Monomer formation model versus chain growth model of the Fischer-Tropsch reaction

Journal of Physical Chemistry C

Volumn 117, Issue 9, 2013, Pages 4488-4504

  Van Santen, Rutger A ^a   Markvoort, Albert J ^a   Ghouri, Minhaj M ^a   Hilbers, Peter A J ^a   Hensen, Emiel J M ^a  

^a EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC REACTIONS; FISCHER-TROPSCH REACTION; HETEROGENEOUS CATALYTIC REACTIONS; HIGH ACTIVATION ENERGY; HYDROCARBON CHAINS; INSERTION POLYMERIZATION; INTERMEDIATE REACTIVITY; RATE-CONTROLLING STEPS;

ACTIVATION ENERGY; CATALYSIS; CHEMICAL BONDS; HYDROCARBONS; QUANTUM CHEMISTRY; SURFACE MORPHOLOGY; SYNTHESIS GAS;

MONOMERS;

EID: 84874873254     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp310245m     Document Type: Article

References (113)

1. Storch, H. H.; Golumbic, N.; Anderson, R. B. The Fischer-Tropsch and Related Syntheses; John Wiley & Sons: New York, 1951.
2. Anderson, R. B.; Kölbel, H.; Rálek, M. The Fischer-Tropsch Synthesis; Academic Press: New York, 1984.
3. Steynberg, A. P.; Dry, M. E. Fischer-Tropsch Technology; Elsevier: Amsterdam, 2004; Vol. 152.
4. Bartholomew, C. H.; Farrauto, R. J. Fundamentals of Industrial Catalytic Processes, 2 nd ed.; John Wiley and Sons, Inc.: Hoboken, NJ, 2005.
5. Fischer, F.; Tropsch, H. Brenstoff-Chem 1926, 7, 97-116
6. Hammer, B.; Nørskov, J. K. Theoretical Surface Science and Catalysis-Calculations and Concepts Adv. Catal. 2000, 45, 71-129
7. van Santen, R. A.; Neurock, M., Molecular Heterogeneous Catalysis; Wiley-VCH: New York, 2006.
8. Nilsson, A.; Petterson, L. G. M.; Norskov, J. K. Chemical Bonding at Surfaces and Interfaces, 1 st ed.; Elsevier Science: Amsterdam, 2007.
9. Valero, M. C.; Raybaud, P. Cobalt Catalyzed Fischer-Tropsch Synthesis: Perspectives Opened by First Principles Calculations Catal. Lett. 2013, 143, 1
10. Inderwildi, O. R.; Jenkins, S. J. In-silico Investigations in Heterogeneous Catalysis-Combustion and Synthesis of Small Alkanes Chem. Soc. Rev. 2008, 37, 2274-2309
11. van Santen, R. A.; Neurock, M.; Shetty, S. Reactivity Theory of Transition-Metal Surfaces: A Brønsted-Evans-Polanyi Linear Activation Energy-Free-Energy Analysis Chem. Rev. 2010, 110 (4) 2005-2048
12. Iglesia, E.; Reyes, S. C.; Madon, R. J.; Soled, S. L. Selectivity Control and Catalyst Design in the Fischer-Tropsch Synthesis: Sites, Pellets, and Reactors Adv. Catal. 1993, 39, 221-302
13. Lozano-Blanco, G.; Thybaut, J. W.; Surla, K.; Galtier, P.; Marin, G. B. Fischer-Tropsch Synthesis: Development of a Microkinetic Model for Metal Catalysis Oil Gas Sci. Technol. 2006, 61 (4) 489-496
14. Lozano-Blanco, G.; Thybaut, J. W.; Surla, K.; Galtier, P.; Marin, G. B. Single-Event Microkinetic Model for Fischer-Tropsch Synthesis on Iron-Based Catalysts Ind. Eng. Chem. Res. 2008, 47 (16) 5879-5891
15. 3 Fischer-Tropsch Catalyst Ind. Eng. Chem. Res. 2009, 48, 10439-10447
16. Huff, G. A.; Satterfield, C. N. Intrinsic Kinetics of the Fischer-Tropsch Synthesis on a Reduced Fused-Magnetite Catalyst Ind. Eng. Chem. Proc. D 1984, 23, 696-705
17. Yates, I. C.; Satterfield, C. N. Intrinsic Kinetics of the Fischer-Tropsch Synthesis on a Cobalt Catalyst Energy Fuels 1991, 5, 168-173
