Two-channel decomposition of methanol on Pt nanoclusters supported on a thin film of Al2O3/NiAl(100)

Journal of Physical Chemistry C

Volumn 117, Issue 11, 2013, Pages 5667-5677

  Chao, Chen Sheng ^a   Li, Yu Da ^a   Hsu, Bo Wei ^a   Lin, Won Ru ^a   Hsu, Hsin Chung ^a   Hung, Ting Chieh ^a   Wang, Chao Chuan ^a   Luo, Meng Fan ^a  

^a NATIONAL CENTRAL UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORBED MONOLAYERS; BOND SCISSIONS; GROWN FROM VAPORS; MEAN DIAMETER; PREFERENTIAL REACTION; PT NANOCLUSTERS; SURFACE PROBES; ULTRAHIGH VACUUM CONDITIONS;

ALUMINUM; COALESCENCE; DEHYDROGENATION; LATTICE CONSTANTS; METHANE; METHANOL; MONOLAYERS; NANOCLUSTERS; PLATINUM; REACTION INTERMEDIATES; THIN FILMS;

PLATINUM COMPOUNDS;

EID: 84875449596     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp3080282     Document Type: Article

References (62)

1. Hamnett, A. Mechanism and Electrocatalysis in the Direct Methanol Fuel Cell Catal. Today 1997, 38, 445-457
2. Williams, K. R.; Burstein, G. T. Low Temperature Fuel Cells: Interactions between Catalysts and Engineering Design Catal. Today 1997, 38, 401-410
3. Burstein, G. T.; Barnett, C. J.; Kucernak, A. R.; Williams, K. R. Aspects of the Anodic Oxidation of Methanol Catal. Today 1997, 38, 425-437
4. Beden, B.; Lamy, C.; Leger, J. R. Electrocatalytic Oxidation of Oxygenated Aliphatic Organic Compounds at Noble Metal Electrodes; Bockris, J. O. M.; Conway, B. E.; White, R. E., Eds.; Plenum Publishers: New York, 1992; Vol. 22, p 566.
5. Rostrup-Nielsen, J. R.; Nielsen, R. Fuels and Energy for the Future: The Role of Catalysis Catal. Rev., Sci. Eng. 2004, 46, 247-270
6. Sexton, B. A. Methanol Decomposition on Platinum (111) Surf. Sci. 1981, 102, 271-281
7. 4 Alcohols Adsorbed on Platinum (111) Surf. Sci. 1982, 121, 181-198
8. Sexton, B, A.; Hughes, A. E. A Comparison of Weak Molecular Adsorption of Organic Molecules on Clean Copper and Platinum Surfaces Surf. Sci. 1984, 140, 227-248
9. Ehlers, D. H.; Spitzer, A.; Lüth, H. The Adsorption of Methanol on Pt(111), an IR Reflection and UV Photoemission Study Surf. Sci. 1985, 160, 57-69
10. Akhter, S.; White, J. M. A Static SIMS/TPD Study of the Kinetics of Methoxy Formation and Decomposition on O/Pt(111) Surf. Sci. 1986, 167, 101-126
11. Gibson, K. D.; Dubois, L. H. Step Effects in the Methanol Decomposition of Methanol on Pt(111) Surf. Sci. 1990, 233, 59-64
12. Wang, J.; Masel, R. I. Structure Sensitivity of Methanol Decomposition on (1 × 1) and (2 ×1) Pt(110) J. Vac. Sci. Technol. A 1990, 9 (3) 1879-1884
13. Wang, J.; Masel, R. I. C-O Bond Scission during Methanol Decomposition on (1 × 1) and (2 ×1) Pt(110) J. Am. Chem. Soc. 1991, 113, 5850-5856
14. Franaszczuk, K.; Herrero, E.; Zelenay, P.; Wieckowski, A.; Wang, J.; Masel, R. I. A Comparison of Electrochemical and Gas-Phase Decomposition of Methanol on Platinum Surfaces J. Phys. Chem. 1992, 96, 8509-8516
15. Kizhakevariam, N.; Stuve, E. M. Promotion and Poisoning of the Reaction of Methanol on Clean and Modified Platinum (100) Surf. Sci. 1993, 286, 246-260
16. Diekhöner, Butler, D. A.; Baurichter, A.; Luntz, A. C. Parallel Pathways in Methanol Decomposition on Pt(111) Surf. Sci. 1998, 409, 384-391
