Ions, ion pairs and inverse micelles in non-polar media

Current Opinion in Colloid and Interface Science

Volumn 18, Issue 2, 2013, Pages 93-115

  Dukhin, Andrei ^a   Parlia, Sean ^a  

^a Dispersion technology Inc   (United States)

Author keywords

Dissociation; Inverse micelle; Ion pairs; Ionic strength; Ionic surfactant; Ionization; Ions; Microemulsion; Non aqueous conductivity; Non ionic surfactant; Non polar liquids

Indexed keywords

INVERSE MICELLES; ION PAIRS; IONIC SURFACTANTS; NON-AQUEOUS; NONPOLAR LIQUIDS;

DISSOCIATION; ELECTROCHEMISTRY; ELECTROLYTES; IONIC LIQUIDS; IONIC STRENGTH; IONIZATION; IONS; MICELLES; MICROEMULSIONS; SURFACE ACTIVE AGENTS;

IONIZATION OF LIQUIDS;

ELECTROLYTE; ION; IONIC SURFACTANT; NONIONIC SURFACTANT; SURFACTANT; WATER;

CHEMICAL ANALYSIS; CHEMICAL COMPOSITION; CHEMICAL MODIFICATION; COLLOID; CONCENTRATION (PARAMETERS); DISSOCIATION CONSTANT; ELECTROCHEMISTRY; EQUILIBRIUM CONSTANT; HUMAN; INVERSE MICELLE; ION CONDUCTANCE; ION PAIR EXTRACTION; LIQUID; MICELLE; MICELLIZATION; MICROEMULSION; MOLECULAR STABILITY; PHASE TRANSITION; REVIEW; SCIENTIST; STEREOCHEMISTRY; THEORETICAL MODEL; WATER CONTENT;

EID: 84875529766     PISSN: 13590294     EISSN: 18790399     Source Type: Journal    
DOI: 10.1016/j.cocis.2013.02.004     Document Type: Review

References (120)

