Selectivity of bis-triazinyl bipyridine ligands for americium(iii) in Am/Eu separation by solvent extraction. Part 1. Quantum mechanical study on the structures of BTBP complexes and on the energy of the separation

Dalton Transactions

Volumn 41, Issue 47, 2012, Pages 14416-14424

  Narbutt, Jerzy ^a   Oziminski, Wojciech P ^a,b  

^a INSTITUTE OF NUCLEAR CHEMISTRY AND TECHNOLOGY   (Poland)

^b NATIONAL MEDICINES INSTITUTE   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

ANALOGOUS COMPLEXES; B3LYP/6-31G; BASIS SETS; BIPYRIDINE LIGANDS; BIPYRIDINES; COMPLEX FORMATIONS; COVALENCIES; EFFECTIVE CORE POTENTIAL; ENERGY CHANGES; EUROPIUM COMPLEX; EUROPIUM IONS; EXTRACTION PROCESS; EXTRACTION SEPARATION; LIPOPHILIC PROPERTIES; ORGANIC PHASE; PHYSICOCHEMICAL PROPERTY; QUANTUM-MECHANICAL STUDY; SEMI-QUANTITATIVE ANALYSIS; SEPARATION PROCESS; SINGLE-POINT CALCULATIONS; THEORETICAL STUDY; TOTAL ENERGY; TWO-STEP MODEL;

AMERICIUM; CHEMICAL PROPERTIES; EUROPIUM; LIGANDS; METAL COMPLEXES; METAL IONS; QUANTUM THEORY; SOLVENT EXTRACTION;

SEPARATION;

2,2' BIPYRIDINE; AMERICIUM; COORDINATION COMPOUND; EUROPIUM; LIGAND; SOLVENT;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; FRACTIONATION; ISOLATION AND PURIFICATION; THERMODYNAMICS;

2,2'-DIPYRIDYL; AMERICIUM; CHEMICAL FRACTIONATION; COORDINATION COMPLEXES; EUROPIUM; LIGANDS; MODELS, MOLECULAR; SOLVENTS; THERMODYNAMICS;

EID: 84873166646     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c2dt31503c     Document Type: Article

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