메뉴 건너뛰기




Volumn 117, Issue 11, 2013, Pages 5774-5784

Characterization of the active surface species responsible for UV-induced desorption of O2 from the rutile TiO2(110) surface

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SURFACE SPECIES; ADSORPTION SITE; FIVE-COORDINATED; PHOTOCHEMICAL PROPERTIES; PHOTON STIMULATED DESORPTION; PHYSISORBED; SINGLY CHARGED; VALENCE-BAND HOLES;

EID: 84875418754     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp312161y     Document Type: Article
Times cited : (40)

References (112)
  • 1
    • 0037233037 scopus 로고    scopus 로고
    • The Surface Science of Titanium Dioxide
    • Diebold, U. The Surface Science of Titanium Dioxide Surf. Sci. Rep. 2003, 48, 53-229
    • (2003) Surf. Sci. Rep. , vol.48 , pp. 53-229
    • Diebold, U.1
  • 25
    • 26444619077 scopus 로고    scopus 로고
    • 2-Based Photocatalysis: Surface Defects, Oxygen and Charge Transfer
    • 2-Based Photocatalysis: Surface Defects, Oxygen and Charge Transfer Top. Catal. 2005, 35, 197-210
    • (2005) Top. Catal. , vol.35 , pp. 197-210
    • Thompson, T.L.1    Yates Jr., J.T.2
  • 27
    • 65149098910 scopus 로고    scopus 로고
    • 2: Mechanisms behind the Surface Chemistry
    • 2: Mechanisms Behind the Surface Chemistry Surf. Sci. 2009, 603, 1605-1612
    • (2009) Surf. Sci. , vol.603 , pp. 1605-1612
    • Yates Jr., J.T.1
  • 29
    • 43849088933 scopus 로고    scopus 로고
    • 2(110): Oxygen Adsorption and Reactions with Bridging Oxygen Vacancies
    • 2(110): Oxygen Adsorption and Reactions with Bridging Oxygen Vacancies Phys. Rev. Lett. 2008, 100, 196102
    • (2008) Phys. Rev. Lett. , vol.100 , pp. 196102
    • Kimmel, G.A.1    Petrik, N.G.2
  • 35
    • 0041379810 scopus 로고    scopus 로고
    • An EPR Study of Thermally and Photochemically Generated Oxygen Radicals on Hydrated and Dehydrated Titania Surfaces
    • Attwood, A. L.; Murphy, D. M.; Edwards, J. L.; Egerton, T. A.; Harrison, R. W. An EPR Study of Thermally and Photochemically Generated Oxygen Radicals on Hydrated and Dehydrated Titania Surfaces Res. Chem. Intermed. 2003, 29, 449-465
    • (2003) Res. Chem. Intermed. , vol.29 , pp. 449-465
    • Attwood, A.L.1    Murphy, D.M.2    Edwards, J.L.3    Egerton, T.A.4    Harrison, R.W.5
  • 37
    • 77955341229 scopus 로고    scopus 로고
    • Vibrational Spectroscopic Observation of Weakly Bound Adsorbed Molecular Oxygen on Powdered Titanium Dioxide
    • Green, I. X.; Yates, J. T., Jr. Vibrational Spectroscopic Observation of Weakly Bound Adsorbed Molecular Oxygen on Powdered Titanium Dioxide J. Phys. Chem. C 2010, 114, 11924-11930
    • (2010) J. Phys. Chem. C , vol.114 , pp. 11924-11930
    • Green, I.X.1    Yates Jr., J.T.2
  • 38
    • 0030172935 scopus 로고    scopus 로고
    • 2(110): The Extent of Molecular Versus Dissociative Adsorption
    • 2(110): The Extent of Molecular Versus Dissociative Adsorption Surf. Sci. 1996, 355, 151-166
    • (1996) Surf. Sci. , vol.355 , pp. 151-166
    • Henderson, M.A.1
  • 44
    • 0000531782 scopus 로고
    • 2(110) Studied by High-Resolution Electron-Energy-Loss Spectroscopy
