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85033819385
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29Si NMR of the sublimate also matches that for authentic sample.
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24
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Korchkov, V. P.; Martynova, T. N. Russ. J. Appl. Chem. 1985, 58, 1923 translated from Zh. Prikl. Khim. 1985, 58, 2089. Ton'shin, A. M.; Kamaritskii, B. A; Spektor, V. N. Russ. Chem. Rev. 1983, 52. 775 (translated from Uspekhi Khim. 1983, 52, 1365). Voronkov, M. G.; Lavrent'yev, V. I. Top. Curr. Chem. 1982, 102, 199.
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Korchkov, V. P.; Martynova, T. N. Russ. J. Appl. Chem. 1985, 58, 1923 translated from Zh. Prikl. Khim. 1985, 58, 2089. Ton'shin, A. M.; Kamaritskii, B. A; Spektor, V. N. Russ. Chem. Rev. 1983, 52. 775 (translated from Uspekhi Khim. 1983, 52, 1365). Voronkov, M. G.; Lavrent'yev, V. I. Top. Curr. Chem. 1982, 102, 199.
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Korchkov, V. P.; Martynova, T. N. Russ. J. Appl. Chem. 1985, 58, 1923 translated from Zh. Prikl. Khim. 1985, 58, 2089. Ton'shin, A. M.; Kamaritskii, B. A; Spektor, V. N. Russ. Chem. Rev. 1983, 52. 775 (translated from Uspekhi Khim. 1983, 52, 1365). Voronkov, M. G.; Lavrent'yev, V. I. Top. Curr. Chem. 1982, 102, 199.
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Korchkov, V. P.; Martynova, T. N. Russ. J. Appl. Chem. 1985, 58, 1923 translated from Zh. Prikl. Khim. 1985, 58, 2089. Ton'shin, A. M.; Kamaritskii, B. A; Spektor, V. N. Russ. Chem. Rev. 1983, 52. 775 (translated from Uspekhi Khim. 1983, 52, 1365). Voronkov, M. G.; Lavrent'yev, V. I. Top. Curr. Chem. 1982, 102, 199.
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Korchkov, V. P.; Martynova, T. N. Russ. J. Appl. Chem. 1985, 58, 1923 translated from Zh. Prikl. Khim. 1985, 58, 2089. Ton'shin, A. M.; Kamaritskii, B. A; Spektor, V. N. Russ. Chem. Rev. 1983, 52. 775 (translated from Uspekhi Khim. 1983, 52, 1365). Voronkov, M. G.; Lavrent'yev, V. I. Top. Curr. Chem. 1982, 102, 199.
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Differences in molecular weight and polydispersity between the two polymer samples was not expected to significantly influence thermochemistry given previous observations in poly(phenylsilsesquioxane) systems. See: Xisheng, Z.; Lianghe, S.; Shuqing, L.; Yizhen, L. Poly. Degradation Stability 1988, 20, 157.
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85033810063
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note
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4 siloxanes were also detected by mass spectroscopic analysis of the evolved gas during thermolysis experiments in the static reactor apparatus and evidenced by the mass peaks at 222 and 296 amu.
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Patai, S. Rappoport, Z., Eds.; John Wiley and Sons: New York
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Bamford, C. H., Tipper, C. F. H., Eds.; Elsevier Scientific Publishing Co.: Amsterdam
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Kendrick, T. C.; Parbhoo, B.; White, J. W. In The Chemistry of Organic Silicon Compounds; Patai, S. Rappoport, Z., Eds.; John Wiley and Sons: New York, 1989; Part 2, pp 1319-1340. David, C. In: Comprehensive Chemical Kinetics; Bamford, C. H., Tipper, C. F. H., Eds.; Elsevier Scientific Publishing Co.: Amsterdam, 1975; Vol. 14, p 105.
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David, C.1
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0017478738
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For increased thermal stability of PDMS in carborane-siloxane systems see: Peters, E. N.; Kawakomi, J. H.; Kwiatkowski, G. T.; Hedaya, E.; Joesten, B. L.; McNeil, D. W.; Owens, D. A. J. Polym. Sci., Polym. Chem. Ed. 1977, 15, 723.
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Schneider, O. Thermochim. Acta 1988, 134, 269 Blazso', M.; Ga'l, E.; Makarova, N. N. Polyhedron 1983, 2, 455.
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Belot, V.; Corriu, R. J. P.; Leclercq, D.; Mutin, P. H.; Vioux, A. J. Mater. Sci. Lett. 1990, 9, 1052. Belot, V.; Corriu, R.; Leclercq, D.; Mutin, P. H.; Vioux, A. Chem. Mater. 1991, 3, 127. Birot, M.; Pillot, J.-P.; Dunogués, J. J. Chem. Rev. 1995, 95, 1443
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As an additional note, heating of either the monomer or polymer samples in air did not result in the formation of β-crystobalite. It is well-known, however, that heating amorphous silica for long periods (days-weeks) will promote formation of this form of silica For example see: Leadbetty, A.; et al. Nature 1973, 244, 125.
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This assumes the decomposition reaction is a first-order reaction.
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