Combined effects of hydrogen back-pressure and NbF5 addition on the dehydrogenation and rehydrogenation kinetics of the LiBH4- MgH2 composite system

International Journal of Hydrogen Energy

Volumn 38, Issue 9, 2013, Pages 3650-3660

  Mao, Jianfeng ^a   Guo, Zaiping ^a   Yu, Xuebin ^b   Liu, Huakun ^a  

^a UNIVERSITY OF WOLLONGONG   (Australia)

^b FUDAN UNIVERSITY   (China)

Author keywords

Additive; Hydrogen storage; LiBH4; MgH2

Indexed keywords

ABSORPTION KINETICS; DEHYDROGENATION KINETICS; DESORPTION KINETICS; HYDROGEN STORAGE CAPACITIES; LIBH4; MGH2; REHYDROGENATION; REVERSIBLE DEHYDROGENATION;

ADDITIVES; DEHYDROGENATION; DESORPTION; HYDROGEN; HYDROGEN STORAGE; VACUUM;

KINETICS;

EID: 84875506547     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.12.106     Document Type: Article

References (63)

1. V.M. Vishnyakov Proton exchange membrane fuel cells Vacuum 80 2006 1053 1065 (Pubitemid 44056062)
2. L. Schlapbach, and A. Zuttel Hydrogen-storage materials for mobile applications Nature 414 2001 353 358 (Pubitemid 33097818)
3. http://www1.eere.energy.gov/hydrogenandfuelcells/storage/pdfs/ targets-onboard-hydro-storage-explanation.pdf (Web release date Jan 4, 2010).
4. S. Orimo, Y. Nakamori, J.R. Eliseo, A. Züttel, and C.M. Jensen Complex hydrides for hydrogen storage Chem Rev 107 2007 4111 4132 (Pubitemid 350054218)
5. 4 J. Alloys Compd 356-357 2003 515 520
6. 4 J Alloys Compd 404-406 2005 427 430 (Pubitemid 41688671)
7. 4 for hydrogen storage: A review Int J Hydrogen Energy 36 2011 14512 14526
8. 4 J Phys Chem C 116 2012 13488 13496
9. W.W. Sun, S.F. Li, J.F. Mao, Z.P. Guo, H.K. Liu, and S.X. Dou Nanoconfinement of lithium borohydride in Cu-MOFs towards low temperature dehydrogenation Dalton Trans 40 2011 5673 5676
10. 4 nanoparticles supported by disordered mesoporous carbon: Hydrogen storage performances and destabilization mechanisms Int J Hydrogen Energy 32 2007 3976 3980 (Pubitemid 350016589)
11. 3 composite J Phys Chem C 112 2008 4005 4010
12. 4-Al composite J Phys Chem C 113 2009 18424 18430
13. 2) J Phys Chem C 111 2007 19134 19140
14. 2 J Phys Chem C 112 2008 11059 11062
15. M. Au, A. Jurgensen, W. Spencer, D. Anton, F. Pinkerton, and S. Hwang Stability and reversibility of lithium borohydrides doped by metal halides and hydrides J Phys Chem C 112 2008 18661 18671
16. 4 system J Alloys Compd 487 2009 434 438
17. 4 system J Phys Chem C 114 2010 13132 13135
18. 4 system Mater Sci Forum 654-656 2010 2855 2858
19. 4 J Phys Chem B 109 2005 3719 3722
20. T. Nakagawa, T. Ichikawa, N. Hanada, Y. Kojima, and H. Fujii Thermal analysis on the Li-Mg-B-H systems J Alloys Compd 446-447 2007 306 309 (Pubitemid 47539053)
21. 2 hydrogen storage material J Phys Chem C 111 2007 12881 12885 (Pubitemid 47459182)
22. 2 composite system J Phys Chem C 114 2010 15212 15217
23. X.B. Yu, D.M. Grant, and G.S. Walker A new dehydrogenation mechanism for reversible multicomponent borohydride systems-the role of Li-Mg alloys Chem Commun 2006 3906 3908 (Pubitemid 44424677)
24. 4 catalyzed magnesium J Phys Chem C 111 2007 12495 12498 (Pubitemid 47387811)
25. 2 J Power Sources 194 2009 1128 1134
26. 2 multi-component hydrogen storage system-the effects of stoichiometry and decomposition environment on cycling behaviour Int J Hydrogen Energy 35 2010 4154 4161