1. Lyklema J. Principles of the stability of lyophobic colloidal dispersions in non-aqueous media. Adv Colloid Interface Sci 1968, 2:65-114.
2. van der Ph C Hoeve, Lyklema J. Electrostatic stabilization of suspensions in non-aqueous media. Adv Colloid Interf Sci 1992, 42:205-277.
3. Electrochemistry in Nonaqueous Solutions 2007, Willey-VCH. K. Izutsu (Ed.).
4. Nonaqueous Electrochemistry 1999, Marcel Dekker. D. Aurbach (Ed.).
5. Ion-Pair Chromatography and related Techniques. Analytical chemistry series 2010, CRC Press. T. Cecchi (Ed.).
6. Morrison I.D. Electrical charges in non-aqueous media. Colloids Surf A 1993, 71:1-37.
7. Bockris J., Reddy A.K. Modern electrochemistry 1977, vol.1. A Plenum/Rosetta edition.
8. Bjerrum N. A new form for the electrolyte dissociation theory. Proceedings of the 7th International Congress of Applied Chemistry, Section X 1929, 55-60. [London].
9. Onsager L. Report on revision of the conductivity theory. Trans Faraday Soc 1927, 23:341-349.
10. Fuoss R.M. Ionic association. I. Derivation of constants from conductance data. J Am Chem Soc 1957, 79(13):3301-3303.
11. Fuoss R.M. Influence of dipole fields between solute molecules. II. On molecular polarization. J Am Chem Soc 1934, 56:1031-1033.
12. Onsager L. Deviation from Ohm's law in weak electrolytes. J Chem Phys 1934, 2:599.
13. Eicke H.F., Borkovec M., Das-Gupta B. Conductivity of water-in-oil microemulsions: a quantitative charge fluctuation model. J Phys Chem 1989, 93:314-317.
14. Faraday Michael Experimental researches in chemistry and physics 1859, 33-53. Richard Taylor and William Francis, London.
15. Kraus C.A., Fuoss R.M. Properties of electrolytic solutions. 1. Conductance as influenced by the dielectric constant of the solvent medium. J Am Chem Soc 1933, 55(1):21-36.
16. Kablukoff Iwan Uber die elektrische Leitfahigkeit von Chlorwasser-stoff in verschiedenen Losungsmitteln. Zeitschrift fur Physikalische Chemie 1889, 4:429-434. W. Ostwald, J.H. van't Hoff (Eds.).
17. Plotnikov W. Die elecktrische Leitahigkeit der Gemische von Brom und Ather. Zeitschrift fur Physikalische Chemie 1906, 57:502-506. W. Ostwald, J.H. van't Hoff (Eds.).
18. Walden P. Bull Acad Imp Sci St Petersburg 1913, 7:934.
19. Walden P. Salts, Acids, and Basis; Electrolytes; Stereochemistry 1929, referenced according to, McGraw-Hill, New York.
20. Cady H.P., Lichtenwalter H.O. Chemical reactions and electrical conductivity of non-aqueous solutions. J Am Chem Soc 1913, 35(10):1134-1140.
21. Cady H.P., Baldwin E. Reactivity and conductance of benzene solutions. J Am Chem Soc 1921, 43(3):646-651.
22. Hill A.J., Kelsey E.B. Researches on thiocyanites and isothiocyanites. XV. The nature of the intermolecular rearrangement of isothiocyanito-acetanilides. J Am Chem Soc 1922, 44(10):1164.
23. Plotnikov Z Phys Chem 1925, 116:111.
24. Finkelstein Z Phys Chem 1926, 121:46.
25. Ussanoiwitch Z Phys Chem 1926, 124:427.
26. Bruns Z Anorg Allg Chem 1927, 163:120.
27. Plotnikov, Jakubson Z Phys Chem 1928, 138:235.
28. Rabinovich Z Phys Chem 1928, 132:83.
29. Plotnikov, Kudra Z Phys Chem 1929, 145:625.
30. Walden Z Phys Chem 1930, 147:1.
31. LaMer V.K., Downes H.C. Acidity in nonaqueous solvents, conductometric and electrometric titrations of acids and bases in benzene. J Am Chem Soc 1931, 53:888.
32. Debye P., Hückel E. Zur Theorie der Elektrolyte. I. Gefrierpunktserniedrigung und verwandte Erscheinungen. Physikalische Zeitschrift 1923, 24:185-206.
33. Fuoss R.M., Kraus C.A. Properties of electrolytic solutions. IV. The conductance minimum and the formation of triple ions due to the action of columbic forces. J Am Chem Soc 1933, 55(6):2387-2399.
34. Mead D.J., Fuoss R.M., Kraus C.A. Properties of electrolytic solutions. XIX. The conductance of mixed electrolytes in ethylene chloride, tetrabutyl- and tetramethyl-ammonium picrates. Trans Faraday Soc 1936, 32:594-606.
35. Wyman Phys Rev 1930, 33:623.
36. Kraus C.A., Hooper G.S. The dielectric properties of solutions of electrolytes in non-polar solvent. Proc Natl Acad Sci 1933, 19(11):939-943.
