Accessibility of acid sites in hierarchical zeolites: Quantitative IR studies of pivalonitrile adsorption

Journal of Physical Chemistry C

Volumn 117, Issue 18, 2013, Pages 9237-9244

  Sadowska, Karolina ^a   Góra Marek, Kinga ^a   Datka, Jerzy ^a  

^a JAGIELLONIAN UNIVERSITY   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

ALKALINE TREATMENT; DEHYDROXYLATIONS; EXTERNAL SURFACES; EXTINCTION COEFFICIENTS; HIERARCHICAL ZEOLITES; PROBE MOLECULES; SILICEOUS ZEOLITE; TETRABUTYLAMMONIUM HYDROXIDES;

INFRARED IMAGING; MICROPOROSITY; MOLECULES; REDOX REACTIONS;

ZEOLITES;

EID: 84877721035     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp400400t     Document Type: Article

References (26)

1. van Donk, S.; Janssen, A. H.; Bitter, J. H.; de Jong, K. P. Generation, Characterization, and Impact of Mesopores in Zeolite Catalyst Catal. Rev.: Sci. Eng. 2003, 45, 297-319
2. Pérez-Ramírez, J.; Christensen, C. H.; Egeblad, E.; Christensen, C. H.; Groen, J. C. Hierarchical Zeolites: Enhanced Utilization of Microporous Crystals in Catalysis by Advances in Materials Design Chem. Soc. Rev. 2008, 37, 2530-2542
3. Egeblad, K.; Christensen, C. H.; Kustova, M.; Christensen, C. H. Templating Mesoporous Zeolites Chem. Mater. 2008, 20, 946-960
4. Groen, J. C.; Moulijn, J. A.; Perez-Ramirez, J. Desilication: On the Controlled Generation of Mesoporosity in MFI Zeolites J. Mater. Chem. 2006, 16, 2121-2131
5. Chal, R.; Grardin, C.; Bulut, M.; van Donk, S. Overview and Industrial Assessment of Synthesis Strategies towards Zeolites with Mesopores ChemCatChem 2011, 3, 67-81
6. Groen, J. C.; Jansen, J. C.; Moulijn, J. A.; Pérez-Ramírez, J. Optimal Aluminum-Assisted Mesoporosity Development in MFI Zeolites by Desilication J. Phys. Chem. B 2004, 108, 13062-13065
7. Groen, J. C.; Peffer, L. A. A.; Moulijn, J. A.; Pérez- Ramírez, J. Aldol Condensations over Reconstructed Mg-Al Hydrotalcites: Structure-Activity Relationships Related to the Rehydration Method Chem.-Eur. J. 2005, 11, 4983-4994
8. Zhao, L.; Shen, B.; Gao, J.; Xu, C. Investigation on the Mechanism of Diffusion in Mesopore Structured ZSM-5 and Improved Heavy Oil Conversion J. Catal. 2008, 258, 228-234
9. Groen, J. C.; Sano, T.; Moulijn, J. A.; Pérez-Ramírez, J. Alkaline-Mediated Mesoporous Mordenite Zeolites for Acid-Catalyzed Conversions J. Catal. 2007, 251, 21-27
10. Gopalakrishnan, S.; Zampieri, A.; Schwieger, W. Mesoporous ZSM-5 Zeolites via Alkali Treatment for the Direct Hydroxylation of Benzene to Phenol with N2O J. Catal. 2008, 260, 193-197
11. Jin, F.; Cui, Y.; Li, Y. Effect of Alkaline and Atom-Planting Treatment on the Catalytic Performance of ZSM-5 Catalyst in Pyridine and Picolines Synthesis Appl. Catal., A 2008, 350, 71-78
12. Groen, J. C.; Peffer, L. A. A.; Moulijn, J. A.; Pérez- Ramírez, J. On the Introduction of Intracrystalline Mesoporosity in Zeolites upon Desilication in Alkaline Medium Microporous Mesoporous Mater. 2004, 69, 29-34