18. van Steen, E.; Schulz, H. Polymerisation Kinetics of the Fischer-Tropsch CO Hydrogenation using Iron and Cobalt based Catalysts Appl. Catal. A: Gen. 1999, 186, 309-320
19. Bell, A. T. Catalytic Synthesis of Hydrocarbons over Group VIII Metals. A Discussion of the Reaction Mechanism Catal. Rev. 1981, 23, 203-322
20. Outi, A.; Rautavuoma, I.; van der Baan, H. S. Kinetics and Mechanism of the Fischer-Tropsch Hydrocarbon Synthesis on a Cobalt on Alumina catalyst Appl. Catal. 1981, 1, 247-272
21. Lox, E. S.; Froment, G. F. Kinetics of the Fischer-Tropsch Reaction on a Precipitated Promoted Iron Catalyst. 2. Kinetic modeling Ind. Eng. Chem. Res. 1993, 32, 71-82
22. Van der Laan, G. P.; Beenackers, A. A. C. M. Kinetics and Selectivity of the Fischer-Tropsch Synthesis: A Literature Review Catal. Rev. 1999, 41, 255-318
23. van der Laan, G. P.; Beenackers, A. A. C. M. Hydrocarbon Selectivity Model for the Gas-Solid Fischer-Tropsch Synthesis on Precipitated Iron Catalysts Ind. Eng. Chem. Res. 1999, 38, 1277-1290
24. Wojciechowski, B. W. The Kinetics of the Fischer-Tropsch Synthesis Catal. Rev. 1988, 30, 629-702
25. Zennaro, R.; Tagliabue, M.; Bartholomew, C. H. Kinetics of Fischer-Tropsch Synthesis on Titania-Supported Cobalt Catal. Today 2000, 58, 309-319
26. Iglesia, E.; Reyes, S. C.; Madon, R. J. Transport-Enhanced α-Olefin Readsorption Pathways in Ru-Catalyzed Hydrocarbon Synthesis J. Catal. 1991, 129, 238-256
27. Iglesia, E. Design, Synthesis, and Use of Cobalt-based Fischer-Tropsch Synthesis Catalysts Appl. Catal., A 1997, 161, 59-78
28. Lee, W. H.; Bartholomew, C. H. Multiple Reaction States in CO Hydrogenation on Alumina-supported Cobalt Catalysts J. Catal. 1989, 120, 256-271
29. Bartholomew, C. H., Recent Developments in Fischer-Tropsch Catalysis. In Studies in Surface Science and Catalysis: New Trends in CO Activation; Guczi, L., Ed.; Elsevier B.V.: Waltham, MA, 1991; Vol. 64, pp 158-224.
30. Rameswaran, M.; Bartholomew, C. H. Effects of Preparation, Dispersion, and Extent of Reduction on Activity/Selectivity Properties of Iron/Alumina CO Hydrogenation Catalysts J. Catal. 1989, 117, 218-236
31. Schulz, H. Major and Minor Reactions in Fischer-Tropsch Synthesis on Cobalt Catalysts Top. Catal. 2003, 26, 73-85
32. Geerlings, J. J. C.; Zonnevylle, M. C.; de Groot, C. P. M. Structure Sensitivity of the Fischer-Tropsch Reaction on Cobalt Single Crystals Surf. Sci. 1991, 241, 315-324
33. Wilson, J.; de Groot, C. Atomic-Scale Restructuring in High-Pressure Catalysis J. Phys. Chem. 1995, 99, 7860-7866
34. Davis, B. H. Fischer-Tropsch Synthesis: Current Mechanism and Futuristic Needs Fuel Process. Technol. 2001, 71, 157-166
35. Maitlis, P. M.; Quyoum, R.; Long, H. C.; Turner, M. L. Towards a Chemical Understanding of the Fischer-Tropsch Reaction: Alkene Formation Appl. Catal., A 1999, 186, 363-374
36. Overett, M. J.; Hill, R. O.; Moss, J. R. Organometallic Chemistry and Surface Science: Mechanistic Models for the Fischer-Tropsch Synthesis Coord. Chem. Rev. 2000, 206-207, 581-605
37. Ciobiîca, I. M.; Kramer, G. J.; Ge, Q.; Neurock, M.; van Santen, R. A. Mechanisms for Chain Growth in Fischer-Tropsch Synthesis over Ru(0001) J. Catal. 2002, 212, 136-144
38. Liu, Z.-P.; Hu, P. A New Insight into Fischer-Tropsch Synthesis J. Am. Chem. Soc. 2002, 124, 11568-11569
