Self-assembly of tetramers of 5,6-dihydroxyindole explains the primary physical properties of eumelanin: Experiment, simulation, and design

ACS Nano

Volumn 7, Issue 2, 2013, Pages 1524-1532

  Chen, Chun Teh ^a   Ball, Vincent ^b,c,d,e   De Almeida Gracio, José Joaquim ^f,g   Singh, Manoj Kumar ^f,g   Toniazzo, Valérie ^b   Ruch, David ^a,b,h   Buehler, Markus J ^a  

^a USA   (United States)

^b LUXEMBOURG INSTITUTE OF SCIENCE AND TECHNOLOGY   (Luxembourg)

^c UNIVERSITÉ DE STRASBOURG   (France)

^d INSERM   (France)

^e Fédération de Médecine Translationelle de Strasbourg ^*  (France)

^f UNIVERSITY OF AVEIRO   (Portugal)

^g UNIVERSITY OF AVEIRO   (Portugal)

^h MIT Energy Initiative   (United States)

Author keywords

electrical conductivity; eumelanin; mechanical properties; molecular dynamics; self assembly

Indexed keywords

BROAD BANDS; DENSITY FUNCTIONAL THEORY CALCULATIONS; DRY AND WET CONDITIONS; ELECTRICAL CONDUCTIVITY; EUMELANIN FILMS; EUMELANINS; EXPERIMENTAL OBSERVATION; FREE RADICAL SCAVENGING; INTERLAYER DISTANCE; ISOTROPIC MATERIALS; LAYER-BY-LAYER FILMS; MASS DENSITIES; NON-COVALENT; NON-RADIATIVE RELAXATION; ORDERS OF MAGNITUDE; PHYSICOCHEMICAL PROPERTY; QUANTUM-MECHANICAL STUDY; SECONDARY STRUCTURES; STRUCTURAL AND MECHANICAL PROPERTIES; SUPRAMOLECULAR ORGANIZATIONS; TETRAMERS; TRANSMISSION ELECTRON MICROSCOPE; YOUNG'S MODULUS;

ABSORPTION SPECTROSCOPY; DENSITY (SPECIFIC GRAVITY); DENSITY FUNCTIONAL THEORY; ELASTIC MODULI; ELECTRIC CONDUCTIVITY; MECHANICAL PROPERTIES; MOLECULAR DYNAMICS; MOLECULES; OLIGOMERS; QUANTUM THEORY; SELF ASSEMBLY; TRANSMISSION ELECTRON MICROSCOPY;

STRUCTURAL DESIGN;

5,6 DIHYDROXYINDOLE; 5,6-DIHYDROXYINDOLE; EUMELANIN; INDOLE DERIVATIVE; MELANIN; POLYMER;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; DRUG DESIGN; ELECTRIC CONDUCTIVITY; PHYSICAL PHENOMENA;

DRUG DESIGN; ELECTRIC CONDUCTIVITY; INDOLES; MELANINS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PHYSICAL PROCESSES; POLYMERS;

EID: 84874444535     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn305305d     Document Type: Article

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