Control of a surface photochemical process by fractal electron transport across the surface: O2 photodesorption from TiO2(110)

Journal of Physical Chemistry B

Volumn 110, Issue 14, 2006, Pages 7431-7435

  Thompson, Tracy L ^a   Yates Jr , John T ^a  

^a UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DESORPTION; FRACTALS; PERCOLATION (SOLID STATE); PHOTOCHEMICAL REACTIONS; SURFACE PROPERTIES; TITANIUM OXIDES;

ELECTRON PERCOLATION; FILLED ORBITALS; KINETIC BEHAVIORS; PHOTOPRODUCED HOLES;

ELECTRON TRANSITIONS;

EID: 33646256815     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0562126     Document Type: Article

References (31)

1. Kamat, P. V. Prog. React. Kinet. 1994, 19, 277-316.
2. Mora-Sero, I.; Dittrich, T.; Belaidi, A.; Garcia-Belmonte, G.; Bisquert, J. J. Phys. Chem. B 2005, 109, 14932-14938.
3. Leng, W. H.; Zhang, Z.; Zhang, J. Q.; Cao, C. N. J. Phys. Chem. B 2005, 109, 15008-15023.
4. Finger, M.; Haeger, A.; Hesse, D. Chem. Eng. Technol. 2005, 28, 783-789.
5. Berger, T.; Sterrer, M.; Diwald, O.; Knözinger, E. ChemPhysChem 2005, 6, 2104-2112.
6. Fox, M. A.; Dulay, M. T. Chem. Rev. 1993, 93, 341-357.
7. Henderson, M. A.; Epling, W. S.; Perkins, C. L.; Peden, C. H. F.; Diebold, U. J. Phys. Chem. B 1999, 105, 5328-5337.
8. Lu, G. Q.; Linsebigler, A.; Yates, J. T., Jr. J. Phys. Chem. 1994, 98, 11733-11738.
9. Lu, G. Q.; Linsebigler, A.; Yates, J. T., Jr. J. Chem. Phys. 1995, 102, 4657-4662.
10. Rasmussen, M. D.; Molina, L. M.; Hammer, B. J. Chem. Phys. 2004, 120, 988-997.
11. Pan, J. M.; Maschhoff, B. L.; Diebold, U.; Madey, T. E. J. Vac. Sci. Technol., A 1992, 10, 2470-2476.
12. Diebold, U. Surf. Sci. Rep. 2003, 48, 53-229.
13. Anpo, M.; Che, M.; Fubini, B.; Garrone, E.; Giamello, E.; Paganini, M. C. Top. Catal. 1999, 8, 189-198.
14. de Lara-Castells, M. P.; Krause, J. L. Chem. Phys. Lett. 2002, 354, 483-490.
15. de Lara-Castells, M. P.; Krause, J. L. J. Chem. Phys. 2001, 115, 4798-4810.
16. de Lara-Castells, M. P.; Krause, J. L. J. Chem. Phys. 2003, 118, 5098-5105.
17. Linsebigler, A. L.; Lu, G. Q.; Yates, J. T., Jr. Chem. Rev. 1995, 95, 735-758.
18. Thompson, T. L.; Yates, J. T., Jr. Top. Catal. 2005, 35, 197-210.
19. Thompson, T. L.; Yates, J. T., Jr. J. Phys. Chem. B 2005, 109, 18230-18236.
20. Yates, J. T., Jr. Experimental Innovations in Surface Science; AIP and Springer-Verlag: New York, 1998.
21. Thompson, T. L.; Diwald, O.; Yates, J. T., Jr. J. Phys. Chem. B 2003, 107, 11700-11704.
22. Yates, J. T., Jr. The Thermal Desorption of Adsorbed Species. In Methods of Experimental Physics; Park, R. L., Ed.; Academic Press: New York, 1985; Vol. 22.
23. Lu, G. Q.; Linsebigler, A.; Yates, J. T., Jr. J. Chem. Phys. 1995, 102, 3005-3008.
24. Rusu, C. N.; Yates, J. T., Jr. Langmuir 1997, 13, 4311-4316.
25. 2 films of varying thickness (0-60 Å). The actual measured mean absorption length was 103 Å. We thank Dr. Tykhon Zubkov for these measurements. See Zubkov et al. J. Phys Chem. B. 2005, 109, 15454-15462.
26. Kopelman, R. Science 1988, 241, 1620-1626.
27. Kopelman, R. J. Stat. Phys. 1986, 42, 185-201.
28. Kopelman, R. Diffusion-controlled Reaction Kinetics. In The Fractal Approach to Heterogeneous Chemistry: Surfaces Colloids and Polymers; Avnir, D., Ed.; John Wiley and Sons: New York, 1989; pp 295-309.
29. Vijay, A.; Mills, G.; Metiu, H. J. Chem. Phys. 2003, 118, 6536-6551.
30. 2 single crystals exhibit an inherent anisotropy in bulk electrical conductivity. See: (a) Temga, T.; Guerret-Piecourt, C.; Juve, O.; Treheux, O. IEEE Annu. Rep. CEIDP, IEEE 02CH37372 2002, 656-659.
31. (b) Hollander, L. E., Jr.; Castro, P. L. Phys. Rev. 1960, 119, 1882-1885.