39. Liu, Z.-P.; Hu, P. General Rules for Predicting Where a Catalytic Reaction Should Occur on Metal Surfaces: A Density Functional Theory Study of C-H and C-O Bond Breaking/Making on Flat, Stepped, and Kinked Metal Surfaces J. Am. Chem. Soc. 2003, 125, 1958-1967
40. Ciobiîca, I. M.; van Santen, R. A. Carbon Monoxide Dissociation on Planar and Stepped Ru(0001) Surfaces J. Phys. Chem. B 2003, 107, 3808-3812
41. Ge, Q.; Neurock, M. Adsorption and Activation of CO over Flat and Stepped Co Surfaces: A First Principles Analysis J. Phys. Chem. B 2006, 110, 15368-15380
42. 2-Induced CO Dissociation on Nickel Surfaces J. Catal. 2008, 255, 6-19
43. Cheng, J.; Gong, X.-Q.; Hu, P.; Lok, C. M.; Ellis, P.; French, S. A Density Functional Theory Study of the α-Olefin Selectivity in Fischer-Tropsch Synthesis J. Catal. 2008, 255, 20-28
44. Cheng, J.; Hu, P.; Ellis, P.; French, S.; Kelly, J.; Lok, C. M. Chain Growth Mechanism in Fischer-Tropsch Synthesis: A DFT Study of C-C Coupling over Ru, Fe, Rh, and Re Surfaces J. Phys. Chem. C 2008, 112, 6082-6086
45. Inderwildi, O. R.; Jenkins, S. J.; King, D. A. Fischer-Tropsch Mechanism Revisited: Alternative Pathways for the Production of Higher Hydrocarbons from Synthesis Gas J. Phys. Chem. C 2008, 112, 1305-1307
46. Cheng, J.; Gong, X.-Q.; Hu, P.; Lok, C. M.; Ellis, P.; French, S. A Quantitative Determination of Reaction Mechanisms from Density Functional Theory Calculations: Fischer-Tropsch Synthesis on Flat and Stepped Cobalt Surfaces J. Catal. 2008, 254, 285-295
47. Shetty, S.; Jansen, A. P. J.; van Santen, R. A. Direct versus Hydrogen-Assisted CO Dissociation J. Am. Chem. Soc. 2009, 131, 12874-12875
48. Zhuo, M.; Tan, K. F.; Borgna, A.; Saeys, M. Density Functional Theory Study of the CO Insertion Mechanism for Fischer-Tropsch Synthesis over Co Catalysts J. Phys. Chem. C 2009, 113, 8357-8365
49. Ojeda, M.; Nabar, R.; Nilekar, A. U.; Ishikawa, A.; Mavrikakis, M.; Iglesia, E. CO Activation Pathways and the Mechanism of Fischer-Tropsch Synthesis J. Catal. 2010, 272, 287-297
50. van Santen, R. A.; Ciobiîca, I. M.; van Steen, E.; Ghouri, M. M. Mechanistic Issues in Fischer-Tropsch Catalysis Adv. Catal. 2011, 54, 127-187
51. Mirwald, J. W.; Inderwildi, O. R. Unraveling the Fischer-Tropsch Mechanism: a Combined DFT and Microkinetic Investigation of C-C bond Formation on Ru Phys. Chem. Chem. Phys. 2012, 14, 7028-7031
52. Lo, J. M. H.; Ziegler, T.; First-Principle, A. Study of Chain Propagation Steps in the Fischer-Tropsch Synthesis on Fe(100) J. Phys. Chem. C 2008, 112, 13681-13691
53. 2 Hydrocarbon Species on the Fe(100) Surface J. Phys. Chem. C 2007, 111, 13149-13162
54. Bromfield, T. C.; Ferré, D. C.; Niemantsverdriet, J. W. A DFT Study of the Adsorption and Dissociation of CO on Fe(100): Influence of Surface Coverage on the Nature of Accessible Adsorption States ChemPhysChem 2005, 6, 254-260
55. Ge, Q.; Neurock, M.; Wright, H. A.; Srinivasan, N. A First Principles Study of Carbon-Carbon Coupling over the {0001} Surfaces of Co and Ru J. Phys. Chem. B 2002, 106, 2826-2829
56. Gokhale, A. A.; Mavrikakis, M. M. Early Fischer-Tropsch Steps on Fe(110) and Co(0001) Surfaces: Comparative DFT studies, Preprints of Symposia; American Chemical Society, Division of Fuel Chemistry: Washington, DC, 2005; p 149.