    • 2(110) Studied by High-Resolution Electron-Energy-Loss Spectroscopy Phys. Rev. B 1984, 30, 3704-3708
    • (1984) Phys. Rev. B , vol.30 , pp. 3704-3708
    • Rocker, G.1    Schaefer, J.A.2    Gopel, W.3
  • 46
    • 4043165715 scopus 로고
    • 2(110) Surfaces: A Study by EELS
    • 2(110) Surfaces: A Study by EELS Surf. Sci. 1987, 180, 263-278
    • (1987) Surf. Sci. , vol.180 , pp. 263-278
    • Eriksen, S.1    Egdell, R.G.2
  • 49
    • 0344236131 scopus 로고    scopus 로고
    • Photochemical Charge Transfer and Trapping at the Interface between an Organic Adlayer and an Oxide Semiconductor
    • Henderson, M. A.; White, J. M.; Uetsuka, H.; Onishi, H. Photochemical Charge Transfer and Trapping at the Interface between an Organic Adlayer and an Oxide Semiconductor J. Am. Chem. Soc. 2003, 125, 14974-14975
    • (2003) J. Am. Chem. Soc. , vol.125 , pp. 14974-14975
    • Henderson, M.A.1    White, J.M.2    Uetsuka, H.3    Onishi, H.4
  • 52
    • 84865340571 scopus 로고    scopus 로고
    • 2 Complexes Bearing Macrocyclic N-Tetramethylated Cyclam Ligands
    • 2 Complexes Bearing Macrocyclic N-Tetramethylated Cyclam Ligands Acc. Chem. Res. 2012, 45, 1321-1330
    • (2012) Acc. Chem. Res. , vol.45 , pp. 1321-1330
    • Cho, J.1    Sarangi, R.2    Nam, W.3
  • 53
    • 33847798770 scopus 로고
    • Dioxygen-Metal Complexes: Toward a Unified View
    • Vaska, L. Dioxygen-Metal Complexes: Toward a Unified View Acc. Chem. Res. 1976, 9, 175-83
    • (1976) Acc. Chem. Res. , vol.9 , pp. 175-183
    • Vaska, L.1
  • 56
    • 20444492017 scopus 로고    scopus 로고
    • Structural Characteristics of Peroxo Complexes of Group IV and v Transition Metals. Review
    • Sergienko, V. S. Structural Characteristics of Peroxo Complexes of Group IV and V Transition Metals. Review Crystallogr. Rep. 2004, 49, 907-929
    • (2004) Crystallogr. Rep. , vol.49 , pp. 907-929
    • Sergienko, V.S.1
  • 59
    • 84862812018 scopus 로고    scopus 로고
    • Monomeric Peroxo Titanate Coordinated with Cyclohexanediaminetetraacetate: Towards the Active Oxygen Species of the Ti(IV) Site Hosted in the Titanium Silicalite Catalyst Ts-1
    • Liu, Q. X.; Zhou, Z. H. Monomeric Peroxo Titanate Coordinated with Cyclohexanediaminetetraacetate: Towards the Active Oxygen Species of the Ti(IV) Site Hosted in the Titanium Silicalite Catalyst Ts-1 Polyhedron 2012, 35, 1-6
    • (2012) Polyhedron , vol.35 , pp. 1-6
    • Liu, Q.X.1    Zhou, Z.H.2
  • 60
    • 0032700147 scopus 로고    scopus 로고
    • Activity of Peroxo and Hydroperoxo Complexes of Ti-IV in Olefin Epoxidation: A Density Functional Model Study of Energetics and Mechanism
    • Yudanov, I. V.; Gisdakis, P.; Di Valentin, C.; Rosch, N. Activity of Peroxo and Hydroperoxo Complexes of Ti-IV in Olefin Epoxidation: A Density Functional Model Study of Energetics and Mechanism Eur. J. Inorg. Chem. 1999, 2135-2145
    • (1999) Eur. J. Inorg. Chem. , pp. 2135-2145
    • Yudanov, I.V.1    Gisdakis, P.2    Di Valentin, C.3    Rosch, N.4
  • 62
    • 0000212825 scopus 로고    scopus 로고