17. Panja, C.; Saliba, N.; Koel, B. E. Adsorption of Methanol, Ethanol and Water on Well-Characterized Pt-Sn Surface Alloys Surf. Sci. 1998, 395, 248-259
18. Lu, C.; Thomas, F. S.; Masel, R. I. Chemistry of Methoxonium on (2 × 1) Pt(110) J. Phys. Chem. B 2001, 105, 8583-8590
19. 2 on Polycrystalline Platinum J. Chem. Phys. 2009, 131, 154701
20. Matolínová, I.; Johánek, V.; Myslivecek, J.; Prince, K. C.; Skála, T.; Škoda, M.; Tsud, N.; Vorokhta, M.; Matolín, V. CO and Methanol Adsorption on (2 × 1) Pt(110) and Ion-Eroded Pt(111) Model Catalysts Surf. Interface Anal. 2011, 43, 1325-1331
21. Schauermann, S.; Hoffmann, J.; Johánek, V.; Hartmann, J.; Libuda, J. Adsorption, Decomposition and Oxidation of Methanol on Alumina Supported Palladium Particles Phys. Chem. Chem. Phys. 2002, 4, 3909-3918
22. Schauermann, S.; Hoffmann, J.; Johánek, V.; Hartmann, J.; Libuda, J.; Freund, H.-J. The Molecular Origins of Selectivity in Methanol Decomposition on Pd nanoparticles Catal. Lett. 2002, 84, 209-217
23. Schauermann, S.; Hoffmann, J.; Johánek, V.; Hartmann, J.; Libuda, J.; Freund, H.-J. Catalytic Activity and Poisoning of Specific Sites on Supported Metal Nanoparticles Angrew. Chem. Int. Ed. 2002, 41, 2532-2535
24. Bäumer, M.; Libuda, J.; Neyman, K. M.; Rösch, N.; Rupprechter, G.; Freund, H.-J. Adsorption and Reaction of Methanol on Supported Palladium Catalysts: Microscopic-Level Studies from Ultrahigh Vacuum to Ambient Pressure Phys. Chem. Chem. Phys. 2007, 9, 3541-3558
25. Freund, H.-J. Model Systems in Heterogeneous Catalysis: Selectivity Studies at the Atomic Level Top. Catal. 2008, 48, 137-144
26. 3 Layers on NiAl(001)-HREELS on Aluminum Oxide Films Surf. Sci. 1994, 319, 95-109
27. 3 Stripes in NiAl(001) Surf. Sci. 1998, 396, 176-188
28. Frémy, N.; Maurice, V.; Marcus, P. Initial Stages of Growth of Alumina on NiAl(001) at 1025 K J. Am. Ceram. Soc. 2003, 86, 669-675
29. 3 on NiAl(100) by Gas Phase Oxidation and Electrooxidation Surf. Sci. 2006, 600, 1942-1951
30. 3/NiAl(100) Nanotechnol. 2006, 17, 360-366
31. 3/NiAl(100) from Reflection High-Energy Electron Diffraction and Scanning-Tunnelling Microscopy Surf. Sci. 2007, 601, 2139-2146
32. 3 on NiAl(100) J. Phys. Chem. C 2009, 113, 12419-12426
33. Hong, I.-H.; Lee, T.-H.; Yin, G.-C.; Wei, D.-H.; Juang, J.-M.; Dann, T.-E.; Klauser, R.; Chuang, T. J.; Chen, C. T.; Tsang, K.-L. Performance of the SRRC Scanning Photoelectron Microscope Nucl. Instrum. Methods A 2001, 467, 905-908
34. 3/NiAl(100) Surface at Low Water Vapour Pressure Surf. Sci. 2005, 581, 88-104
35. Moulder, J. F.; Stickle, W. F.; Sobol, P. E.; Bomben, K. D. Handbook of X-ray Photoelectron Spectroscopy; Physical Electronics, Inc.: USA, 1995.
36. 3/NiAl(100) J. Phys. Chem. C 2008, 112, 2066-2073
37. 3/NiAl(100) Surf. Sci. 2006, 600, 4978-4985
38. Jaeger, R. M.; Kuhlenbeck, K.; Freund, H.-J.; Wuttig, M.; Hoffmann, W.; Franchy, R.; Ibach, H. Formation of a Well-Ordered Aluminium Oxide Overlayer by Oxidation of NiAl(110) Surf. Sci. 1991, 259, 235-252
39. 3/NiAl(100) J. Phys. Chem. C 2009, 113, 21054-21062
40. Greeley, J.; Marvikakis, M. Competitive Paths for Methanol Decomposition on Pt(111) J. Am. Chem. Soc. 2004, 126, 3910-3919