57. Anderson, R. B. In Hydrocarbon Synthesis, Hydrogenation and Cyclization; Emmett, P. H., Ed.; Reinhold Publishing: New York, 1956; Vol. IV.
58. Gong, X.-Q.; Raval, R.; Hu, P. CO Dissociation and O Removal on Co(0001): A Density Functional Theory Study Surf. Sci. 2004, 562, 247-256
59. Liu, Z.-P.; Hu, P. General Trends in CO Dissociation on Transition Metal Surfaces J. Chem. Phys. 2001, 114, 8244-8247
60. Engbæk, J.; Lytken, O.; Nielsen, J. H.; Chorkendorff, I. CO Dissociation on Ni;The Effect of Steps and of Nickel Carbonyl Surf. Sci. 2008, 602, 733-743
61. van Helden, P.; van den Berg, J.-A.; Ciobiîca, I. M. Hydrogen-Assisted CO Dissociation on the Co(211) Stepped Surface Catal. Sci. Technol. 2012, 2, 491-494
62. 1 Fragments on Metal Surfaces J. Am. Chem. Soc. 1988, 110, 749-774
63. van Santen, R. A.; Ghouri, M. M.; Shetty, S.; Hensen, E. J. M. Structure Sensitivity of the Fischer-Tropsch Reaction; Molecular Kinetics Simulations Catal. Sci. Tecnol. 2011, 1, 891-911
64. 2 (Recent Results in the Synthesis of Hydrocarbons from Carbon Monoxide and Hydrogen) Chem. Eng. Technol. 1970, 42, 1162-1174
65. Gaube, J.; Klein, H. F. Studies on the Reaction Mechanism of the Fischer-Tropsch Synthesis on Iron and Cobalt J. Mol. Catal., A 2008, 283, 60-68
66. Brady, R. C., III; Pettit, R. Mechanism of the Fischer-Tropsch Reaction. The Chain Propagation Step J. Am. Chem. Soc. 1981, 103, 1287-1289
67. Ciobiîca, I. M.; Frechard, F.; van Santen, R. A.; Kleyn, A. W.; Hafner, J. A DFT Study of Transition States for C-H Activation on the Ru(0001) Surface J. Phys. Chem. B 2000, 104, 3364-3369
68. x Chemisorption and Transition States for C-H Activation on the Ru(11 2 0) Surface J. Phys. Chem. B 2002, 106, 6200-6205
69. van Grootel, P. W.; Hensen, E. J. M.; van Santen, R. A. The CO Formation Reaction Pathway in Steam Methane Reforming by Rhodium Langmuir 2010, 26, 16339-16348
70. Shetty, S.; Ciobiîca, I. M.; Hensen, E. J. M.; van Santen, R. A. Site Regeneration in the Fischer-Tropsch Synthesis Reaction: a Synchronized CO Dissociation and C-C Coupling Pathway Chem. Commun. 2011, 47, 9822-9824
71. Kellner, C. S.; Bell, A. T. The Kinetics and Mechanism of Carbon Monoxide Hydrogenation over Alumina-supported Ruthenium J. Catal. 1981, 70, 418-432
72. van Dijk, H. A. J. The Fischer-Tropsch Synthesis: A Mechanistic Study using Transient Isotopic Tracing; Technische Universiteit Eindhoven: Eindhoven, 2001.