37. Geddes J.A., Kraus C.A. Properties of electrolytic solutions. XVIII. Molecular polarizations and polar moments of some electrolytes in benzene solutions. Trans Faraday Soc 1936, 32:585-593.
38. Batson, Kraus C.A. Properties of electrolytic solutions. J Am Chem Soc 1934, 56:2017.
39. Fuoss R.M., Kraus C.A. Properties of electrolytic solutions. XV. Thermodynamic properties of weak electrolytes. J Am Chem Soc 1935, 57:1-5.
40. Rothrock D.A., Kraus C.A. Properties of electrolytic solutions. XX. Freezing points of solutions of electrolytes in benzene. J Am Chem Soc 1937, 59:1699-1703.
41. Janz G.J., Tait M.J. Application of Fuoss-Onsager theory to conductance data for sodium and potassium iodide solutions in various solvents. Can J Chem 1967, 45:1101-1108.
42. Miyoshi K. Comparison of the conductance equations of Fuoss-Onsager, Fuoss-Hsia and Pitts with the data of bis(2,9-dimethyl-1,10-phenanthroline)Cu(1) Perchlorate. Bull Chem Soc Jpn 1973, 46:426-430.
43. Nelson S.M., Pink R.C. Solutions of metal soaps in organic solvents. Part IV. Direct current conductivity in solutions of some metal oleates in toluene. J Chem Soc 1954, 4412-4417.
44. Kaufman S., Singleterry C.R. Micelle formation by sulfonates in a nonpolar solvent. J Colloid Sci 1955, 10(2):139-150.
45. McGrown D.N.L., Parfitt G.D., Willis E. Stability of non-aqueous dispersions. 1. The relationship between surface potential and stability in hydrocarbon media. J Colloid Sci 1965, 20:650-654.
46. Bowyer P.M., Ledwith A., Sherrington D.C. Ion-pair dissociation equilibria for hexachloroantimonate salts of stable organic cations in dichloromehane. J Chem Soc B 1971, 1511-1517.
47. Fowkes F.M., Jinnal H., Mostafa M.A., Andreson F.W., Moore R.J. Mechanism of electric charging of particles in nonaqueous liquids. Colloids Surf Reprog Technol 1982, 307-324. [Chapter 15].
48. Chowdiah P., Wasan D.T., Gidaspow D. On interpretation of streaming potential data in nonaqueous media. Colloids Surf 1983, 7:291-299.
49. Labib M.E., Williams R. The use of zeta-potential measurements in organic solvents to determine the donor-acceptor properties of solid surfaces. J Colloid Interface Sci 1984, 97(2):356-366.
50. Labib M.E., Williams R. An experimental comparison between the aqueous pH scale and the electron donicity scale. Colloid Polym Sci 1986, 264:533-541.
51. Labib M.E., Williams R. The effect of moisture on the charge at the interface between solids and organic liquids. J Colloid Interface Sci 1987, 115(2):330-338.
52. Labib M.E. The origin of the surface charge on particles suspended in organic liquids. Colloids Surf 1988, 29:293-304.
53. Marlow B.J., Sresty G.C., Hughes R.D., Mahajan O.P. Colloidal stabilization of clays by asphaltenes in hydrocarbon media. Colloids Surf 1987, 24:283-297.
54. Pearlstine K.A., Swanson J.R. Charging of polymer particles in nonaqueous liquid with carboxylic acid charge additives. JCIS 1992, 151(2):343-350.
55. Crocer J.C., Grier D.G. Microscopic measurement of the pair interaction potential of charged-stabilized colloids. Phys Rev Lett 1994, 73(2):352-355.
56. Hsu M.F., Dufresne E.R., Weitz D.A. Charge stabilization in nonpolar solvents. Langmuir 2005, 21(11):4881-4887.
57. Dukhin A.S., Goetz P.J. How non-ionic "electrically neutral" surfactants enhance electrical conductivity and ion stability in non-polar liquids. J Electroanal Chem 2006, 588:44-50.
58. Kim J., Anderson J.L., Garoff S., Schlangen L.J.M. Ionic conduction and electrode polarization in a dopped nonpolar liquid. Langmuir 2005, 21:8620-8629.
59. Prieve D.C., Haggard J.D., Fu R., Sides P.J., Bethea R. Two independent measurement of Debye length in dopped nonploar liquids. Langmuir 2008, 24:1120-1132.
60. Strubbe F., Verschueren A.R.M., Schlangen L.J.M., Beunis F., Neyts K. Generation current of charged micelles in nonaqueous liquids: Measurements and simulations. J Colloid Interface Sci 2006, 300(1):396-403.
61. Beunis F., Strubbe F., Marescaux M., Neyts K., Verschueren A.R.M. Micellization and adsorption of surfactant in a nonpolar liquid in micrometer scale geometries. Appl Phys Lett 2010, 97(18).