27. 2 system J Phys Chem C 112 2008 18232 18243
28. T.K. Nielsen, U. Bösenberg, R. Gosalawit, M. Dornheim, Y. Cerenius, and F. Besenbacher A reversible nanoconfined chemical reaction ACS Nano 4 2010 3903 3908
29. 2 prepared by direct melt infiltration into nanoporous materials J Phys Chem C 115 2011 10903 10910
30. P.J. Wang, Z.Z. Fang, L.P. Ma, X.D. Kang, and P. Wang Effect of carbon addition on hydrogen storage behaviors of Li-Mg-B-H system Int J Hydrogen Energy 35 2010 3072 3075
31. P.J. Wang, L.P. Ma, Z.Z. Fang, X.D. Kang, and P. Wang Improved hydrogen storage property of Li-Mg-B-H system by milling with titanium trifluoride Energy Environ Sci 2 2009 120 123
32. 3 J Phys Chem C 114 2010 11643 11649
33. 2 system by introducing Ni nanoparticles J Mater Res 26 2011 1143 1150
34. 2 system catalysed by Ru nanoparticles supported on multiwalled carbon nanotubes J Alloys Compd 509 2011 5012 5016
35. 3 Int J Hydrogen Energy 36 2011 7128 7135
36. 2 composite Int J Hydrogen Energy 33 2008 74 80
37. 2-Al system J Phys Chem C 113 2009 21964 21969
38. 2 hydrogen storage system Int J Hydrogen Energy 36 2011 5425 5430
39. 2 system with the addition of Mn and V dopants J Power Sources 195 2010 7380 7385
40. 2 reactive hydride composites for sorption kinetics Acta Mater 58 2010 3381 3389
41. 2 composites improved by Ce-based additives Int J Hydrogen Energy 36 2011 5418 5424
42. 2 system Faraday Discuss 151 2011 133 141
43. 2 system Int J Hydrogen Energy 37 2012 1021 1026
44. 2 hydrogen storage system Int J Hydrogen Energy 37 2012 13147 13154
45. 5 catalyst J Phys Chem C 116 2012 13545 13550
46. 4 destabilized by chlorides of transition metal Fe, Co, and Ni Int J Hydrogen Energy 35 2010 7288 7294
47. K. Bukka, J.D. Miller, and J. Shabtai FTIR study of deuterated montmorillonites: Structural features relevant to pillared clay stability Clays Clay Miner 40 1992 92 102
48. 2+M) systems (M=Al, Ti, Fe, Ni, Cu and Nb) for hydrogen storage Int J Hydrogen Energy 29 2004 73 80
49. - and related anions J Am Chem Soc 84 1962 2506 2508
50. 2- complexes during hydrogen desorption from metal borohydrides J Phys Chem C 112 2008 3164 3169 (Pubitemid 351488297)
51. 2 system J Phys Chem C 115 2011 19419 19423
52. 4 by fluorine anion doping for hydrogen storage: a density functional study Chem Phys Lett 450 2008 318 321
53. 4 J Phys Chem C 115 2011 11839 11845
54. 4: General description and new insights Acta Mater 59 2011 1725 1733
55. 5 J Alloys Compd 453 2008 138 142 (Pubitemid 351329545)
56. 5 "pathway effect" on hydrogen sorption in Mg J Phys Chem B 110 2006 7845 7850
57. T. Ma, S. Isobe, E. Morita, Y.M. Wang, N. Hashimoto, and S. Ohnuki Correlation between kinetics and chemical bonding state of catalyst surface in catalyzed magnesium hydride Int J Hydrogen Energy 36 2011 12319 12323
58. 2 hydrogen storage system Int J Hydrogen Energy 36 2011 3932 3940
59. 2 J Phys Chem C 114 2010 3309 3317
60. 2,67 with metal additives: Ni, Fe and Zn J Alloys Compd 433 2007 282 291 (Pubitemid 46420664)
61. 5 J Alloys Compd 450 2008 395 399 (Pubitemid 350298781)
62. 4 for hydrogen storage induces grain refinement and impacts on hydrogen vacancy formation Acta Mater 55 2007 5549 5557 (Pubitemid 47302378)
63. 2 properties during mechanical milling Int J Hydrogen Energy 32 2007 2400 2407 (Pubitemid 47302608)