Modeling of the carbonation kinetics of a synthetic CaO-based sorbent

Chemical Engineering Science

Volumn 95, Issue , 2013, Pages 283-290

  Zhou, Zhiming ^a   Xu, Pan ^a   Xie, Miaomiao ^a   Cheng, Zhenmin ^a   Yuan, Weikang ^a  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Absorption; CaO based sorbent; Carbonation; Diffusion; Kinetics; Stability

Indexed keywords

ABSORPTION; ACTIVATION ENERGY; ALUMINUM; C (PROGRAMMING LANGUAGE); CALCINATION; CALCIUM; CARBON DIOXIDE; CARBONATION; CONVERGENCE OF NUMERICAL METHODS; DIFFUSION; ENZYME KINETICS; KINETICS; RATE CONSTANTS; SORPTION; SURFACE REACTIONS;

AVERAGE VALUES; GRAIN MODELS; INTRINSIC RATE CONSTANT; PRODUCT LAYER; RANDOM PORE MODEL; TEMPERATURE RANGE;

SORBENTS;

EID: 84876716398     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2013.03.047     Document Type: Article

References (53)

1. 2 with lime. Energy Fuels 2003, 17:308-315.
2. 2. Ind. Eng. Chem. Res. 2005, 44:5608-5615.
3. Anthony E.J. Ca looping technology: current status, developments and future directions. Greenhouse Gases: Sci. Technol. 2011, 1:36-47.
4. Arias B., Abanades J.C., Grasa G.S. An analysis of the effect of carbonation conditions on CaO deactivation curves. Chem. Eng. J. 2011, 167:255-261.
5. 2. J. Appl. Chem. Biotechnol. 1973, 23:733-742.
6. Bhatia S.K., Perlmutter D.D. A random pore model for fluid-solid reactions: I. Isothermal, kinetic control. AIChE J. 1980, 26:379-386.
7. Bhatia S.K., Perlmutter D.D. A random pore model for fluid-solid reactions: II. Diffusion and transport effects. AIChE J. 1981, 27:247-254.
8. 2-lime reaction. AIChE J. 1983, 29:79-86.
9. 2 capture. Prog. Energy Combust. Sci. 2010, 36:260-279.
10. Broda M., Kierzkowska A.M., Müller C.R. Application of the sol-gel technique to develop synthetic calcium-based sorbents with excellent carbon dioxide capture characteristics. ChemSusChem 2012, 5:411-418.
11. 2 sorbents. Adv. Mater. 2012, 24:3059-3064.
12. 2 sorbents. Environ. Sci. Technol. 2012, 46:10849-10856.
13. 2 by a synthetic, CaO-containing sorbent. Chem. Eng. Sci. 2009, 64:2147-2157.
14. 3 carbon dioxide absorbent with enhanced stability for sorption-enhanced reforming applications. Ind. Eng. Chem. Res. 2011, 50:12741-12749.
15. Fan L.S. Chemical Looping Systems for Fossil Energy Conversion 2010, Wiley, New York.
16. 2 capture. Energy Fuels 2006, 20:2417-2420.
17. 2 capture capacity of CaO in long series of carbonation/ calcination cycles. Ind. Eng. Chem. Res. 2006, 45:8846-8851.
18. Grasa G., Murillo R., Alonso M., Abanades J.C. Application of the random pore model to the carbonation cyclic reaction. AIChE J. 2009, 55:1246-1255.
19. 2-sorbent at intermediate temperatures. Ind. Eng. Chem. Res. 2011, 50:4042-4049.
20. Gupta H., Fan L.S. Carbonation-calcination cycle using high reactivity calcium oxide for carbon dioxide separation from flue gas. Ind. Eng. Chem. Res. 2002, 41:4035-4042.
21. Heesink A.B.M., Prins W., van Swaaij W.P.M. A grain size distribution model for non-catalytic gas-solid reactions. Chem. Eng. J. 1993, 53:25-37.
