Clay minerals for nanocomposites and biotechnology: Surface modification, dynamics and responses to stimuli

Clay Minerals

Volumn 47, Issue 2, 2012, Pages 205-230

  Heinz, H ^a  

^a University of Akron   (United States)

Author keywords

Biotechnology; Clay minerals; Dispersion; Nanocomposites; Nanomechanics; Simulation; Surfactants

Indexed keywords

ADSORPTION MECHANISM; ALKYLAMMONIUM; ATOMIC CHARGE; CHAIN CONFORMATIONS; CHEMICAL AND PHYSICAL PROPERTIES; CLAY LAYERS; COVALENT AND IONIC BONDINGS; DISTRIBUTION OF METAL; FUNDAMENTAL PROPERTIES; INTERFACIAL PROPERTY; MINERAL SURFACES; MODIFIED CLAYS; NANOMETRES; OPTICAL RESPONSE; ORGANIC INTERLAYERS; PACKING DENSITY; POLYMER MATRICES; POTENTIAL APPLICATIONS; SIMULATION; SURFACE CHARACTERISTICS; THERMAL TRANSITIONS;

BIOTECHNOLOGY; CHEMICAL BONDS; DISPERSION (WAVES); DISPERSIONS; FUNCTIONAL MATERIALS; NANOCOMPOSITES; NANOMECHANICS; POSITIVE IONS; SELF ASSEMBLY; SOLUBILITY; SURFACE ACTIVE AGENTS; SURFACE STRUCTURE;

CLAY MINERALS;

ADSORPTION; AQUEOUS SOLUTION; BIOTECHNOLOGY; CHEMICAL BONDING; CLAY MINERAL; COMPOSITE; DESIGN; DISPERSION; INDUSTRIAL PRODUCTION; NANOTECHNOLOGY; NUMERICAL MODEL; PHYSICAL PROPERTY; SOLUBILITY; SURFACTANT;

EID: 84873615956     PISSN: 00098558     EISSN: 14718030     Source Type: Journal    
DOI: 10.1180/claymin.2012.047.2.05     Document Type: Article

References (106)