    • Oxygen-17 NMR, Electronic, and Vibrational Spectroscopy of Transition Metal Peroxo Complexes: Correlation with Reactivity
    • Reynolds, M. S.; Butler, A. Oxygen-17 NMR, Electronic, and Vibrational Spectroscopy of Transition Metal Peroxo Complexes: Correlation with Reactivity Inorg. Chem. 1996, 35, 2378-2383
    • (1996) Inorg. Chem. , vol.35 , pp. 2378-2383
    • Reynolds, M.S.1    Butler, A.2
  • 63
    • 0038298368 scopus 로고    scopus 로고
    • A New Dinuclear Ti(IV)-Peroxo-Citrate Complex from Aqueous Solutions. Synthetic, Structural, and Spectroscopic Studies in Relevance to Aqueous Titanium(IV)-Peroxo-Citrate Speciation
    • Dakanali, M.; Kefalas, E. T.; Raptopoulou, C. P.; Terzis, A.; Voyiatzis, G.; Kyrikou, I.; Mavromoustakos, T.; Salifoglou, A. A New Dinuclear Ti(IV)-Peroxo-Citrate Complex from Aqueous Solutions. Synthetic, Structural, and Spectroscopic Studies in Relevance to Aqueous Titanium(IV)-Peroxo-Citrate Speciation Inorg. Chem. 2003, 42, 4632-4639
    • (2003) Inorg. Chem. , vol.42 , pp. 4632-4639
    • Dakanali, M.1    Kefalas, E.T.2    Raptopoulou, C.P.3    Terzis, A.4    Voyiatzis, G.5    Kyrikou, I.6    Mavromoustakos, T.7    Salifoglou, A.8
  • 65
    • 14744283615 scopus 로고    scopus 로고
    • Synthesis, Characterization, and Reactivity of Ti(IV)-Monosubstituted Keggin Polyoxometalates
    • Kholdeeva, O. A.; Trubitsina, T. A.; Maksimov, G. M.; Golovin, A. V.; Maksimovskaya, R. I. Synthesis, Characterization, and Reactivity of Ti(IV)-Monosubstituted Keggin Polyoxometalates Inorg. Chem. 2005, 44, 1635-1642
    • (2005) Inorg. Chem. , vol.44 , pp. 1635-1642
    • Kholdeeva, O.A.1    Trubitsina, T.A.2    Maksimov, G.M.3    Golovin, A.V.4    Maksimovskaya, R.I.5
  • 66
    • 84863348115 scopus 로고    scopus 로고
    • Tetravalent Titanium, Zirconium, and Cerium Oxo and Peroxo Complexes Containing an Imidodiphosphinate Ligand
    • Wang, G. C.; Sung, H. H. Y.; Williams, I. D.; Leung, W. H. Tetravalent Titanium, Zirconium, and Cerium Oxo and Peroxo Complexes Containing an Imidodiphosphinate Ligand Inorg. Chem. 2012, 51, 3640-3647
    • (2012) Inorg. Chem. , vol.51 , pp. 3640-3647
    • Wang, G.C.1    Sung, H.H.Y.2    Williams, I.D.3    Leung, W.H.4
  • 68
    • 14644413703 scopus 로고    scopus 로고
    • Syntheses and Photochemistry of Fluorinated and Chlorinated Titanium Porphyrinates: Crystal Structure of Oxotitanium meso -Tetrakis(2,3,4,5,6- pentafluorophenyl)porphyrinate
    • Esser, P. E.; Englert, U.; Keim, W. Syntheses and Photochemistry of Fluorinated and Chlorinated Titanium Porphyrinates: Crystal Structure of Oxotitanium meso -Tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrinate Chem. Ber. 1996, 129, 833-836
    • (1996) Chem. Ber. , vol.129 , pp. 833-836
    • Esser, P.E.1    Englert, U.2    Keim, W.3
  • 69
    • 38849209245 scopus 로고    scopus 로고
    • Active Peroxo Titanium Complexes: Syntheses, Characterization and Their Potential in the Photooxidation of 2-Propanol