62. Sainis S.K., Merrill J.W., Dufresne E.R. Electrostatic interactions of colloidal particles at vanishing ionic strength. Langmuir 2008, 24(23):13334-13337.
63. Poovarodom S., Berg J.C. Effect of particle and surfactant acid-base properties on charging of colloids in apolar media. J Colloid Interface Sci 2010, 346:370-377.
64. Guo Q., Singh V., Behrens S.H. Electric charging in non-polar dispersions due to non-ionazable surfactants. Langmuir 2010, 26(5):3203-3207.
65. Espinosa C.E., Guo Q., Singh V., Behrens S.H. Particle charging and charge screening in nonpolar dispersions with non-ionic surfactants. Langmuir 2010, 26(22):16941-16948.
66. Bockris J.O'.M., Saluja P.P.S. Ionic salvation numbers from compressibilities and ionic vibration potential measurements. J Phys Chem 1972, 76(15):2140-2151.
67. Maxwell J.C. Electricity and magnetism 1892, vol. 1. Clarendon Press, Oxford.
68. Wagner K.W. Erklärung der dielektrischen Nachwirkungsvorgänge auf Grund Maxwellscher Vorstellungen. Arch Electrotech 1914, 2:371.
69. Singlettery C.R., Weinberger L.A. J Am Chem Soc 1951, 73:4574.
70. Kaufman S., Singlettery C.R. J Colloid Sci 1952, 7:453.
71. Berne B.J., Pecora R. Dynamic light scattering 2000, Dover Publications.
72. Parent M.E., Yang J., Jeon Y., Toney M.F., Zhou Z.L., Henze D. Influence of surfactant structure on inverse micelle size and charge for non-polar electrophoretic inks. Langmuir 2011, 27(19):11845-11851.
73. Kitahara A. Zeta potential in non-aqueous media and its effect on dispersion stability. Prog Org Coat 1973/4, 2:81-98.
74. Kitahara A. Nonaqueous systems. Electrical phenomena at interfaces 1984, Marcel Decker. A. Kitahara, A. Watanabe (Eds.).
75. Dukhin A.S., Goetz P.J. Ultrasound for characterizing liquids, nano- and micro- particulates, and porous bodies 2010, Elsevier.
76. Debye P. A method for the determination of the mass of electrolyte ions. J Chem Phys 1933, 1:13-16.
77. Shilov V.N., Borkovskaja Yu B., Dukhin A.S. Electroacoustic theory for concentrated colloids with arbitrary κa. Nano-colloids. Non-aqueous colloids. JCIS 2004, 277:247-258.
78. Prieve D.C. Measurement of colloidal forces with TIRM. Adv Colloid Interf Sci 1999, 82:93-125.
79. Derjaguin B.V., Landau L. Acta Phisicochim 1941, 14:633. USSR.
80. Verwey E.J.W., Overbeek J.T.G. Theory of the stability of lyophobic colloids: the interpretation of sol particles having an electric double layer 1948, Elsevier, NY.
81. Beunis F., Strubbe F., Marescaux M., Neyts K., Verschueren A.R.M. Diffuse double layer charging in nonpolar liquids. Appl Phys Lett 2007, 91(18).
82. Beunis F., Strubbe F., Neyts K., Verschueren A.R.M. Power-law transient charge transport in a nonpolar liquid. Appl Phys Lett 2007, 90(18).
83. Beunis F., Strubbe F., Marescaux M., Beeckman J., Neyts K., Verschueren A.R.M. Dynamics of charge transport in planar devices. Phys Rev E Stat Nonlin Soft Matter Phys 2008, 78(1).
84. Neyts K., Beunis F., Strubbe F., Marescaux M., Verboven B., Karvar M., et al. Charge transport and current in non-polar liquids. J Phys Condens Matter 2010, 22(49).
85. Karvar M., Strubbe F., Beunis F., Kemp R., Smith A., Goulding M., et al. Transport of charged aerosol OT inverse micelles in nonpolar liquids. Langmuir 2011, 27(17):10386-10391.
86. Fuoss R.M. Ionic association. III. The equilibrium between ion pairs and free ions. J Am Chem Soc 1958, 80(19):5059-5061.
87. Gilkerson W.R. Application of free volume theory to ion pair dissociation constant. J Chem Phys 1956, 25(6):1199-1201.
88. Justice J.C. An interpretation of distance parameter of the Fuoss-Onsager conductance equation in the case of ionic association. Electrochim Acta 1971, 16:701-712.
89. Fuoss R.M., Hsia K. Association of 1-1 salts in water. Proc Natl Acad Sci U S A 1967, 57(6):1550-1557.
90. Bauer F. Ann d Physik 1930, 5(6):253. [referenced according paper [12]].
91. Gemant A. Electrophysik der Isolierstoffe 1930, 78. Springer, Berlin, [referenced according paper [12]].