1. Adams A.W. & Gast A.P. (1997) Physical Chemistry of Surfaces, 6th edition. Wiley, New York.
2. Aguzzi C., Cerezo P., Viseras C. & Caramella C. (2007) Use of clays as drug delivery systems: Possibilities and limitations. Applied Clay Science, 36, 22-36.
3. Bailey S.W. (1988) Hydrous Phyllosilicates (Exclusive of Micas), Reviews in Mineralogy, 13. Mineralogical Society of America, Washington D.C.
4. 2O. Physics and Chemistry of Minerals, 29, 430-438.
5. +-exchanged forms. Clays and Clay Minerals, 43, 324-336.
6. Bergaya F. & Lagaly G. (2001) Surface modification of clay minerals. Applied Clay Science, 19, 1-3.
7. Bergaya F., Theng, B.K.G. & Lagaly G. (2006) Handbook of Clay Science. Elsevier, Amsterdam.
8. Brandrup J., Immergut E.H. & Grulke E.A., editors (1999) Polymer Handbook. Wiley, New York.
9. Breen C., Watson R., Madejova J., Komadel P. & Klapyta Z. (1997) Acid-activated organoclays: Preparation, characterization and catalytic activity of acid-treated tetraalkylammonium-exchanged smectites. Langmuir, 13, 6473-6479.
10. Brovelli D., Caseri W.R. & Hahner G. (1999) Selfassembled monolayers of alkylammonium ions on mica: Direct determination of the orientation of the alkyl chains. Journal of Colloid and Interface Science, 216, 418-423.
11. Brown G. (1961) The X-ray Identification and Crystal Structures of Clay Minerals. Mineralogical Society, London.
12. Cases J.M., Berend I., Besson G., Francois M., Uriot J.P., Thomas F. & Poirier J.E. (1992a) Mechanism of adsorption and desorption of water vapor by homoionic montmorillonite. 1. The sodium-exchanged form. Langmuir, 8, 2730-2739.
13. Cases J.M., Pons C.H., Berend I., Francois M., Min J.H., Tchoubar D., Besson G., Thomas F. & Bottero J. Y. (1992b) Fluid-swelling clays interaction. Proceedings of the 6th IFP Exploration and Production Research Conference, Institut Français du Pétrole, 27-32.
14. 2+ exchanged forms. Clays and Clay Minerals, 45, 8-22.
15. 1 muscovite at room pressure and at 2 GPa. European Journal of Mineralogy, 6, 171-178.
16. Chassin P., Jounay C. & Quiquampoix H. (1986) Measurement of the surface free energy of calciummontmorillonite. Clay Minerals, 21, 899-907.
17. Christenson H.K. (1993) Adhesion and surface energy of mica in air and water. The Journal of Physical Chemistry, 97, 12034-12041.
18. Cygan R.T., Liang J.J. & Kalinichev A.G. (2004) Molecular models of hydroxide, oxyhydroxide, and clay phases and the development of a general force field. The Journal of Physical Chemistry B, 108, 1255-1266.
19. Cygan R.T., Greathouse J.A., Heinz H. & Kalinichev A.G. (2009) Molecular models and simulations of layered materials. Journal of Materials Chemistry, 19, 2470-2481.
20. Drummy L.F., Koerner H., Phillips D.M., McAuliffe J.C., Kumar M., Farmer B.L., Vaia R.A. & Naik R.R. (2009) Repeat sequence proteins as matrices for nanocomposites. Materials Science Engineering C, 29, 1266-1272.
21. Drummy L.F., Jones S.E., Pandey R.B., Farmer B.L., Vaia R.A. & Naik R.R. (2010) Bioassembled layered silicate-metal nanoparticle hybrids. ACS Appied. Materials & Interfaces, 2, 1492-1498.
22. Fermeglia M. & Pricl S. (2007) Multiscale modeling for polymer systems of industrial interest. Progress in Organic Coatings, 58, 187-199.
23. Fu Y.T. & Heinz H. (2010a) Cleavage energy of alkylammonium-modified montmorillonite and the relation to exfoliation in nanocomposites: Influence of cation density, head group structure, and chain length. Chemistry of Materials, 22, 1595-1605.
24. Fu Y.T. & Heinz H. (2010b) Structure and cleavage energy of surfactant-modified clay minerals: Influence of CEC, head group, and chain length. Philosophical Magazine, 90, 2415-2424.