    • Rohe, M.; Merz, K. Active Peroxo Titanium Complexes: Syntheses, Characterization and Their Potential in the Photooxidation of 2-Propanol Chem. Commun. 2008, 862-864
    • (2008) Chem. Commun. , pp. 862-864
    • Rohe, M.1    Merz, K.2
  • 70
    • 0001033925 scopus 로고
    • DRS UR-vis and EPR Spectroscopy of Hydroperoxo and Superoxo Complexes in Titanium Silicalite
    • Geobaldo, F.; Bordiga, S.; Zecchina, A.; Giamello, E.; Leofanti, G.; Petrini, G. DRS UR-vis and EPR Spectroscopy of Hydroperoxo and Superoxo Complexes in Titanium Silicalite Catal. Lett. 1992, 16, 109-115
    • (1992) Catal. Lett. , vol.16 , pp. 109-115
    • Geobaldo, F.1    Bordiga, S.2    Zecchina, A.3    Giamello, E.4    Leofanti, G.5    Petrini, G.6
  • 71
    • 34547530693 scopus 로고    scopus 로고
    • Interconvertible Side-On- and End-On-Bonded Oxo-Superoxo Titanium Ozonide Complexes
    • Gong, Y.; Zhou, M. F.; Tian, S. X.; Yang, J. L. Interconvertible Side-On- and End-On-Bonded Oxo-Superoxo Titanium Ozonide Complexes J. Phys. Chem. A 2007, 111, 6127-6130
    • (2007) J. Phys. Chem. A , vol.111 , pp. 6127-6130
    • Gong, Y.1    Zhou, M.F.2    Tian, S.X.3    Yang, J.L.4
  • 75
    • 50249167176 scopus 로고    scopus 로고
    • 2(110) Surface and on the Same Surface Precovered with Au(1) and Au(2): The Importance of Spin Conservation
    • 2(110) Surface and on the Same Surface Precovered with Au(1) and Au(2): The Importance of Spin Conservation. J. Chem. Phys. 2008, 129, 074705.
    • (2008) J. Chem. Phys. , vol.129 , pp. 074705
    • Chretien, S.1    Metiu, H.2
  • 76
    • 0034514386 scopus 로고    scopus 로고
    • Systematic Study of Oxo, Peroxo, and Superoxo Isomers of 3d-Metal Dioxides and Their Anions
    • Gutsev, G. L.; Rao, B. K.; Jena, P. Systematic Study of Oxo, Peroxo, and Superoxo Isomers of 3d-Metal Dioxides and Their Anions J. Phys. Chem. A 2000, 104, 11961-11971
    • (2000) J. Phys. Chem. A , vol.104 , pp. 11961-11971
    • Gutsev, G.L.1    Rao, B.K.2    Jena, P.3
  • 77
    • 0001275806 scopus 로고
    • Multiple-Scattering Analysis of NEXAFS Spectra of Molecular Oxygen Anions in Differently Grown Cesium Oxides
    • Pedio, M.; Benfatto, M.; Aminpirooz, S.; Haase, J. Multiple-Scattering Analysis of NEXAFS Spectra of Molecular Oxygen Anions in Differently Grown Cesium Oxides Phys. Rev. B 1994, 50, 6596-6602
    • (1994) Phys. Rev. B , vol.50 , pp. 6596-6602
    • Pedio, M.1    Benfatto, M.2    Aminpirooz, S.3    Haase, J.4
  • 78
    • 0000724884 scopus 로고
    • A Theoretical-Study of the Peroxo and Superoxo Forms of Molecular-Oxygen on Metal-Surfaces
    • Panas, I.; Siegbahn, P. A Theoretical-Study of the Peroxo and Superoxo Forms of Molecular-Oxygen on Metal-Surfaces Chem. Phys. Lett. 1988, 153, 458-464
    • (1988) Chem. Phys. Lett. , vol.153 , pp. 458-464
    • Panas, I.1    Siegbahn, P.2
  • 79
    • 0001650141 scopus 로고
    • Photochemistry of Peroxotitanium(IV) Porphyrin. A Novel Photocleavage of the Oxygen-Oxygen Bond
    • Hoshino, M.; Yamamoto, K.; Lillis, J. P.; Chijimatsu, T.; Uzawa, J. Photochemistry of Peroxotitanium(IV) Porphyrin. A Novel Photocleavage of the Oxygen-Oxygen Bond Inorg. Chem. 1993, 32, 5002
