Effect of iron promoter on structure and performance of K/Cu-Zn catalyst for higher alcohols synthesis from CO2 hydrogenation

Catalysis Letters

Volumn 143, Issue 4, 2013, Pages 345-355

  Li, Shanggui ^a,b   Guo, Haijun ^a,c   Luo, Cairong ^a,c   Zhang, Hairong ^a,c   Xiong, Lian ^a,c   Chen, Xinde ^a,c   Ma, Longlong ^a,c  

^a GUANGZHOU INSTITUTE OF ENERGY CONVERSION   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

^c INSTITUTE OF GEOLOGY AND GEOPHYSICS   (China)

Author keywords

CO2 hydrogenation; Higher alcohols synthesis; Iron promoter; K Cu Zn Fe catalyst; Synergistic effect

Indexed keywords

ADSORPTION/DESORPTION; FIELD EMISSION SCANNING ELECTRON MICROSCOPES; HIGHER ALCOHOLS SYNTHESIS; IRON CONCENTRATIONS; IRON PROMOTER; STRUCTURE AND PERFORMANCE; SYNERGISTIC EFFECT; TEMPERATURE-PROGRAMMED REDUCTION;

CARBIDES; CARBON DIOXIDE; CHEMICAL REACTORS; HYDROGENATION; IRON; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION; ZINC;

CATALYST SELECTIVITY;

EID: 84876190831     PISSN: 1011372X     EISSN: 1572879X     Source Type: Journal    
DOI: 10.1007/s10562-013-0977-7     Document Type: Article

References (37)

1. 2 sequestration and caprock integrity. Fuel 89:2651-2664
2. 2 for the production of synthesis gas and for methanol synthesis over copper-based zirconia-containing catalysts. Catal Today 144:318-323
3. Wang W, Wang SP, Ma XB, Gong JL (2011) Recent advances in catalytic hydrogenation of carbon dioxide. Chem Soc Rev 40:3369-4260
4. 2 hydrogenation to methanol catalyst. Catal Lett 118:264-269
5. 2 catalytic hydrogenation to methanol. J Fuel Chem Tech 39:912-917
6. Kanoun N, Astier MP, Pajonk GM (1992) Catalytic properties of new Cu based catalysts containing Zr and/or V for methanol synthesis from a carbon dioxide and hydrogen mixture. Catal Lett 15:231-235
7. 2 mixtures: catalytic structures and performance. J Catal 210:285-294
8. Deluga GA, Salge JR, Schmidt LD, Verykios XE (2004) Renewable hydrogen from ethanol by autothermal reforming. Science 303:993-997
9. Spivey JJ, Egbebi A (2007) Heterogeneous catalytic synthesis of ethanol from biomass-derived syngas. Chem Soc Rev 36:1514-1528
10. Centi G, Perathoner S (2009) Opportunities and prospects in the chemical recycling of carbon dioxide to fuels. Catal Today 148:191-205
11. Inoue T, Iizuka T, Tanabe K (1989) Hydrogenation of carbon dioxide and carbon monoxide over supported rhodium catalysts under 10 bar pressure. Appl Catal 46:1-9
12. Trovarelli A, Mustazza C, Dolcetti G, KasËpar J, Graziani M (1990) Carbon dioxide hydrogenation on rhodium supported on transition metal oxides: effect of reduction temperature on product distribution. Appl Catal 65:129-142
13. 2-hydrogenation on well balanced multi-functional FT-type composite catalysts. Appl Catal A Gen 186:395-406
14. 2+ alcohols synthesis over silica-supported Ir-Mo catalysts. Chem Lett 3:555-556
15. 2 hydrogenation over carbide catalysts. Chem Lett 1:5-8
16. 2 on Fe, Cu-based novel catalysts. Stud Surf Sci Catal 114:513-516
17. Takagawa M, Okamoto A, Fujimura H, Izawa Y, Arakawa H (1998) Ethanol synthesis from carbon dioxide and hydrogen. Stud Surf Sci Catal 114:525-528
18. 3 catalyst. J Catal 130:616-626
19. 2 catalysts. Energy 22:343-348
20. Li S, Li A, Krishnamoorthy S, Iglesia E (2001) Effects of Zn, Cu, and K promoters on the structure and on the reduction, carburization, and catalytic behavior of iron-based Fischer-Tropsch synthesis catalysts. Catal Lett 77:197-205
21. 4-catalysis and XPS aspects. J Catal 210:405-417
22. 2-rich stream over Cu-Zn-Fe composite-oxide catalysts. J Taiwan Inst Chem E 42:632-639
23. Shimokawabe M, Asakawa H, Takezawa N (1990) Characterization of copper/zirconia catalysts prepared by an impregnation method. Appl Catal 59:45-58
24. Faungnawakij K et al (2007) Hydrogen production from dimethyl ether steam reforming over composite catalysts of copper ferrite spinel and alumina. Appl Catal B 74(1-2):144-151
25. 4 by TPR technique. J Nat Gas Chem 18(1):110-113
26. Fang KG, Li DB, Lin MG, Xiang ML, Wei W, Sun YH (2009) A short review of heterogeneous catalytic process for mixed alcohols synthesis via syngas. Catal Today 147:133-138
27. 4 as an oxidant for two-step thermochemical methane reforming. Int J Hydrogen Energ 33:4560-4568
28. Ran HF, Fang KG, Lin MG, Sun YH (2010) Effect of Cu/Fe ratios on catalytic performances of co-precipitated Cu-Fe based catalysts for higher alcohols synthesis. Nat Gas Chem Indus 35:1-5
29. Lu YW, Yu F, Hu J, Liu J (2012) Catalytic conversion of syngas to mixed alcohols over Zn-Mn promoted Cu-Fe based catalyst. Appl Catal A Gen 429-430:48-58
30. Ding MY, Qiu MH, Liu JG, Li YP, Wang TJ, Ma LL, Wu CZ (2012) Influence of manganese promoter on co-precipitated Fe-Cu based catalysts for higher alcohols synthesis. Fuel. doi: 10.1016/j.fuel.2012.06.034
31. Gupta M, Smith ML, Spivey JJ (2011) Heterogeneous catalytic conversion of dry syngas to ethanol and higher alcohols on Cu-based catalysts. ACS Catal 1:641-656
32. Outokumpu (2002) HSC Chemistry® for Windows. Chemical reaction and equilibrium software with extensive thermochemical database. Version 5.1, ISBN 952-9507-08-9
33. Lwin Y (2000) Chemical equilibrium by Gibbs energy minimization on spreadsheets. Int J Eng Ed 4:335-339
34. 2 over a Zn-deposited Cu(111): formate intermediate. Appl Surf Sci 121-122:583-586
35. Nakamura J, Nakamura I, Uchijima T (1995) Methanol synthesis over a Zn-deposited copper model catalyst. Catal Lett 31:325-331
36. 2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001). Phys Chem Chem Phys 12:9909-9917
37. Ding MY, Qiu MH, Wang TJ, Ma LL, Wu CZ, Liu JG (2012) Effect of iron promoter on structure and performance of CuMnZnO catalyst for higher alcohols synthesis. Appl Energy 97:543-547