13. Groen, J. C.; Peffer, L. A. A.; Moulijn, J. A.; Pérez- Ramírez, J. Mesoporosity Development in ZSM-5 Zeolite upon Optimized Desilication Conditions in Alkaline Medium Colloids Surf., A 2004, 241, 53-58
14. Pérez-Ramírez, J.; Verboekend, D.; Bonilla, A.; Abelló, S. Zeolite Catalysts with Tunable Hierarchy Factor by Pore-Growth Moderators Adv. Funct. Mater. 2009, 19, 3972-3979
15. Verboekend, D.; Pérez-Ramírez, J. Desilication Mechanism Revisited: Highly Mesoporous All-Silica Zeolites Enabled through Pore-Directing Agents Chem.-Eur. J. 2011, 17, 1137-1147
16. Groen, J. C.; Hamminga, G. M.; Moulijn, J. A.; Pérez- Ramírez, J. In Situ Monitoring of Desilication of MFI-Type Zeolites in Alkaline Medium Phys. Chem. Chem. Phys. 2007, 9, 4822-4830
17. Sadowska, K.; Wach, A.; Olejniczak, Z.; Kuśtrowski, P.; Datka, J. Hierarchic Zeolites: Zeolite ZSM-5 Desilicated with NaOH and NaOH/tetrabutylamine Hydroxide Microporous Mesoporous Mater. 2013, 167, 82-88
18. Sadowska, K.; Góra-Marek, K.; Datka, J. Hierarchic Zeolites Studied by IR Spectroscopy: Acid Properties of Zeolite ZSM-5 Desilicated with NaOH and NaOH/tetrabutylamine Hydroxide Vib. Spectrosc. 2012, 63, 418-425
19. Sadowska, K.; Góra-Marek, K.; Drozdek, M.; Kuśtrowski, P.; Datka, J.; Martinez Triguero, J.; Rey, F. Desilication of Highly Siliceous Zeolite ZSM-5 with NaOH and NaOH/tetrabutylamine Hydroxide Microporous Mesoporous Mater. 2013, 168, 195-205
20. Trobmetta, M.; Busca, G.; Lenarda, M.; Storaro, L.; Pavan, M. An Investigation of the Surface Acidity of Mesoporous Al-Containing MCM-41 and of the External Surface of Ferrierite through Pivalonitrile Adsorption Appl. Catal., A 1999, 182, 225-235
21. Nesterenko, N. S.; Thibault-Starzyk, F.; Montouillout, V.; Youschnko, V. V.; Fernandez, C.; Gilson, J.-P.; Fajula, F.; Ivanova, I. I. Accessibility of the Acid Sites in Dealuminated Small-Port Mordenites Studied by FTIR of Co-Adsorbed Alkylpyridines and CO Microporous Mesoporous Mater. 2004, 71, 157-166
22. Thibault-Starzyk, F.; Stan, I.; Abelló, S.; Bonilla, A.; Thomas, K.; Fernandez, C.; Gilson, J.-P.; Pérez-Ramírez, J. Quantification of Enhanced Acid Site Accessibility in Hierarchical Zeolites-the Accessibility Index J. Catal. 2009, 264, 11-14
23. Góra-Marek, K.; Datka, J. IR Studies of OH Groups in Mesoporous Aluminosilicates Appl. Catal., A 2006, 302, 104-109
24. Holm, M. S.; Svelle, S.; Joensen, F.; Beato, P.; Christensen, C. H.; Bordiga, S.; Bjørgen, M. Assessing the Acid Properties of Desilicated ZSM-5 by FTIR Using CO and 2,4,6-Trimethylpyridine (Collidine) As Molecular Probes Appl. Catal., A 2009, 356, 23-30
25. Góra-Marek, K.; Derewiński, M.; Datka, J.; Sarv, P. IR and NMR Studies of Mesoporous Alumina and Related Aluminosilicates Catal. Today 2005, 101, 131-138
26. Góra-Marek, K.; Palomares, A. E.; Glanowska, A.; Sadowska, K.; Datka, J. Copper Sites in Zeolites-Quantitative IR Studies Microporous Mesoporous Mater. 2012, 162, 175-180