25. Fu Y.T., Zartman G.D., Yoonessi M., Drummy L.F. & Heinz H. (2011) Bending of layered silicates on the nanometer scale: mechanism, stored energy, and curvature limits. The Journal of Physical Chemistry C, 115, 22292-22300.
26. Gaines G.L., Jr. (1957) The ion-exchange properties of muscovite mica. The Journal of Physical Chemistry, 61, 1408-1413.
27. Giese R.F. & van Oss C.J. (2002) Colloid and Surface Properties of Clays and Related Minerals. Dekker, New York.
28. Giese R.F., Constanzo P.M. & van Oss C.J. (1991) The surface free energies of talc and pyrophyllite. Physics and Chemistry of Minerals, 17, 611-616.
29. Greathouse J.A., Refson K. & Sposito G. (2000) Molecular dynamics simulation of water mobility in magnesium-smectite hydrates. Journal of the American Chemical Society, 122, 11459-11464.
30. Greenwell H.C., Harvey M.J., Boulet P., Bowden A.A., Coveney P.V. & Whiting A. (2005) Interlayer structure and bonding in nonswelling primary amine intercalated clays. Macromolecules, 38, 6189-6200.
31. Habelitz S., Carl G., Rüssel C., Theil S., Gerth U., Schnapp J. D., Jordanov A. & Knake H. (1997) Mechanical properties of oriented mica glass ceramic. Journal of Non-Crystalline Solids, 220, 291-298.
32. Hackett E., Manias E. & Giannelis E.P. (1998) Molecular dynamics simulations of organically modified layered silicates. Journal of Chemical Physics, 108, 7410-7415.
33. Hayes W.A. & Schwartz D.K. (1998) Two-stage growth of octadecyltrimethyl-ammonium bromide monolayers at mica from aqueous solution below the Krafft point. Langmuir, 14, 5913-5917.
34. +/montmorillonite hybrids. Journal of Physical Chemistry B, 109, 13301-13306.
35. Heinz H. (2010) Computational screening of biomolecular adsorption and self-assembly on nanoscale surfaces. Journal of Computational Chemistry, 31, 1564-1568.
36. Heinz H. & Suter U.W. (2004a) Surface structure of organoclays. Angewandte Chemie, 43, 2239-2243.
37. Heinz H. & Suter U.W. (2004b) Atomic charges for classical simulations of polar systems. The Journal of Phyical. Chemistry B, 108, 18341-18352.
38. Heinz H., Castelijns H.J. & Suter U.W. (2003) Structure and phase transitions of alkyl chains on mica. Journal of the American Chemical Society, 125, 9500-9510.
39. Heinz H., Paul W., Binder K. & Suter U. W. (2004) Analysis of the phase transitions in alkyl-mica by density and pressure profiles. Journal of Chemical Physics, 120, 3847-3854.
40. Heinz H., Koerner H., Anderson K.L., Vaia R.A. & Farmer B.L. (2005) Force field for mica-type silicates and dynamics of octadecylammonium chains grafted to montmorillonite. Chemistry of Materials, 17, 5658-5669.
41. Heinz H., Vaia R.A. & Farmer B.L. (2006) Interaction energy and surface reconstruction between sheets of layered silicates. Journal of Chemical Physics, 124, 224713.
42. Heinz H., Vaia R.A., Krishnamoorti R. & Farmer B.L. (2007) Self-assembly of alkylammonium chains on montmorillonite: Effect of chain length, headgroup structure, and cation exchange capacity. Chemistry of Materials, 19, 59-68.
43. Heinz H., Vaia R.A. & Farmer B.L. (2008a) Relation between packing density and thermal transitions of alkyl chains on layered silicate and metal surfaces. Langmuir, 24, 3727-3733.
44. Heinz H., Vaia R.A., Koerner H. & Farmer B.L. (2008b) Photoisomerization of azobenzene grafted to montmorillonite: Simulation and experimental challenges. Chemistry of Materials, 20, 6444-6456.
45. Herrero C.P. & Sanz J. (1991) Short-range order of the Si,Al distribution in layer silicates. Journal of Physics and Chemistry of Solids, 52, 1129-1135.
