Catalytic, enantioselective, intramolecular carbosulfenylation of olefins

Journal of the American Chemical Society

Volumn 135, Issue 17, 2013, Pages 6419-6422

  Denmark, Scott E ^a   Jaunet, Alex ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC NUCLEOPHILES; ARYL-SUBSTITUTED ALKENES; ENANTIOMERIC RATIO; ENANTIOSELECTIVE; TETRAHYDRONAPHTHALENES;

HYDROCARBONS;

ENANTIOSELECTIVITY;

ALKENE; NUCLEOPHILE; TETRALIN DERIVATIVE;

ARTICLE; CATALYSIS; ENANTIOMER; ENANTIOSELECTIVITY; STEREOSPECIFICITY; SUBSTITUTION REACTION;

ALKENES; CATALYSIS; INDICATORS AND REAGENTS; STEREOISOMERISM; SULFUR; TETRAHYDRONAPHTHALENES;

EID: 84877082727     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja401867b     Document Type: Article

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46. 1H NMR chemical shifts of HC(3) with known products trans-2a and cis-2a.(6, 18) The absolute configuration of (-)- trans-3k was determined to be (1 R,2 R) by X-ray crystallographic analysis of the derived sulfone trans-12. The crystallographic coordinates of trans-12 have been deposited with the Cambridge Crystallographic Data Centre; deposition no. 913987. These data can be obtained free of charge via from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44) 1223-336-033; via www.ccdc.cam.ac.uk/conts/retrieving.html or deposit@ccdc.cam.ac.uk.