Hydrocarbon selectivity model for the gas-solid Fischer-Tropsch synthesis on precipitated iron catalysts

Industrial and Engineering Chemistry Research

Volumn 38, Issue 4, 1999, Pages 1277-1290

  Van Der Laan, Gerard P ^a   Beenackers, Antonie A C M ^a  

^a UNIVERSITY OF GRONINGEN   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; HYDROCARBONS; IRON; MATHEMATICAL MODELS; MOLECULAR STRUCTURE; OLEFINS; PARAFFINS; REACTION KINETICS; SILICA; SOLUBILITY; SYNTHESIS (CHEMICAL);

ANDERSON-SCHULZ-FLORY DISTRIBUTION;

FISCHER-TROPSCH SYNTHESIS;

ALKENE DERIVATIVE; COPPER; ETHYLENE; HYDROCARBON; IRON; METHANE; PARAFFIN; POTASSIUM; SILICON DIOXIDE;

CATALYST; GAS-SOLID MIXING; HYDROCARBON;

ADSORPTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; EXPERIMENTAL MODEL; METHYLATION; PRECIPITATION; REACTION ANALYSIS; REACTION TIME; SOLUBILITY; SYNTHESIS;

EID: 0032946903     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie980561n     Document Type: Article

References (55)

1. Fox, J. M., III. The different catalytic routes for methane valorization: an assessment of processes for liquid fuels. Catal. Rev.-Sci. Eng. 1993, 35, 169-212.
2. Gregor, J. H. Fischer-Tropsch products as liquid fuels or chemicals. An economical evaluation. Catal. Lett. 1990, 7, 317-332.
3. Adesina, A. A. Hydrocarbon synthesis via Fischer-Tropsch reaction: travails and triumphs, Appl. Catal. A 1996, 138, 345-367.
4. Anderson, R. B. Catalysts for the Fischer-Tropsch Synthesis; Van Nostrand Reinhold: New York, 1956, Vol. 4.
5. Bell, A. T. Catalytic synthesis of hydrocarbons over group VIII metals. A discussion on the reaction mechanism. Catal. Rev.-Sci. Eng. 1981, 23, 203-232.
6. Dry, M. E. The Fischer-Tropsch synthesis. In Anderson, J. R., Boudart, M., Eds.; Catalysis-Science and Technology; Springer-Verlag: New York, 1981; Vol. 1, pp 160-255.
7. Glebov, L. S.; Kliger, G. A. The molecular weight distribution of the products of the Fischer-Tropsch synthesis. Russ. Chem. Rev. 1994, 63, 185-194.
8. Wojciechowski, B. W. The kinetics of the Fischer-Tropsch synthesis, Catal. Rev.-Sci. Eng. 1988, 30, 629-702.
9. 2. J. Catal. 1994, 146, 237-248.
10. Schulz, H.; Van Steen, E.; Claeys, M. Olefin formation, hydrogenation and isomerization in the kinetic regime of Fischer-Tropsch synthesis. In Selective hydrogenation and dehydrogenation; DGMK: Kassel, Germany, 1993.
11. Kuipers, E. W.; Scheper, C.; Wilson, J. H.; Oosterbeek, H. Non-ASF product distributions due to secondary reactions during Fischer-Tropsch synthesis. J. Catal. 1996, 158, 288-300.
12. Novak, S.; Madon, R. J.; Suhl, H. Models of hydrocarbon product distributions in Fischer-Tropsch synthesis. J. Chem. Phys. 1981, 74, 6083-6091.
13. Van der Laan, G. P.; Beenackers, A. A. C. M. Kinetics and selectivity of the Fischer-Tropsch synthesis. A literature review. Accepted for publication in Catal. Rev.-Sci. Eng. 1999.
14. Iglesia, E.; Reyes, S. C.; Soled, S. L. Reaction-transport selectivity models and the design of Fischer-Tropsch catalysts. In Becker, E. R., Pereira, C. J., Eds.; Computer-aided design of catalysts; Marcel Dekker: New York, 1993; pp 199-257.
15. Iglesia, E.; Reyes, S. C.; Madon, R. J.; Soled, S. L. Selectivity control and catalyst design in the Fischer-Tropsch synthesis: sites, pellets, and reactors. In Advances in Catalysis; Eley, E. E., Pines, H., Weisz, P. B., Eds.; Academic Press: New York, 1993; Vol. 39, pp 221-302.
