Counterintuitive mechanisms of the addition of hydrogen and simple olefins to heavy group 13 alkene analogues

Journal of the American Chemical Society

Volumn 135, Issue 5, 2013, Pages 1952-1960

  Caputo, Christine A ^a   Koivistoinen, Juha ^b   Moilanen, Jani ^b   Boynton, Jessica N ^a   Tuononen, Heikki M ^b   Power, Philip P ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF JYVÄSKYLÄ   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

[2 + 2] CYCLOADDITION; ACTIVATION BARRIERS; AROMATIC GROUP; CYCLOADDITIONS; DENSITY FUNCTIONAL THEORY CALCULATIONS; DIFFERENT MECHANISMS; DIRADICALS; EXPERIMENTAL METHODS; EXPERIMENTAL OBSERVATION; HYDROCARBON SOLUTIONS; OPEN-SHELL; TRANSITION STATE;

CYCLOADDITION; DENSITY FUNCTIONAL THEORY; DIMERS; ETHYLENE; GALLIUM; HYDROCARBONS; MONOMERS; PROPYLENE;

HYDROGEN;

ALKENE; ALKENE DERIVATIVE; ETHYLENE; HYDROGEN;

ARTICLE; CALCULATION; CYCLOADDITION; DIMERIZATION; X RAY CRYSTALLOGRAPHY;

ALKENES; ALUMINUM; CYCLIZATION; CYCLOBUTANES; GALLIUM; HYDROGEN; ORGANOMETALLIC COMPOUNDS; QUANTUM THEORY;

EID: 84873334608     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3116789     Document Type: Article

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