73. van Dijk, H. A. J.; Hoebink, J. H. B. J.; Schouten, J. C. A Mechanistic Study of the Fischer-Tropsch Synthesis Using Transient Isotopic Tracing. Part 1: Model Identification and Discrimination Top. Catal. 2003, 26, 111-119
74. Van Dijk, H. A. J.; Hoebink, J. H. B. J.; Schouten, J. C. A Mechanistic Study of the Fischer-Tropsch Synthesis Using Transient Isotopic Tracing. Part 2: Model Quantification Top. Catal. 2003, 26, 163-171
75. Visconti, C. G.; Tronconi, E.; Lietti, L.; Forzatti, P.; Rossini, S.; Zennaro, R. Detailed Kinetics of the Fischer-Tropsch Synthesis on Cobalt Catalysts Based on H-Assisted CO Activation Top. Catal. 2011, 54, 786-800
76. Beitel, G. A.; de Groot, C. P. M.; Oosterbeek, H.; Wilson, J. H. A Combined in-Situ PM-RAIRS and Kinetic Study of Single-Crystal Cobalt Catalysts under Synthesis Gas at Pressures up to 300 mbar J. Phys. Chem. B 1997, 101, 4035-4043
77. Beitel, G. A.; Laskov, A.; Oosterbeek, H.; Kuipers, E. W. Polarization Modulation Infrared Reflection Absorption Spectroscopy of CO Adsorption on Co(0001) under a High-Pressure Regime J. Phys. Chem. 1996, 100, 12494-12502
78. 2 J. Catal. 1994, 150, 400-406
79. van Dijk, H. A. J.; Hoebink, J. H. B. J.; Schouten, J. C. A Steady State Isotopic Transient Kinetic Analysis of the Fischer-Tropsch Synthesis Reaction over a Cobalt Based Catalyst Stud. Surf. Sci. Catal. 2000, 130, 383-388
80. Biloen, P.; Helle, J. N.; van den Berg, F. G. A.; Sachtler, W. M. H. On the Activity of Fischer-Tropsch and Methanation Catalysts: A Study Utilizing Isotopic Transients J. Catal. 1983, 81, 450-463
81. Zhang, X.; Biloen, P. A Transient Kinetic Observation of Chain Growth in the Fischer-Tropsch Synthesis J. Catal. 1986, 98, 468-476
82. 2 Products in the Fischer-Tropsch Synthesis over Cobalt Catalysts Surf. Sci. 2006, 600, 2051-2063
83. Shustorovich, E.; Sellers, H. The UBI-QEP Method: A Practical Theoretical Approach to Understanding Chemistry on Transition Metal Surfaces Surf. Sci. Rep. 1998, 31, 1-119
84. Biloen, P.; Helle, J. W.; Sachtler, W. M. H. Incorporation of Surface Carbon into Hydrocarbons during Fischer-Tropsch Synthesis: Mechanistic Implications J. Catal. 1979, 58, 95-107
85. Biloen, P.; Sachtler, W. M. H. Mechanism of Hydrocarbon Synthesis over Fischer-Tropsch Catalysts Adv. Catal. 1981, 30, 165-216
86. 2/CO Reactant Ratio for Hydrocarbon Chain Growth on Ruthenium Catalysts J. Catal. 1993, 139, 576-590
87. Quyoum, R.; Berdini, V.; Turner, M. L.; Long, H. C.; Maitlis, P. M. Mechanistic Studies of Methylene Chain Propagation in the Fischer-Tropsch Synthesis J. Catal. 1998, 173, 355-365
88. Markvoort, A. J.; Van Santen, R. A.; Hilbers, P. A. J.; Hensen, E. J. M. Kinetics of the Fischer-Tropsch Reaction Angew. Chem., Int. Ed. 2012, 51, 9015-9019
89. Maitlis, P. M.; Zanotti, V. The Role of Electrophilic Species in the Fischer-Tropsch Reaction Chem. Commun. 2009, 1619-1634
90. 13C NMR Spectroscopy of Regiospecific Carbon-Carbon Coupling during Fischer-Tropsch Probe Reactions J. Am. Chem. Soc. 1999, 121, 6497-6498
91. van Santen, R. A.; Ghouri, M. M.; Markvoort, A. J.; Hensen, E. J. M. The molecular kinetics of the Fischer-Tropsch reaction. 2012, Manuscript in preparation.
92. van Santen, R. A. Complementary Structure Sensitive and Insensitive Catalytic Relationships Acc. Chem. Res. 2009, 42, 57-66
93. Shetty, S.; Jansen, A. P. J.; van Santen, R. A. CO Dissociation on the Ru(11 2 1) Surface J. Phys. Chem. C 2008, 112, 14027-14033
