Photocatalytic conversion of gaseous nitrogen trichloride into available chlorine - Experimental and modeling study

Environmental Science and Technology

Volumn 47, Issue 9, 2013, Pages 4628-4635

  Gerardin F ^a   Cloteaux, A ^a,b   Guillemot, M ^a   Faure, M ^a,b   Andre J C ^b  

^a INSTITUT NATIONAL DE RECHERCHE ET DE SÉCURITÉ   (France)

^b UNIVERSITÉ DE LORRAINE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CONTROLLED DEGRADATION; DISINFECTION BY-PRODUCT; LABORATORY CONDITIONS; LANGMUIR-HINSHELWOOD MODELS; NITROGEN TRICHLORIDES; PHOTOCATALYTIC OXIDATIONS; PHOTOCATALYTIC PROCESS; TECHNICAL SOLUTIONS;

BYPRODUCTS; CHLORINE; DISINFECTION; NITROGEN; PHOTOCATALYSIS; PHOTOLYSIS; WATER RECYCLING;

CHLORINE COMPOUNDS;

CHLORINE; HYDROGEN; NITROGEN; NITROGEN CHLORIDE; UNCLASSIFIED DRUG;

CATALYSIS; CHLORIDE; DISINFECTION; EXPERIMENTAL STUDY; LABORATORY METHOD; NITROGEN COMPOUND; NUMERICAL MODEL; PHOTOOXIDATION; QUANTUM MECHANICS; WATER POLLUTION;

ARTICLE; BIOREACTOR; DIFFUSION; DISINFECTION; GAS; KINETICS; OXIDATION; PHOTOCATALYSIS; PHOTOLYSIS; QUANTUM CHEMISTRY;

CATALYSIS; CHLORIDES; GASES; MODELS, CHEMICAL; NITROGEN COMPOUNDS; PHOTOCHEMICAL PROCESSES;

EID: 84877626950     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es400588m     Document Type: Article

References (28)

1. Guidelines for the Safe Recreational Water Environments, Vol. 2, Swimming Pools and Similar Environments; World Health Organization (WHO), 2006.
2. Weaver, W. A.; Li, J.; Wen, Y.; Johnston, J.; Blatchley, M. R.; Blatchley, E. R., III Volatile disinfection by-product analysis from chlorinated indoor swimming pools Water Res. 2009, 43, 3308-3318
3. Holzwartz, G.; Balmer, R. G.; Sony, L. The rate of chlorine and chloramines in cooling towers. Henry's law constants for flashoff Water Res. 1984, 18, 1421-1427
4. Héry, M.; Hecht, G.; Gerber, J. M.; Gendre, J. C.; Hubert, G.; Blachère, V.; Rebuffaud, J.; Dorotte, M. Exposition aux chloramines dans les atmosphères des halls de piscine INRS-Cahiers de Notes Documentaires 1994, 156, 285-292
5. Héry, M.; Hecht, G.; Gerber, J. M.; Gendre, J. C.; Hubert, G.; Rebuffaud, J. Exposure to chloramines in the atmosphere of indoor swimming pools Ann. Occup. Hyg. 1995, 39, 427-439
6. Héry, M.; Gerber, J. M.; Hecht, G.; Subra, I.; Possoz, C.; Dieudonné, M.; André, J. C. Exposure to chloramines in a green salad processing plant Ann. Occup. Hyg. 1998, 42, 437-451
7. Gérardin, F.; Gerber, J. M.; Héry, M.; Quenis, B. Extraction de chloramines par contact gaz/liquide dans les eaux de piscines INRS-Cahiers de Notes Documentaires 1999, 177, 21-29
8. Gérardin, F.; Gagnaire, F.; Hecht, G.; Héry, M.; Hubert, G.; Massin, N.; Subra, I. Réduction de l'exposition des travailleurs au trichlorure d'azote dans deux secteurs d'activités par action sur les procédés-synthèse INRS-Cahiers de Notes Documentaires 2005, 201, 9-18
9. Alberici, R. M.; Jardim, W. F. Photocatalytic destruction of VOCs in the gas-phase using titanium dioxide Appl. Catal., B 1997, 14, 55-68
10. Gilbert, J. V.; Wu, X. L.; Stedman, D. H.; Coombe, R. D. Photolysis of nitrogen trichloride J. Phys. Chem. 1987, 91 (16) 4265-4269
11. 3 at 193 and 249 nm J. Phys. Chem. 2002, 106 (36) 8422-8426
12. Briggs, A. G.; Norrish, R. G. The decomposition of nitrogen trichloride photosensitized by chlorine Proc. R. Soc. London 1964, 278, 27-34
13. 3 free radicals using time-resolved absorption spectrophotometry Trans. Faraday Soc. 1969, 65, 2994-3004
14. 2 impregnated surfaces. Ph.D. Dissertation, Georgia Institute of Technology, 2010.
15. Jafvert, C. T.; Valentine, R. L. Reactional scheme for the chlorination of ammoniacal water Environ. Sci. Technol. 1992, 26, 577-586
16. Ozekin, K.; Valentine, R. L.; Vikesland, P. J. Modeling the decomposition of disinfecting residuals of chloramines. In Water Disinfection and Natural Organic Matter: Characterization and Control; Minear, R.; Amy, G., Eds.; American Chemical Society: Washington, DC, 1996; pp 115-125.
17. Gérardin, F.; Subra, I. Mise au point d'une méthode de prélèvement et d'analyse du trichlorure d'azote en phase aqueuse INRS-Cahiers de Notes Documentaires 2004, 194, 39-50
18. Villermaux, J. Génie de la réaction chimique-Conception et fonctionnement des réacteurs, 2 nd ed.; Tec & Doc-Lavoisier: Paris, France, 1993.
19. Perry, R. H.; Green, D. W. Perry's Chemical Engineer's Handbook, 7 th ed.; McGraw-Hill: New York, 1997.
20. Assadi, A. A.; Bouzaza, A.; Wolbert, D. Photocatalytic oxidation of trimethylamine and isovaleraldehyde in an annular reactor: Influence of the mass transfer and the relative humidity J. Photochem. Photobiol., A 2012, 236, 61-69
21. Czech, F. W.; Fuchs, R. J.; Henry, F. A. Determination of mono-, di-, and trichloramine by ultraviolet absorption spectrometry Anal. Chem. 1961, 33 (6) 705-707
22. Standard Methods for the Examination of Water and Wastewater, 9 th ed.; APHA-AWWA-WEF: Washington, DC, 1995.
23. Zall, D. M.; Fisher, D.; Garner, M. Q. Photometric determination of chloride in water Anal. Chem. 1956, 28, 1665-1668
24. Rubtsov, N. M. Kinetic mechanism and chemical oscillations in the branching chain decomposition of nitrogen trichloride Mendeleev Commun. 2001, 8 (5) 173-175
25. Van Dam, M. H. H.; Corriou, J. P.; Midoux, N.; Lamine, A. S.; Roizard, C. Modeling and measurement of sulfur dioxide absorption rate in a laminar falling film reactor Chem. Eng. Sci. 1999, 54, 5311-5318
26. 2 configurations) J. Photochem. Photobiol., A 2011, 222 (2-3) 323-329
27. André, J. C.; D'Allest, J. F. Industrial photochemistry. VIII: Light repartition in heterogeneous cylindrical photoreactors J. Photochem. 1987, 36 (2) 221-234
28. Vogt, R.; Schindler, R. N. Product channels in the photolysis of HClO J. Photochem. Photobiol., A 1992, 66, 133-140