On the use of unpolarized infrared spectroscopy for quantitative analysis of absorbing species in birefringent crystals

American Mineralogist

Volumn 98, Issue 4, 2013, Pages 689-697

  Withers, Anthony C ^a  

^a University of Minnesota   (United States)

Author keywords

Hydroxyl; Infrared spectroscopy; Olivine; Quantitative; Unpolarized

Indexed keywords

ANISOTROPY; BIREFRINGENCE; CRYSTALS; INFRARED SPECTROSCOPY; OLIVINE; SYSTEMATIC ERRORS; TRANSMISSIONS;

BIREFRINGENT CRYSTALS; HYDROXYL; INFRARED ABSORBANCE; O-H STRETCHING BANDS; QUANTITATIVE; QUANTITATIVE INFORMATION; TRANSMISSION DOMAINS; UNPOLARIZED;

SPECTRUM ANALYSIS;

ABSORBANCE; ABSORPTION; ANISOTROPIC MEDIUM; BIREFRINGENCE; CRYSTAL; INFRARED SPECTROSCOPY; OLIVINE; POLARIZATION; QUANTITATIVE ANALYSIS; THEORETICAL STUDY;

EID: 84875747697     PISSN: 0003004X     EISSN: 19453027     Source Type: Journal    
DOI: 10.2138/am.2013.4316     Document Type: Article

References (18)

1. Asimow, P.D., Stein, L.C., Mosenfelder, J.L., and Rossman, G.R. (2006) Quantitative polarized infrared analysis of trace OH in populations of randomly oriented mineral grains. American Mineralogist, 91, 278-284.
2. Bai, Q. and Kohlstedt, D.L. (1993) Effects of chemical environment on the solubility and incorporation mechanism for hydrogen in olivine. Physics and Chemistry of Minerals, 19, 460-471.
3. Bell, D.R., Rossman, G.R., Maldener, J., Endisch, D., and Rauch, F. (2003) Hydroxide in olivine: A quantitative determination of the absolute amount and calibration of the IR spectrum. Journal of Geophysical Research-Solid Earth, 108, 2105.
4. Euler, L. (1769) De summis serierum numeros Bernoullianos involventium. Novi Commentarii Academiae Scientiarum Petropolitanae, 14, 129-167.
5. Kohlstedt, D.L., Keppler, H., and Rubie, D.C. (1996) Solubility of water in the a, b and g phases of (Mg,Fe)2SiO4. Contributions to Mineralogy and Petrology, 123, 345-357.
6. Kovács, I., Hermann, J., O'Neill, H.St.C., Gerald, J.F., Sambridge, M., and Horvath, G. (2008) Quantitative absorbance spectroscopy with unpolarized light: Part II. Experimental evaluation and development of a protocol for quantitative analysis of mineral IR spectra. American Mineralogist, 93, 765-778.
7. Kovács, I., O'Neill, H.St.C., Hermann, J., and Hauri, E.H. (2010) Site-specific infrared O-H absorption coefficients for water substitution into olivine. American Mineralogist, 95, 292-299.
8. Lemaire, C., Kohn, S.C., and Brooker, R.A. (2004) The effect of silica activity on the incorporation mechanisms of water in synthetic forsterite: a polarised infrared spectroscopic study. Contributions to Mineralogy and Petrology, 147, 48-57.
9. Libowitzky, E. and Rossman, G.R. (1996) Principles of quantitative absorbance measurements in anisotropic crystals. Physics and Chemistry of Minerals, 23, 319-327.
10. Litasov, K.D., Ohtani, E., Kagi, H., Jacobsen, S.D., and Ghosh, S. (2007) Temperature dependence and mechanism of hydrogen incorporation in olivine at 12.5-14.0 GPa. Geophysical Research Letters, 34, L16314.
11. Miller, G.H., Rossman, G.R., and Harlow, G.E. (1987) The natural occurrence of hydroxide in olivine. Physics and Chemistry of Minerals, 14, 461-472.
12. Mosenfelder, J.L., Deligne, N.I., Asimow, P.D., and Rossman, G.R. (2006) Hydrogen incorporation in olivine from 2-12 GPa. American Mineralogist, 91, 285-294.
13. Press, W.H., Teukolsky, S.A., Vetterling, W.T., and Flannery, B.P. (2007) Numerical Recipes: The Art of Scientific Computing, 1235 p. Cambridge University Press, New York.
14. Rossman, G.R. (2006) Analytical methods for measuring water in nominally anhydrous minerals. In H. Keppler and J.R. Smyth, Eds., Water in Nominally Anhydrous Minerals, 62, p. 1-28. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Chantilly, Virginia.
15. Sambridge, M., Gerald, J.F., Kovács, I., O'Neill, H.St.C., and Hermann, J. (2008) Quantitative absorbance spectroscopy with unpolarized light: Part I. Physical and mathematical development. American Mineralogist, 93, 751-764.
16. Smyth, J.R., Frost, D.J., Nestola, F., Holl, C.M., and Bromiley, G. (2006) Olivine hydration in the deep upper mantle: Effects of temperature and silica activity. Geophysical Research Letters, 33, L15301.
17. Withers, A.C., Hirschmann, M.M., and Tenner, T.J. (2011) The effect of Fe on olivine H2O storage capacity: Consequences for H2O in the martian mantle. American Mineralogist, 96, 1039-1053.
18. Withers, A.C., Bureau, H., Raepsaet, C., and Hirschmann, M.M. (2012) Calibration of infrared spectroscopy by elastic recoil detection analysis of H in synthetic olivine. Chemical Geology, 334, 92-98.