22. 2 Capture and Storage: A Key Carbon Abatement Option 2008, IEA Publications, Paris.
23. Johnsen K., Grace J.R., Elnashaie S.S.E.H., Kolbeinsen L., Eriksen D. Modeling of sorption-enhanced steam reforming in a dual fluidized bubbling bed reactor. Ind. Eng. Chem. Res. 2006, 45:4133-4144.
24. 2 capture process. ChemPlusChem 2013, 78:92-100.
25. 2 capture at high temperature. Energy Fuels 2012, 26:3103-3109.
26. Lee D.K. An apparent kinetic model for the carbonation of calcium oxide by carbon dioxide. Chem. Eng. J. 2004, 100:71-77.
27. Li Z.S., Cai N.S., Huang Y.Y., Han H.J. Synthesis, experimental studies, and analysis of a new calcium-based carbon dioxide absorbent. Energy Fuels 2005, 19:1447-1452.
28. 2 capture and multiple carbonation-calcination cycles for a new-based sorbent. Ind. Eng. Chem. Res. 2006, 45:1911-1917.
29. Li Z.S., Cai N.S. Modeling of multiple cycles for sorption-enhanced steam methane reforming and sorbent regeneration in fixed bed reactor. Energy Fuels 2007, 21:2909-2918.
30. 2. Energy Fuels 2012, 26:4607-4616.
31. Li Z.S., Liu Y., Cai N.S. Understanding the effect of inert support on the reactivity stabilization for synthetic calcium based sorbents. Chem. Eng. Sci. 2013, 89:235-243.
32. 2 capture. Environ. Sci. Technol. 2010, 44:841-847.
33. 2 capture. Environ. Sci. Technol. 2010, 44:3093-3097.
34. 2 capture-a review. Energy Fuels 2012, 26:2751-2767.
35. 2 uptake by a synthetic calcium based sorbent. Chem. Eng. Sci. 2012, 69:644-658.
36. 2 capture. Energy Fuels 2009, 23:1093-1100.
37. 2 capture-a review of sorbent modification methods. Int. J. Environ. Res. Public Health 2010, 7:3129-3140.
38. 2 removal at high temperature. Microporous Mesoporous Mater. 2008, 110:119-127.
39. 2 sorption capacity and stability on multicycle operation. Ind. Eng. Chem. Res. 2008, 47:9537-9543.
40. Mess D., Sarofim A.F., Longwell J.P. Product layer diffusion during the reaction of calcium oxide with carbon dioxide. Energy Fuels 1999, 13:999-1005.
41. Petzold L.R. A Description of DASSL: A Differential/Algebraic System Solver 1982, Sandia National Laboratories, Albuquerque, NM, Report SAND82-8637.
42. 2 capture by a mixing method. Environ. Sci. Technol. 2012, 46:1932-1939.
43. 2 sorbents. CIESC J. 2009, 60:641-648.
44. 2 reaction. Chem. Eng. Sci. 2008, 63:47-56.
45. 2 reaction. Chem. Eng. Sci. 2008, 63:57-70.
46. Stendardo S., Foscolo P.U. Carbon dioxide capture with dolomite: a model for gas-solid reaction within the grains of a particulate sorbent. Chem. Eng. Sci. 2009, 64:2343-2352.
47. Szekely J., Evans J.W. A structural model for gas-solid reactions with a moving boundary. Chem. Eng. Sci. 1970, 25:1091-1107.
48. 2 reactive adsorbent. Ind. Eng. Chem. Res. 2010, 49:2701-2706.
49. 2 in a sorption complex catalyst. AIChE J. 2012, 58:1570-1577.
50. 18 sorbent. Chem. Eng. J. 2012, 207-208:142-150.
51. 2 capture: a perspective. Ind. Eng. Chem. Res. 2012, 51:2133-2142.
52. 2 capture. Int. J. Greenhouse Gas Cont. 2012, 10:510-519.
53. 2 capture performance. Chem. Eng. Sci. 2012, 74:172-180.