메뉴 건너뛰기




Volumn 46, Issue 3, 2013, Pages 988-1001

X-ray crystal structures, packing behavior, and thermal stability studies of a homologous series of n -alkyl-substituted polyhedral oligomeric silsesquioxanes

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL CHAIN; HOMOLOGOUS SERIES; MALDI-TOF; N-ALKENES; PACKING BEHAVIOR; PACKING SYSTEMS; POLYHEDRAL OLIGOMERIC SILSESQUIOXANES; PYROLYSIS-GAS CHROMATOGRAPHY/MASS SPECTROMETRY; THERMAL CRACKING; THERMAL STABILITY STUDIES; X RAY CRYSTAL STRUCTURES;

EID: 84873667167     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma302229v     Document Type: Article
Times cited : (37)

References (47)
  • 7
    • 26244468303 scopus 로고    scopus 로고
    • Laine, R. M. J. Mater. Chem. 2005, 15 (35-36) 3725-3744
    • (2005) J. Mater. Chem. , vol.15 , Issue.3536 , pp. 3725-3744
    • Laine, R.M.1
  • 13
    • 84873670297 scopus 로고    scopus 로고
    • Ph.D. dissertation, The Open University
    • El Aziz, Y. Ph.D. dissertation, The Open University: 2010.
    • (2010)
    • El Aziz, Y.1
  • 46
    • 84980084304 scopus 로고
    • From this compilation, it can be seen that without any exception a member with an odd number of carbon atoms has a lower melting point than that with an additional carbon atom, while in both series the melting points increase with the exception of the first members. If there is a general law in this pattern, it would be the easiest to study the melting points of the anilides and normal fatty acids and it would be desirable that colleagues who have the necessary material available would expand our knowledge in this direction. A law which would say that in homologous series a odd number of carbon atoms has a relatively lower melting point than those with an even number would have a considerable interest in molecular physics and ask for investigations if the crystal form, solubility etc. are correlated with the nature of the number, which is expressed by the quantity of carbon atoms
    • Baeyer, A. Ber. Chem. Ges. 1877, 10, 1286 From this compilation, it can be seen that without any exception a member with an odd number of carbon atoms has a lower melting point than that with an additional carbon atom, while in both series the melting points increase with the exception of the first members. If there is a general law in this pattern, it would be the easiest to study the melting points of the anilides and normal fatty acids and it would be desirable that colleagues who have the necessary material available would expand our knowledge in this direction. A law which would say that in homologous series a odd number of carbon atoms has a relatively lower melting point than those with an even number would have a considerable interest in molecular physics and ask for investigations if the crystal form, solubility etc. are correlated with the nature of the number, which is expressed by the quantity of carbon atoms
    • (1877) Ber. Chem. Ges. , vol.10 , pp. 1286
    • Baeyer, A.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.