92. Gemant A. Electrotech Zeits 1933, 54:468. [referenced according paper [12]].
93. Tanaka Y., Ishida M., Yokota S., Edamura K. Miniaturized and high-powered micro pump using electro-conjugate fluid. Fac. of Eng. & Design, Hosei Univ., Proc. World Automation Congress Tokyo 2010, 1-6.
94. Nelson S.M., Pink R.C. Solutions of metal soaps in organic solvents. Part III. The aggregation of metal soaps in toluene, isobutyl alcohol, and pyridine. J Chem Soc 1952, 1744-1750.
95. Mathews M.B., Mattoon R.W. J Chem Phys 1949, 17:496-497.
96. Verwey E.J.W. Recl Trav Chim Pays-Bas Belg 1941, 60:887.
97. Verwey E.J.W. Recl Trav Chim Pays-Bas Belg 1942, 61:127.
98. Everett, Coulson Trans Faraday Soc 1940, 36:633.
99. McGrown D.N.L., Parfitt G.D. Stability of non-aqueous dispersions. Discuss Faraday Soc 1966, 42:225-231.
100. Van Tassel J., Randall C.A. Surface chemistry and surface charge formation for an alumina powder in ethanol with addition of HCl and KOH. JCIS 2001, 241:302-316.
101. Gacek M., Bergsman D., Michor E., Berg J.C. Effects of trace water on charging of silica particles dispersed in a nonpolar medium. Langmuir 2012, 28:11633-11638.
102. International Standard ISO 13099-1 Colloidal systems-methods for zeta potential determination. Part 1. Electroacoustic and electrokinetic phenomena 2012.
103. Dukhin S.S., Sjoblom J., Saether O. An experimental and theoretical approach to the dynamic behavior of emulsion. Surfactant science series 2006, vol. 132:1-126. Taylor & Francis, NY. J. Sjoblom (Ed.).
104. Dukhin S.S., Sjoblom J. Fragmentation of primary flocs in emulsions and the subsequent reduction of coalescence. J Dispers Sci Technol 1998, 19:311-327.
105. Chandrasekhar S. Stochastic problems in physics and astronomy. Rev Mod Phys 1943, 15(1):1-89.
106. Fu R., Prieve D. Electrical charges in non-aqueous solutions. 1. Acetone-water mixtures as model polar solvents. Langmuir 2007, 23:8048-8052.
107. Lyklema J. Principles of interactions in non-aqueous electrolyte solutions. J Curr Opin Colloid Interface Sci 2013, 18:116-128. (this issue).
108. Cametti C., Codastefano P.A., Tartaglia P., Chen S.H., Rouch J. Electrical conductivity and percolation phenomena in water-in-oil microemulsions. Phys Rev A 1992, 45(8):5358-5361.
109. Mancui M., Ruckenstein E. Specific ion effects via ion hydration: 1. Surface tension. Adv Colloid Interface Sci 2003, 105:63-101.
110. Mancui M., Ruckenstein E. The polarization model for hydration/double layer interactions: the role of the electrolyte ions. Adv Colloid Interface Sci 2004, 112:109-128.
111. Derjaguin B.V., Dukhin S.S., Yaroschuk A.E. J Colloid Interface Sci 1987, 115:234.
112. Dukhin S.S., Churaev N.V., Shilov V.N., Starov V.M. Problems of modeling reverse osmosis. Adv Chem, USSR 1988, 55(6):1010-1029. [English translation: 43, 6 (1988)].
113. Li Tielong, Li Shujing, Wang Shuaima, An Yi, Jin Zhaohui Preparation of nanoiron by water-in-oil microemulsion for reduction of nitrate in groundwater. J Water Resource Protect 2009, 1:1-57.
114. Wines T.H., Dukhin A.S., Somasundaran P. Acoustic spectroscopy for characterizing heptane/water/AOT inverse microemulsion. JCIS 1999, 216:303-308.
115. Kornilovich P., Jeon Y. Transient electric current in non-polar solvent. J Appl Phys 2011, 109:064509.
116. Dukhin AS, Parlia S. Properties of electrolytic solutions. XXXX. Dissociation, fluctuation and disproportionation models for ionization of surfactant solutions in low- and non-polar liquids. JCIS; submitted for publication.
117. Dukhin AS, Parlia S. Properties of electrolytic solutions. XXXXI. Role of water in ionization of non-polar liquids with ionic surfactants. JCIS; submitted for publication.
118. Bedwell B., Gulari E. Solution behavior of surfactants 1982, vol. 2. Plenum Press, New Your. K.L. Mittal (Ed.).
119. Cabos P.C., Delord P. J Appl Crystallogr 1979, 12:502.
120. Fletcher P.D.I., Robinson B.H., Bermejo-Barrera F., Oaknfull D.G., Dore J.C., Steylter D.C. Microemulsions 1982, 221. Plenum Press, New York. I.D. Rob (Ed.).