46. Hill R.J. (1979) Crystal structure refinement and electron density distribution in diaspora. Physics and Chemistry of Minerals, 5, 179-200.
47. Iyi N., Fujita T., Yelamaggad C.V. & Lopez Arbeloa F. (2001) Intercalation of cationic azobenzene derivatives in a synthetic mica and their photoresponse. Applied Clay Science, 19, 47-58.
48. Jacobs J.D., Koerner H., Heinz H., Farmer B.L., Mirau P., Garrett P.H. & Vaia R.A. (2006) Dynamics of alkyl ammonium intercalants within organically modified montmorillonite: dielectric relaxation and ionic conductivity. The Journal of Physical Chemistry B, 110, 20143-20157.
49. Kamal M.R., Calderon J.U. & Lennox R.B. (2009) Surface energy of modified nanoclays and its effect on polymer/clay nanocomposites. Journal of Adhesion Science Technology, 23, 663-688.
50. Kunz D.A., Max E., Weinkamer R., Lunkenbein T., Breu J. & Fery A. (2009) Deformation measurements on thin clay tactoids. Small, 5, 1816-1820.
51. + montmorillonite intercalates. Chemistry of Materials, 14, 2171-2175.
52. Lagaly G. (1976) Kink-block and gauche-block structures of bimolecular films. Angewandte Chemie International Edition, 15, 575-586.
53. Lagaly G. & Dekany I. (2005) Adsorption on hydrophobized surfaces: clusters and self-organization. Advances in Colloid and Interface Science, 114, 189-204.
54. Lagaly G. & Weiss A. (1970) Arrangement and orientation of cationic tensides on silicate surfaces. 2. Paraffin-like structures in alkylammonium layer silicates with a high layer charge (mica). Kolloid-Zeitschrift und Zeitschrift für Polymere, 237, 364-368.
55. Lagaly G. & Weiss A. (1971) Arrangement and orientation of cationic tensides on silicate surfaces. 4. Arrangement of alkylammonium ions in lowcharged silicates in films. Kolloid-Zeitschrift und Zeitschrift für Polymere, 243, 48-55.
56. Lee J.H. & Guggenheim S. (1981) Single crystal X-ray refinement of pyrophyllite-1Tc. American Mineralogist, 66, 350-357.
57. Lewin M., Mey-Marom A. & Frank R. (2005) Surface free energies of polymeric materials, additives, and minerals. Polymers for Advanced. Technologies, 16, 429-441.
58. 3. Acta Crystallographica Section A, A38, 733-739.
59. Lin F.H., Lee Y.H., Jian C.H., Wong J.M., Shieh M..J. & Wang C.Y. (2002) A study of purified montmorillonite intercalated with 5-fluorouracil as drug carrier. Biomaterials, 23, 1981-1987.
60. Lipsicas M., Raythatha R.H., Pinnavaia T.J., Johnson I.D., Giese R.F., Constanzo P.M. & Robert J.L. (1984) Silicon and aluminium site distribution in 2:1 layered silicate clays. Nature, 309, 604-607.
61. Mazo M.A., Manevitch L.I., Gusarova E.B., Shamaev M.Y., Berlin A.A., Balabaev N.K. & Rutledge G.C. (2008) Molecular dynamics simulation of thermomechanical properties of montmorillonite crystal. 1. Isolated clay nanoplate. The Journal of Physical Chemistry B, 112, 2964-2969.
62. McNeil L.E. & Grimsditch M. (1993) Elastic moduli of muscovite mica. Journal of Physics: Condensed Matter, 5, 1681-1690.
63. Michot L.J., Villieras F., Francois M., Yvon J., LeDred R. & Cases J.M. (1994) The structural microscopic hydrophilicity of talc. Langmuir, 10, 3765-3773.
64. Mooney R.W., Keenan A.G. & Wood L.A. (1952a) Adsorption of water vapor by montmorillonite. I. Heat of desorption and application of BET theory. Journal of the American Chemical Society, 74, 1367-1374.
65. Mooney R.W., Keenan A.G. & Wood L.A. (1952b) Adsorption of water vapor by montmorillonite. II. Effect of exchangeable ions and lattice swelling as measured by X-ray diffraction. Journal of the American Chemical Society, 74, 1371-1374.
