Indium doped niobium phosphates as intermediate temperature proton conductors

International Journal of Hydrogen Energy

Volumn 38, Issue 5, 2013, Pages 2464-2470

  Huang, Yunjie ^a   Li, Qingfeng ^a   Anfimova, Tatiana V ^a   Christensen, Erik ^a   Yin, Min ^a,b   Jensen, Jens Oluf ^a   Bjerrum, Niels J ^a   Xing, Wei ^b  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

^b CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

Author keywords

Indium doping; Intermediate temperature fuel cell; Niobium phosphates; Proton conductivity

Indexed keywords

INDIUM; NIOBIUM; PHOSPHATES; PROTON CONDUCTIVITY; SCANNING ELECTRON MICROSCOPY; X RAY DIFFRACTION;

ANHYDROUS PROTON CONDUCTIVITY; IMPEDANCE SPECTROSCOPY; INDIUM DOPING; INTERMEDIATE TEMPERATURES; INTERMEDIATE-TEMPERATURE FUEL CELLS; NIOBIUM PHOSPHATES; PROTON CONDUCTORS; STABILITY EVALUATION;

NIOBIUM OXIDE;

EID: 84874108712     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.11.125     Document Type: Article

References (31)

1. Steele BCH, Heinzel A. Materials for fuel-cell technologies. Nature 2001;414:345-52.
2. Kreuer KD. Proton conductivity: materials and applications. Chem Mater 1996;8:610-41.
3. Heo P, Ito K, Tomita A, Hibino T. A proton-conducting fuel cell operating with hydrocarbon fuels. Angew Chem Int Ed 2008;47:7841-4.
4. Haile SM, Chisholm CRI, Sasaki K, Boysen DA, Uda T. Solid acid proton conductors: from laboratory curiosities to fuel cell electrolytes. Faraday Discuss 2007;134:17-39.
5. Schuster M, Rager T, Noda A, Kreuer KD, Maier J. About the choice of the protogenic group in PEM separator materials for intermediate temperature, low humidity operation: a critical comparison of sulphonic acid, phosphonic acid and imidazole functionalized model compounds. Fuel Cells 2005; 5:355-65.
6. Paddison SJ, Kreuer KD, Maier J. About the choice of the protogenic group in polymer electrolyte membranes: ab initio modelling of sulphonic acid, phosphonic acid, and imidazole functionalized alkanes. Phy Chem Chem Phys 2006;8:4530-42.
7. Steininger H, Schuster M, Kreuer KD, Kaltbeitzel A, Bingol B, Meyer WH, et al. Intermediate temperature proton conductors for PEM fuel cells based on phosphonic acid as protogenic group: a progress report. Phy Chem Chem Phys 2007;9:1764-73.
8. Li Q, Jensen JO, Savinell RF, Bjerrum NJ. High temperature proton exchange membranes based on polybenzimidazoles for fuel cells. Prog Polym Sci 2009;34:449-77.
9. Norby T. Solid-state protonic conductors: principles, properties, progress and prospects. Solid State Ionics 1999; 125:1-11.
10. Paschos O, Kunze J, Stimming U, Maglia F. A review on phosphate based, solid state, protonic conductors for intermediate temperature fuel cells. J Phys Condens Matter 2011;23.
11. Boysen DA, Uda T, Chisholm CRI, Haile SM. Highperformance solid acid fuel cells through humidity stabilization. Science 2004;303:68-70.
12. 4 under both ambient and high pressure conditions. Chem Mater 2003;15:727-36.
13. 3-based electrolytes for intermediate temperature fuel cells. Electrochim Acta 2007;52:7835-40.
14. 2O. Phys Rev B 2006;74.
15. Alberti G, Casciola M, Cavalaglio S, Vivani R. Proton conductivity of mesoporous zirconium phosphate pyrophosphate. Solid State Ionics 1999;125:91-7.
16. 7 for intermediate temperature fuel cells. Solid State Ionics 2008;179:1138-41.
17. 7) at intermediate temperatures. J Mater Chem 2010;20:6214-7.
18. 7 at intermediate temperatures. J Electrochem Soc 2006;153:A1604-9.
19. 7. J Electrochem Soc 2007;154:B1265-9.
20. 7 Solid Proton Conductor for intermediate temperature fuel cells. Fuel Cells 2008;8:453-8.
21. 7 compounds at intermediate temperatures. J Mater Chem 2012;22:14907-15.
22. 7 electrolyte. Electrochem Commun 2012;24:82-4.
23. Huang YJ, Li QF, Jensen AH, Yin M, Jensen JO, Christensen E, et al. Niobium phosphates as an intermediate temperature proton conducting electrolyte for fuel cells. J Mater Chem 2012;22:22452-8.
24. 7 prepared by an aqueous solution method. Solid State Ionics 2009;180:148-53.
25. Colomer MT. Nanoporuous anatase thin films as fast protonconducting materials. Adv Mater 2006;183:371-4.
26. Okazaki S, Kurimata M, Iizuka T, Tanabe K. The effect of phosphoric acid treatment on the catalytic propertiy of niobic acid. Bull Chem Soc Jpn 1987;60:37-41.
27. Da Silva JCG, Folgueras-Dominguez S, Dos Santos ACB. Amorphous niobium phosphate: characterization and acid aspects. J Mater Sci Lett 1999;18:197-200.
28. Armaroli T, Busca G, Carlini C, Giuttari M, Galletti AMR, Sbrana G. Acid sites characterization of niobium phosphate catalysts and their activity in fructose dehydration to 5- hydroxymethyl-2-furaldehyde. J Mol Catal A 2000;151: 233-43.
29. Florentino A, Cartraud P, Magnoux P, Guisnet M. Textural, acidic and catalytic properties of niobium phosphate and of niobium oxide - influence of the pretreatment temperature. Appl Catal A 1992;89:143-53.
30. Zhu JF, Huang YN. Solid-state NMR study of dehydration of layered α-niobium phosphate. Inorg Chem 2009;48: 10186-92.
31. Chai Z, Dong D, Wang C, Zhang H, Webley PA, Zhao D, et al. Nanoporous niobium phosphate electrolyte membrane for low temperature fuel cell. J Membr Sci 2010;356:147-53.