymer sequence distribution R.N. Ibbet, NMR spectroscopy of polymers 1993 Blackie Academic & Professional London 50 79 [Chapter 2]
22. S.J. Moravek, and R.F. Storey Copolymers of rac-lactide and ε-caprolactone: Conventional copolymerization vs. Macroinitiator copolymerization Journal of Macromolecular Science 46 2009 339 345