16. Kuipers, E. W.; Vinkenburg, I. H.; Oosterbeek, H. Chain length dependence of α-olefin readsorption in Fischer-Tropsch synthesis. J. Catal. 1995, 152, 137-146.
17. Satterfield, C. N.; Huff, G. A., Jr. Carbon number distribution of Fischer-Tropsch products formed on an iron catalyst in a slurry reactor. J. Catal. 1982, 73, 187-197.
18. König, L.; Gaube, J. Fischer-Tropsch-Synthese. Neuere Untersuchungen und Entwickelungen. Chem.-Ing.-Tech. 1983, 55, 14-22.
19. Huff, G. A., Jr.; Satterfield, C. N. Evidence for two chain growth probabilities on iron catalysts in the Fischer-Tropsch synthesis. J. Catal. 1984, 85, 370-379.
20. Dictor, R. A.; Bell, A. T. Fischer-Tropsch synthesis over reduced and unreduced iron oxide catalysts. J. Catal. 1986, 97, 121-136.
21. Egiebor, N. O.; Cooper, W. C.; Wojciechowski, B. W. Carbon number distribution of Fischer-Tropsch CO-hydrogenation products from precipitated iron catalysts. Can. J. Chem. Eng. 1985, 63, 826-834.
22. Donnelly, T. J.; Yates, I. C.; Satterfield, C. N. Analysis and prediction of product distributions of the Fischer-Tropsch synthesis. Energy Fuels 1988, 2, 734-739.
23. Donnelly, T. J.; Satterfield, C. N. Product distributions of the Fischer-Tropsch synthesis on precipitated iron catalysts. Appl. Catal. A 1989, 52, 93-114.
24. Zimmerman, W. H.; Bukur, D. B.; Ledakowicz, S. Kinetic model of Fischer-Tropsch selectivity in the slurry phase. Chem. Eng. Sci. 1992, 47, 2707-2712.
25. 2. J. Catal. 1993, 139, 104-118.
26. Schulz, H.; Beck, K; Erich, E. Kinetics of Fischer-Tropsch selectivity. Fuel Process. Tecknol. 1988, 18, 293-304.
27. 14C tracer study of alkene incorporation. Energy Fuels 1990, 4, 94-99.
28. Breman, B. B.; Beenackers, A. A. C. M.; Rietjens, E. W. J.; Stege, R. J. H. Gas-liquid solubilities of carbon monoxide, carbon dioxide, hydrogen, water, 1-alcohols (1 ≤ n ≤ 6), and n-paraffins (1 ≤ n ≤ 6) in hexadecane, octacosane, 1-hexadecanol, phenantrene, and tetraethylene glycol at pressures up to 5.5 MPa and temperatures from 293 to 552 K. J. Chem. Eng. Data 1994, 39, 647-666.
29. Chappelow, C. C.; Prausnitz, J. M. Solubilities of gases in high-boiling hydrocarbon solvents. AIChE J. 1974, 20, 1097-1103.
30. 10 and larger hydrocarbons. Ind. Eng. Chem. Fundam. 1985, 24, 241-246.
31. Caldwell, L.; van Vuuren, D. S. On the formation and composition of the liquid phase in Fischer-Tropsch reactors. Chem. Eng. Sci. 1986, 41, 89-96.
32. Ruthven, D. M. Principles of adsorption and adsorption processes; Wiley & Sons: New York, 1984.
33. Rybolt, T. R.; Wall, M. D.; Thomas, H. E.; Bramblett, J. W.; Phillips, M. Gas-solid chromatography and virial analysis of hydrocarbon adsorption on 13X zeolite. J. Colloid Interface Sci. 1990, 138, 113-121.
34. Keldsen, G. L.; Nicholas, J. B.; Carrado, K. A.; Winans, R. E. Molecular modeling of the enthalpies of hydrocarbons on smectite clay. J. Phys. Chem. 1994, 98, 279-284.
35. Miyabe, K.; Suzuki, M. Chromatographic study on liquid-phase adsorption on octadecylsilyl-silica gel. AIChE J. 1995, 41, 548-558.
36. Miyabe, K.; Suzuki, M. Solvent effect on adsorption phenomena in reversed-phase liquid chromatography. AIChE J. 1995, 41, 536-547.