94. Lide, D. R. Handbook of Chemistry and Physics, 74 th ed.; CRC Press: Boca Raton, FL, 1993-1994.
95. Markvoort, A. J.; ten Eikelder, H. M. M.; Hilbers, P. A. J.; de Greef, T. F. A.; Meijer, E. W. Theoretical Models of Nonlinear Effects in Two-component Cooperative Supramolecular Copolymerizations Nat. Commun. 2011, 2, 509
96. ten Eikelder, H. M. M.; Markvoort, A. J.; de Greef, T. F. A.; Hilbers, P. A. J. An Equilibrium Model for Chiral Amplification in Supramolecular Polymers J. Phys. Chem. B 2012, 116, 5291-5301
97. Bertole, C. J.; Kiss, G.; Mims, C. A. The Effect of Surface-active Carbon on Hydrocarbon Selectivity in the Cobalt-catalyzed Fischer-Tropsch Synthesis J. Catal. 2004, 223, 309-318
98. Andersson, M. P.; Bligaard, T.; Kustov, A.; Larsen, K. E.; Greeley, J.; Johannessen, T.; Christensen, C. H.; Nørskov, J. K. Toward Computational Screening in Heterogeneous Catalysis: Pareto-optimal Methanation Catalysts J. Catal. 2006, 239, 501-506
99. Abild-Pedersen, F.; Studt, F.; Rossmeisl, J.; Munter, T. R.; Moses, P. G.; Skúlason, E.; Bligaard, T.; Nørskov, J. K. Scaling Properties of Adsorption Energies for Hydrogen-Containing Molecules on Transition-Metal Surfaces Phys. Rev. Lett. 2007, 99, 016105
100. Jones, G.; Jakobsen, J. G.; Shim, S. S.; Kleis, J.; Andersson, M. P.; Rossmeisl, J.; Abild-Pedersen, F.; Bligaard, T.; Helveg, S.; Hinnemann, B. First Principles Calculations and Experimental Insight into Methane Steam Reforming over Transition Metal Catalysts J. Catal. 2008, 259, 147-160
101. Enger, B. C.; Holmen, A. Nickel and Fischer-Tropsch Synthesis Catal. Rev. 2012, 54, 437-488
102. x Chemisorption on the Ru(0001) Surface Chem. Phys. Lett. 1999, 311, 185-192
103. Klinke, D. J.; Broadbelt, L. J. Construction of a Mechanistic Model of Fischer-Tropsch Synthesis on Ni(111) and Co(0001) surfaces Chem. Eng. Sci. 1999, 54, 3379-3389
104. van Santen, R. A.; Niemantsverdriet, J. W. Chemical Kinetics and Catalysis; Plenum Press: London, 1995.
105. 2 Reaction over Co-MgO Catalysts J. Phys. Chem. C 2010, 114, 2248-2255
106. Ribiero, F. H.; Schach von Wittenau, A. E.; Bartholomew, C. H.; Somorjai, G. Reproducibility of Turnover Rates in Heterogeneous Metal Catalysis: Compilation of Data and Guidelines for Data Analysis Catal. Rev. 1997, 39, 49-76
107. 2 Fischer-Tropsch Synthesis Catalysts; Brigham Young University: Provo, UT, 2000.
108. Bezemer, G. L.; Bitter, J. H.; Kuipers, H. P. C. E.; Oosterbeek, H.; Holewijn, J. E.; Xu, X.; Kapteijn, F.; van Dillen, A. J.; de Jong, K. P. Cobalt Particle Size Effects in the Fischer-Tropsch Reaction Studied with Carbon Nanofiber Supported Catalysts J. Am. Chem. Soc. 2006, 128, 3956-3964
109. Martínez, A.; Prieto, G. Breaking the Dispersion-reducibility Dependence in Oxide-supported Cobalt Nanoparticles J. Catal. 2007, 245, 470-476
110. 2 Catalysts: Influence of Dispersion in the Fischer-Tropsch Reaction J. Catal. 2001, 200, 106-116
111. Reuel, R. C.; Bartholomew, C. H. Effects of Support and Dispersion on the CO Hydrogenation Activity/Selectivity Properties of Cobalt J. Catal. 1984, 85, 78-88
112. Jones, V. K.; Neubauer, L. R.; Bartholomew, C. H. Effects of Crystallite Size and Support on the Carbon Monoxide Hydrogenation Activity/Selectivity Properties of Iron/Carbon J. Phys. Chem. 1986, 90, 4832-4839
113. Galvis, H. M. T.; Bitter, J. H.; Khare, C. B.; Ruitenbeek, M.; Dugulan, A. I.; de Jong, K. P. Supported Iron Nanoparticles as Catalysts for Sustainable Production of Lower Olefins Science 2012, 335, 835-838