66. Ngo T. & Schwarzenbach D. (1979) The use of electric field gradient calculations in charge density refinements. II. Charge density refinement of the lowquartz structure of aluminum phosphate. Acta Crystallographica Section A, A35, 658-664.
67. Ogawa M., Ishii T., Miyamoto N. & Kuroda K. (2001) Photocontrol of the basal spacing of azobenzenemagadiite intercalation compound. Advanced Materials, 13, 1107-1109.
68. Ogawa M., Ishii T., Miyamoto N. & Kuroda K. (2003) Intercalation of a cationic azobenzene into montmorillonite. Applied Clay Science, 22, 179-185.
69. Okada T., Watanabe Y. & Ogawa, M. (2005) Photoregulation of adsorption behavior of phenol for azobenzene-clay intercalation compounds. Journal of Materials Chemistry, 15, 987-992.
70. Osman M.A. & Suter U.W. (1999) Dodecyl pyridinium alkali metals ion exchange on muscovite mica. Journal of Colloid and Interface Science, 214, 400-406.
71. Osman M.A. & Suter U.W. (2000) Determination of the cation-exchange capacity of muscovite mica. Journal of Colloid and Interface Science, 224, 112-115.
72. Osman M.A., Moor C., Caseri W.R. & Suter U.W. (1999) Alkali metals ion exchange on muscovite mica. Journal of Colloid and Interface Science, 209, 232-239.
73. Osman M.A., Seyfang G. & Suter U.W. (2000) Twodimensional melting of alkane monolayers ionically bonded to mica. The Journal of Physical Chemistry B, 104, 4433-4439.
74. Osman M.A., Ernst M., Meier B.H. & Suter U.W. (2002) Structure and molecular dynamics of alkane monolayers self-assembled on mica platelets. The Journal of Physical Chemistry B, 106, 653-662.
75. Osman M.A., Ploetze M. & Skrabal P.J. (2004) Structure and properties of alkylammonium monolayers self-assembled on montmorillonite platelets. The Journal of Physical Chemistry B, 108, 2580-2588.
76. Osman M.A., Rupp J.E.P. & Suter U.W. (2005) Gas permeation properties of polyethylene-layered silicate nanocomposites. Journal of Materials Chemistry, 15, 1298-1304.
77. Pandey R.B., Anderson K.L., Heinz H. & Farmer B.L. (2005) Conformation and dynamics of a selfavoiding sheet: bond-fluctuation computer simulation. Journal of Polymer Science B, 43, 1041-1046.
78. Pandey R.B., Heinz H., Farmer B.L., Drummy L.F., Jones S.E., Vaia R.A. & Naik R.R. (2010) Layer of clay platelets in a peptide matrix: Binding, encapsulation and morphology. Journal of Polymer Science B, 48, 2566-2574.
79. Parbhakar A., Cuadros J., Sephton M. A., Dubbin W., Coles B. J. & Weiss D. (2007) Adsorption of Llysine on montmorillonite. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 307, 142-149.
80. Patwardhan S.V., Emami F.S., Berry R.J., Jones S.E., Naik R.R., Deschaume O., Heinz H. & Perry C.C. (2012) Chemistry of aqueous silica nanoparticle surfaces and the mechanism of selective peptide adsorption. Journal of the American Chemical Society, 134 (published online).
81. Paul D.R. & Robeson L.M. (2008) Polymer nanotechnology: Nanocomposites. Polymer, 49, 3187-3204.
82. Pawley A.R., Clark S.M. & Chinnery N.J. (2002) Equation of state measurements of chlorite, pyrophyllite, and talc. American Mineralogist, 87, 1172-1182.
83. Pospisil M., Capkova P., Merinska D., Malac Z. & Simonik J. (2001) Structure analysis of montmorillonite intercalated with cetylpyridinium and cetyltrimethylammonium: Molecular simulations and XRD analysis. Journal of Colloid and Interface Science, 236, 127-131.
84. Pospisil M., Kalendova A., Capkova P., Simonik J. & Valaskova M. (2004) Structure analysis of intercalated layer silicates: Combination of molecular simulations and experiment. Journal of Colloid and Interface Science, 277, 154-161.
85. Ray S.S. & Bousmina M. (2005) Biodegradable polymers and their layered silicate nanocomposites: In greening the 21st century materials world. Progress in Materials Science, 50, 962-1079.