37. Iglesia, E.; Reyes, S. C.; Madon, R. J. Transport-enhanced α-olefin readsorption pathways Ru-catalyzed hydrocarbon synthesis. J. Catal. 1991, 129, 238-256.
38. Madon, R. J.; Iglesia, E.; Reyes, S. C. Non-Flory product distributions in Fischer-Tropsch synthesis catalyzed by Ruthenium, Cobalt, and Iron. In Selectivity in Catalysis; Suib, S. L.; Davis, M. E., Eds.; ACS Symposium Series; American Chemical Society: Washington, DC, 1993; pp 382-396.
39. Madon, R. J.; Reyes, S. C.; Iglesia, E. Primary and secondary reaction pathways in ruthenium-catalyzed hydrocarbon synthesis. J. Phys. Chem. 1991, 95, 7795-7804.
40. 2/CO reactant ratio for hydrocarbon chain growth on ruthenium catalysts. J. Catal. 1993, 139, 576-590.
41. Erkey, C.; Rodden, J. B.; Akgerman, A. Diffusivities of synthesis gas and n-alkanes in Fischer-Tropsch wax. Energy Fuels 1990, 4, 275-276.
42. Reid, R. C.; Prausnitz, J. M.; Poling, B. E. The properties of gases and liquids, 4th ed.; McGraw-Hill: New York, 1987.
43. Press, W. H.; Flannery, B. P.; Teukolsky, S. A.; Vetterling, W. T. Numerical recipes in Pascal; Cambridge University Press: New York, 1989.
44. Tajbl, D. G. Kinetics of catalytic ethane hydrogenolysis: stirred reactor study of commercial nickel catalyst. Can. J. Chem. Eng. 1969, 47, 154-156.
45. Frohning, C. D.; Kölbel, H. Ralek, M.; Rottig, W.; Schuur, F.; Schulz, H. Fischer-Tropsch-Synthese. In Chemierohstoffe aus Kohle; Falbe, J., Ed.; Georg Thieme Verlag: Stuttgart, 1977; pp 219-299.
46. Bukur, D. B.; Okabe, K.; Rosynek, M. P.; Li, C.; Wang, D.; Rao, K. R. P. M.; Huffman, G. P. Activation studies with a precipitated iron catalyst for Fischer-Tropsch synthesis. 1. Characterization studies. J. Catal. 1995, 155, 353-365.
47. Lox, E. S.; Marin, G. B.; de Graeve, E.; Bussiere, P. Characterization of a promoted precipitated iron catalyst for Fischer-Tropsch synthesis. Appl. Catal. A 1988, 40, 197-218.
48. Marsman, J. H.; Ede van, C. J.; Breman, B. B.; Stamhuis, E. J.; Beenackers, A. A. C. M. Applications of the deferred standard technique in process gas chromatography. Anal. Chim. Acta 1990, 238, 129-137.
49. Dierickx, J. L.; Plehiers, P. M.; Froment, G. F. On-line gas chromatographic analysis of hydrocarbon effluents. Calibration factors and their correlation. J. Chromatogr. 1986, 362, 155-174.
50. Bukur, D. B.; Nowicki, L.; Manne, R. K.; Lang, X. Activation studies with a precipitated iron catalyst for Fischer-Tropsch synthesis. 2. Reaction studies. J. Catal. 1995, 155, 366-375.
51. Post, M. F. M.; van't Hoog, A. C.; Minderhoud, J. K.; Sie, S. T. Diffusion limitations in Fischer-Tropsch catalysts. AIChE J. 1989, 35, 1107-1114.
52. Zimmerman, W. H.; Bukur, D. B. Effect of particle size on the activity of a fused iron Fischer-Tropsch catalyst. Ind. Eng. Chem. Res. 1989, 28, 406-413.
53. Westerterp, K. R.; van Swaaij, W. P. M.; Beenackers, A. A. C. M. Chemical reactor design and operation, 2nd ed.; Wiley & Sons: New York, 1984.
54. Nettelhoff, H.; Kokuun, R.; Ledakowicz, S.; Deckwer, W.-D. Studies on the kinetics of Fischer-Tropsch synthesis in slurry phase. Ger. Chem. Eng. 1985, 8, 177-185.
55. Bukur, D. B.; Patel, S. A.; Lang, X. Fixed bed and slurry reactor studies of Fischer-Tropsch synthesis on precipitated iron catalyst. Appl. Catal. A 1990, 61, 329-349.