Use of infrared spectroscopy and density functional theory to study the influence of rubidium on alumina-supported molybdenum carbide catalyst for higher alcohol synthesis from syngas

Journal of Catalysis

Volumn 299, Issue , 2013, Pages 150-161

  Shou, Heng ^a   Li, Liwei ^b   Ferrari, Daniela ^c   Sholl, David S ^b   Davis, Robert J ^a  

^a University of Virginia   (United States)

^b Georgia Institute of Technology   (United States)

^c DOW CHEMICAL COMPANY   (United States)

Author keywords

Alkali metal promotion; CO hydrogenation; Density functional theory; Higher alcohol synthesis; Infrared spectroscopy; Molybdenum carbide

Indexed keywords

ACID SITE; ADSORBED CO; ALKALI-METAL PROMOTION; ALUMINA-SUPPORTED; BINDING MODES; CATALYST SURFACES; CO HYDROGENATION; FREE BASIS; HIGHER ALCOHOL SYNTHESIS; HYDROCARBON PRODUCTION; MOLYBDENUM CARBIDE; PRESENCE OF WATER; PROMOTED CATALYSTS; QUANTUM CHEMICAL; REACTIVITY STUDIES; RED SHIFT; SIDE PRODUCTS; SYN-GAS;

ALUMINA; BINDING ENERGY; CARBIDES; CARBON DIOXIDE; CATALYST SUPPORTS; DENSITY FUNCTIONAL THEORY; ETHERS; INFRARED SPECTROSCOPY; MOLYBDENUM; ORGANIC COMPOUNDS; QUANTUM CHEMISTRY; RUBIDIUM; SYNTHESIS GAS;

CATALYST SELECTIVITY;

EID: 84873622747     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2012.12.011     Document Type: Article

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