    • (1993) Inorg. Chem. , vol.32 , pp. 5002
    • Hoshino, M.1    Yamamoto, K.2    Lillis, J.P.3    Chijimatsu, T.4    Uzawa, J.5
  • 81
    • 0000978508 scopus 로고
    • Oxo[5,10,15,20-tetra(4-pyridyl)porphyrinato]titanium(IV): An Ultra-High Sensitivity Spectrophotometric Reagent for Hydrogen-Peroxide
    • Matsubara, C.; Kawamoto, N.; Takamura, K. Oxo[5,10,15,20-tetra(4-pyridyl) porphyrinato]titanium(IV): An Ultra-High Sensitivity Spectrophotometric Reagent for Hydrogen-Peroxide Analyst 1992, 117, 1781-1784
    • (1992) Analyst , vol.117 , pp. 1781-1784
    • Matsubara, C.1    Kawamoto, N.2    Takamura, K.3
  • 82
    • 0001576992 scopus 로고    scopus 로고
    • Metalloporphyrin Peroxo Complexes of Iron(III), Manganese(III), and Titanium(IV). Comparative Studies Demonstrating That the Iron(III) Complex Is Extremely Nucleophilic
    • Sisemore, M. F.; Selke, M.; Burstyn, J. N.; Valentine, J. S. Metalloporphyrin Peroxo Complexes of Iron(III), Manganese(III), and Titanium(IV). Comparative Studies Demonstrating That the Iron(III) Complex Is Extremely Nucleophilic Inorg. Chem. 1997, 36, 979-984
    • (1997) Inorg. Chem. , vol.36 , pp. 979-984
    • Sisemore, M.F.1    Selke, M.2    Burstyn, J.N.3    Valentine, J.S.4
  • 85
    • 0005400588 scopus 로고
    • Kinetics of the Reaction of Hydrogen Peroxide with Some Oxotitanium(IV) Complexes as Studied by a High-Pressure Stopped-Flow Technique
    • Inamo, M.; Funahashi, S.; Tanaka, M. Kinetics of the Reaction of Hydrogen Peroxide with Some Oxotitanium(IV) Complexes as Studied by a High-Pressure Stopped-Flow Technique Inorg. Chem. 1983, 22, 3734
    • (1983) Inorg. Chem. , vol.22 , pp. 3734
    • Inamo, M.1    Funahashi, S.2    Tanaka, M.3
  • 86
    • 0001559365 scopus 로고
    • A Structurally Characterized Mononuclear Copper(II)-Superoxo Complex
    • Harata, M.; Jitsukawa, K.; Masuda, H.; Einaga, H. A Structurally Characterized Mononuclear Copper(II)-Superoxo Complex J. Am. Chem. Soc. 1994, 116, 10817-10818
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 10817-10818
    • Harata, M.1    Jitsukawa, K.2    Masuda, H.3    Einaga, H.4
  • 87
    • 77951685236 scopus 로고    scopus 로고
    • An "end-On" Chromium(III)-Superoxo Complex: Crystallographic and Spectroscopic Characterization and Reactivity in C-H Bond Activation of Hydrocarbons
    • Cho, J.; Woo, J.; Nam, W. An "End-On" Chromium(III)-Superoxo Complex: Crystallographic and Spectroscopic Characterization and Reactivity in C-H Bond Activation of Hydrocarbons J. Am. Chem. Soc. 2010, 132, 5958-5959
    • (2010) J. Am. Chem. Soc. , vol.132 , pp. 5958-5959
    • Cho, J.1    Woo, J.2    Nam, W.3
  • 89
    • 24944574731 scopus 로고    scopus 로고
    • 2 and Vacancy Diffusion on Rutile(110): Pathways and Electronic Properties
    • 2 and Vacancy Diffusion on Rutile(110): Pathways and Electronic Properties ChemPhysChem 2005, 6, 1911-1916
    • (2005) ChemPhysChem , vol.6 , pp. 1911-1916
    • Tilocca, A.1    Selloni, A.2
  • 110


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.