86. Rothbauer R. (1971) Untersuchung eines 2M1-Muskovits mit Neutronenstrahlen. Neues Jahrbuch für Mineralogie., Monatshefte, 143-154.
87. Sachse W. & Ruoff A.L. (1975) Elastic moduli of precompressed pyrophyllite used in ultrahigh-pressure research. Journal of Applied Physics, 46, 3725-3730.
88. 27A1 highresolution MAS-NMR spectra of phyllosilicates. Journal of the American Chemical Society, 106, 4790-4793.
89. Sato H., Yamagishi A. & Kawamura K. (2001) Molecular simulation for flexibility of a single clay layer. The Journal of Physical Chemistry B, 105, 7990-7997.
90. Schoonheydt R.A. & Johnston C.T. (2007) Surface and interface chemistry of clay minerals. Pp. 87-112 in: Handbook of Clay Science I. (F. Bergaya & B.K.G. Theng, editors). Elsevier Science Ltd, Amsterdam.
91. Schoonheydt R.A. & Johnston C.T. (2011) The surface properties of clay minerals. Pp. 335-370 in: Layered Mineral Structures and their Application in Advanced Technologies (M.F. Brigatti & A. Mottana, editors). The European Mineralogical Union.
92. Simmons G. & Wang H. (1971) Single Crystal Elastic Constants and Calculated Aggregate Properties: A Handbook, 2nd edition. MIT Press, Cambridge, MA.
93. Smyth J.R., Jacobsen S.D., Swope R.J., Angel R.J., Arlt T., Domanik K. & Holloway J.R. (2000) European Journal of Mineralogy, 12, 955-963.
94. Suter J.L. & Coveney P.V. (2009) Materials properties of clay nanocomposites: onset of negative Poisson ratio in large-scale molecular dynamics simulation. Soft Matter, 5, 3896-3904.
95. Teppen B.J., Rasmussen K., Bertsch P.M., Miller D.M. & Schafer L. (1997) Molecular dynamics modeling of clay minerals. 1. Gibbsite, kaolinite, pyrophyllite, and beidellite. The Journal of Physical Chemistry B, 101, 1579-1587.
96. Usuki A., Kojima Y., Kawasumi M., Okada A., Fukushima Y., Kurauchi T. & Kamigaito O. (1993) Synthesis of Nylon-6-Clay Hybrid. Journal of Materials Research, 8, 1179-1184. [A similar contribution was first reported at the Fall National Meeting of the American Chemical Society, 1987].
97. Vaia R.A., Teukolsky R.K. & Giannelis E.P. (1994) Interlayer structure and molecular environment of alkylammonium layered silicates. Chemistry of Materials, 6, 1017-1022.
98. Vaia R.A. & Giannelis E.P. (1997) Polymer melt intercalation in organically-modified layered silicates: Model predictions and experiment. Macromolecules, 30, 8000-8009.
99. Van Olphen H. (1977) An Introduction to Clay Colloidal Chemistry. Wiley, New York.
100. Vanorio T., Prasad M. & Nur A. (2003) Elastic properties of dry clay mineral aggregates, suspensions, and sandstones. Geophysical Journal International, 155, 319-326.
101. Vaughan M.T. & Guggenheim S.(1986) Elasticity of muscovite and its relationship to crystal structure. Journal of Geophysical Research, 91, 4657-4664.
102. Weiss A., Mehler A. & Hofmann U. (1956) Organophile vermiculite. Zeitschrift für Naturforschung, 11b, 431-434.
103. Yariv S. & Cross H., editors (2002) Organo-Clay Complexes and Interactions. Dekker, New York.
104. Zartman G.D., Liu H., Akdim B., Pachter R. & Heinz H. (2010) Nanoscale tensile, shear, and failure properties of layered silicates as a function of cation density and stress. The Journal of Physical Chemistry C, 114, 1763-1772.
105. Zeng Q.H., Yu A.B., Lu G.Q. & Standish R.K. (2004) Molecular dynamics simulation of the structural and dynamic properties of dioctadecyldimethyl ammoniums in organoclays. The Journal of Physical Chemistry B, 108, 10025-10033.
106. 13C NMR. Journal of Colloid and Interface Science, 286, 239-244.