Ethanol dehydration by pervaporation using microporous silica membranes

Desalination and Water Treatment

Volumn 51, Issue 10-12, 2013, Pages 2368-2376

  Duque Salazar, Ana Catalina ^a   García, Miguel Ángel Gómez ^a   Fontalvo, Javier ^a   Jedrzejczyk, Marcin ^b   Rynkowski, Jacek Michal ^b   Dobrosz Gómez, Izabela ^a  

^a UNIVERSIDAD NACIONAL DE COLOMBIA   (Colombia)

^b LODZ UNIVERSITY OF TECHNOLOGY   (Poland)

Author keywords

Ethanol dehydration; Membranes preparation; Microporous silica membranes; Pervaporation

Indexed keywords

EID: 84875773453     PISSN: 19443994     EISSN: 19443986     Source Type: Journal    
DOI: 10.1080/19443994.2012.728053     Document Type: Article

References (22)

1. S. Chovau, S. Gaykawad, A.J.J. Straathof, B. Van der Bruggen, Influence of fermentation by-products on the purification of ethanol from water using pervaporation, Bioresour. Technol. 102 (2011) 1669-1674.
2. P. Kaewkannetra, N. Chutinate, S. Moonamart, T. Kamsan, T. Y. Chiu, Separation of ethanol from ethanol-water mixture and fermented sweet sorghum juice using pervaporation membrane reactor, Desalination 271 (2011) 88-91.
3. P.D. Chapman, T. Oliveira, A.G. Livingston, Membranes for the dehydration of solvents by pervaporation, J. Membr. Sci. 318 (2008) 5-37.
4. Y.S. Lin, I. Kumakiri, B.N. Nair, H. Alsyouri, Microporous inorganic membranes, Separ. Purif. Rev. 31 (2002) 229-379.
5. S. Qianyao, X. Chunming, Multilayer membranes based on ceramic materials-sol-gel synthesis characterization and membrane performance, Petroleum Sci. 4 (2007) 80-88.
6. M.P. Pina, M. Arruebo, M. Felipe, F. Fleta, M.P. Bernal, J. Coronas et al., A semi-continuous method for the synthesis of NaA zeolite membranes on tubular supports, J. Membr. Sci. 244 (2004) 141-150.
7. R.J.R. Uhlhorn, M.H.B.J. Huis in't Veld, K. Keizer, A.J. Burggraaf, High permselectivities of microporous silica modified c-alumina membranes, J. Mater. Sci. Lett. 8 (1989) 1135-1138.
8. Y. Ma, J. Wang, T. Tsuru, Pervaporation of water/ethanol mixtures through microporous silica membranes, Sep. Purif. Technol. 66 (2009) 479-485.
9. T. Peters, J. Fontalvo, M. Vorstman, N. Benes, R. Dam, Z. Vroon et al., Hollow fibre microporous silica membranes for gas separation and pervaporation. Synthesis, performance and stability, J. Membr. Sci. 248 (2005) 73-80.
10. B. Bettens, A. Verhoef, H.M. van Veen, C. Vandecasteele, J. Degrève, B. Van der Bruggen, Pervaporation of binary water-alcohol and methanol-alcohol mixtures through microporous methylated silica membranes: Maxwell-Stefan modeling, Comput. Chem. Eng. 34 (2010) 1775-1788.
11. R. Van Gemert, F.P. Cuperus, Newly developed ceramic membranes for dehydration and separation of organic mixtures by pervaporation, J. Membr. Sci. 105 (1995) 287-291.
12. S. Sommer, T. Melin, Influence of operation parameters on the separation of mixtures by pervaporation and vapor permeation with inorganic membranes. Part 1: Dehydration of solvents, Chem. Eng. Sci. 60 (2005) 4509-4523.
13. A. Verkerk, Properties of high flux ceramic pervaporation membranes for dehydration of alcohol/water mixtures, Sep. Purif. Technol. 22-23 (2001) 689-695.
14. A.C. Duque, Development of silica containing materials for the adsorption of organic compounds, M. Sc. Thesis, Universidad Nacional de Colombia Sede Manizales, 2011.
15. R.S.A. de Lange, J.H.A. Hekkink, H.K. Keizer, A.J. Burggraaf, Formation and characterization of supported microporous ceramic membranes prepared by sol-gel modification techniques, J. Membr. Sci. 99 (1995) 57-75.
16. R.M. De Vos, H. Verweij, H. Verweij, Hydrophobic silica membranes for gas separation, J. Membr. Sci. 158 (1999) 277-288.
17. S. Brunauer, P.H. Emmet, E. Teller, Adsorption of gases in multimolecular layers, J. Am. Chem. Soc. 60 (1938) 309-319.
18. G. Horvath, K. Kawazoe, Method for calculation of effective pore size distribution in molecular size carbon, J. Chem. Eng. Jap. 16 (1983) 470-475.
19. K. Czarnobaj, Preparation and characterization of silica xerogels as carriers for drugs, Drug Delivery 15 (2008) 485-492.
20. 3 precursors, J. Mol. Struct. 919 (2009) 140-145.
21. J. Sekulic, J. Elshof, D. Blank, Separation mechanism in dehydration of water/organic binary liquids by pervaporation through microporous silica, J. Membr. Sci. 254 (2005) 267-274.
22. H. van Veen, Y.C. van Delft, C.W.R. Engelen, P.P.A.C. Pex, Dewatering of organics by pervaporation with silica membranes, Sep. Purif. Technol. 22-23 (2001) 361-366.