41. Martine, R.; Gardner, P.; Bradshaw, A. M. The Adsorbate-Induced Removal of the Pt{100} Surface Reconstruction. Part II: CO Surf. Sci. 1995, 342, 69-84
42. Xu, J.; Yates, J. T., Jr Terrace Width Effect on Adsorbate Vibrations: A Comparison of Pt(335) and Pt(112) for Chemisorption of CO Surf. Sci. 1995, 327, 193-201
43. Mukerji, R. J.; Bolina, A. S.; Brown, W. A. A RAIRS and TPD Investigation of the Adsorption of CO on Pt{211} Surf. Sci. 2003, 527, 198-208
44. Yoshinobu, J.; Tsukahara, N.; Yasui, F.; Mukai, K.; Yamashita, Y. Lateral Displacement by Transient Mobility in Chemisorption of CO on Pt(997) Phys. Rev. Lett. 2003, 90, 248301
45. Sun, Y.-N.; Qin, Z.-H.; Lewandowiski, M.; Shaikhutdinov, S.; Freund, H.-J. CO Adsorption and Dissociation on Iron Oxide Supported Pt Particles Surf. Sci. 2009, 603, 3099-3103
46. Lundwall, M. J.; McClure, S. M.; Goodman, D. W. Probing Terrace and Step Sites on Pt Nanoparticles Using CO and Ethylene J. Phys. Chem. C 2010, 114, 7904-7912
47. Stakheev, A. Y.; Shpiro, E. S.; Jaeger, N. I.; Schulzekloff, G. FTIR Evidence of the Formation of Platinum Carbonyls from Pt Metal-Clusters Encaged in KL Zeolite Catal. Lett. 1995, 34, 293-303
48. 2 Mixture J. Catal. 2011, 278, 153-161
49. Beitel, G. A.; Laskov, A.; Oosterbeek, H.; Kuipers, E. W. Polarization Modulation Infrared Reflection Absorption Spectroscopy of CO Adsorption on Co(0001) under a High-Pressure Regime J. Phys. Chem. 1996, 100, 12494-12502
50. Risse, T.; Carlsson, A.; Bäumer, M.; Klüner, T.; Freund, H.-J. Using IR Intensties as a Probe for Studying the Surface Chemical Bond Surf. Sci. 2003, 546, L829-L835
51. 3/NiAl(100) Phys. Chem. Chem. Phys. 2011, 13, 3281-3290
52. Oakes, D. J.; McCoustra, R. S.; Chesters, M. A. Dissociative Adsorption of Methane on Pt(111) Induced by Hyperthermal Collosions Faraday Discuss. 1993, 96, 325-336
53. Huberty, J. S.; Madix, R. J. An FTIR Study of the Bonding of Methoxy on Ni(100): Effects of Coadsorbed Sulfur, Carbon Monoxide and Hydrogen Surf. Sci. 1996, 360, 144-156
54. Sim, W. S.; Gardner, P.; King, D. A. Structure and Reactivity of the Surface Methoxy Species on Ag{111} J. Phys. Chem. 1995, 99, 16002-16010
55. Barros, R. B.; Garcia, A. R.; Ilharco, L. M. The Decomposition Pathways of Methanol on Clean Ru(0001), Studied by Reflection-Absorption Infrared Spectroscopy (RAIRS) J. Phys. Chem. B 2001, 105, 11186-11193
56. Pratt, S. J.; Escott, D. K.; King, D. A. Multilayer Growth and Chemisorbate Reactivity of Methanol on Pd{110} J. Chem. Phys. 2003, 119, 10867-10878
57. Zhou, J.; Mullins, D. R. Adsorption and Reaction of Formaldehyde on Thin-Film Cerium Oxide Surf. Sci. 2006, 600, 1540-1546
58. Henderson, M. A.; Mitchell, G. E.; White, J. M. The Decomposition of Formaldehyde on Pt(111): A TPD and HREELS Study Surf. Sci. 1987, 188, 206-218
59. Attard, G. A.; Ebert, E. D.; Parsons, R. Formaldehyde Decomposition and Oxidation on Pt(110) Surf. Sci. 1990, 240, 125-135
60. Hu, Y.; Griffiths, K. NO-Methanol Interaction on the Surface of Pt(332) Surf. Sci. 2007, 601, 2467-2472
61. Gland, J. L.; Sexton, B. A.; Fisher, G. B. Oxygen Interactions with the Pt(111) Surface Surf. Sci. 1980, 95, 587-602
62. 3: Structure and Adhesion Energy Phys. Rev. Lett. 1999, 83, 4120-4123