Functional hollow fiber adsorbent materials with a self-regulating composite outer layer for gas purification with energy efficient electrothermal regeneration

Industrial and Engineering Chemistry Research

Volumn 52, Issue 3, 2013, Pages 1335-1351

  Bell, Jon G ^a   Angus, Katy ^b   Todd, Christopher ^b   Thomas, K Mark ^a  

^a NEWCASTLE UNIVERSITY   (United Kingdom)

^b Nano Porous Solutions Ltd   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORBENT BEDS; ADSORBENT MATERIALS; ADSORBENT REGENERATION; ADSORPTION KINETICS; ALTERNATING CURRENT; ENERGY EFFICIENT; FIXED-BED ADSORPTION SYSTEMS; HIGH PRESSURE; HOLLOW FIBER; INNER LAYER; INTRA-PARTICLE DIFFUSION; ISOSTERIC ENTHALPY; LINEAR DRIVING FORCE; OUTER LAYER; POLYVINYLIDENE FLUORIDES; POROUS STRUCTURES; POSITIVE TEMPERATURE COEFFICIENT OF RESISTIVITIES; SIGMOIDAL MODEL; STRETCHED EXPONENTIAL; SURFACE COVERAGES; VAPOR ADSORPTION; WATER VAPOR ADSORPTION; ZEOLITE 13X;

ENERGY EFFICIENCY; FIBERS; GAS ADSORPTION; KINETICS; SPINNING (FIBERS); VAPORS;

ADSORBENTS;

EID: 84872943564     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie3022362     Document Type: Article

References (111)

1. Sircar, S. Applications of gas separation by adsorption for the future Adsorpt. Sci. Technol. 2001, 19, 347-366
2. Reid, C. R.; Thomas, K. M. Adsorption Kinetics and Size Exclusion Properties of Probe Molecules for the Selective Porosity in a Carbon Molecular Sieve Used for Air Separation J. Phys. Chem. B 2001, 105, 10619-10629
3. 2 Removal from Flue Gas Ind. Eng. Chem. Res. 2009, 48, 7314-7324
4. Bhown, A. S.; Freeman, B. C. Analysis and Status of Post-Combustion Carbon Dioxide Capture Technologies Environ. Sci. Technol. 2011, 45, 8624-8632
5. Foster, K. L.; Fuerman, R. G.; Economy, J.; Larson, S. M.; Rood, M. J. Adsorption characteristics of trace volatile organic-compounds in gas streams onto activated carbon-fibers Chem. Mater. 1992, 4, 1068-1073
6. Ruhl, M. J. Recover VOCS via Adsorption on Activated Carbon Chem. Eng. Prog. 1993, 89, 37-41
7. Bhandari, D. A.; Bessho, N.; Koros, W. J. Hollow Fiber Sorbents for Desulfurization of Natural Gas Ind. Eng. Chem. Res. 2010, 49, 12038-12050
8. Sircar, S.; Golden, T. C.; Rao, M. B. Activated carbon for gas separation and storage Carbon 1996, 34, 1-12
9. Sircar, S.; Golden, T. C. Purification of hydrogen by pressure swing adsorption Sep. Sci. Technol. 2000, 35, 667-687
10. Sullivan, P. D.; Rood, M. J.; Dombrowski, K. D.; Hay, K. J. Capture of organic vapors using adsorption and electrothermal regeneration J. Environ. Eng.-ASCE 2004, 130, 258-267
11. Das, D.; Gaur, V.; Verma, N. Removal of volatile organic compound by activated carbon fiber Carbon 2004, 42, 2949-2962
12. Ruthven, D. M.; Kaul, B. K. Adsorption of n -hexane and intermediate molecular weight aromatic hydrocarbons on LaY zeolite Ind. Eng. Chem. Res. 1996, 35, 2060-2064
13. Madhugiri, S.; Dalton, A.; Gutierrez, J.; Ferraris, J. P.; Balkus, K. J. Electrospun MEH-PPV/SBA-15 composite nanofibers using a dual syringe method J. Am. Chem. Soc. 2003, 125, 14531-14538
14. Di, J. C.; Chen, H. Y.; Wang, X. F.; Zhao, Y.; Jiang, L.; Yu, J. H.; Xu, R. R. Fabrication of zeolite hollow fibers by coaxial electrospinning Chem. Mater. 2008, 20, 3543-3545
15. Di, J. C.; Zhao, Y.; Yu, J. H. Fabrication of molecular sieve fibers by electrospinning J. Mater. Chem. 2011, 21, 8511-8520
16. Feng, X. S.; Pan, C. Y.; McMinis, C. W.; Ivory, J.; Ghosh, D. Hollow-fiber-based adsorbers for gas separation by pressure-swing adsorption AIChE J. 1998, 44, 1555-1562
17. Nevell, J. M.; Perera, S. P. Novel adsorbent hollow fibres for oxygen concentration Adsorption 2011, 17, 273-283
18. Gilleskie, G. L.; Parker, J. L.; Cussler, E. L. Gas Separations in Hollow-Fiber Adsorbers AIChE J. 1995, 41, 1413-1425
19. Mather, P. J.; Thomas, K. M. Carbon black/high density polyethylene conducting composite materials 1. Structural modification of a carbon black by gasification in carbon dioxide and the effect on the electrical and mechanical properties of the composite J. Mater. Sci. 1997, 32, 401-407
20. Mather, P. J.; Thomas, K. M. Carbon black high density polyethylene conducting composite materials 2. The relationship between the positive temperature coefficient and the volume resistivity J. Mater. Sci. 1997, 32, 1711-1715
21. Zhang, M. Y.; Jia, W. T.; Chen, X. F. Influences of crystallization histories on PTC/NTC effects of PVDF/CB composites J. Appl. Polym. Sci. 1996, 62, 743-747
22. Wu, C. Z.; Zhang, C.; Miura, T.; Asai, S.; Sumita, M. Electrical characteristics of fluorinated carbon black-filled poly(vinylidene fluoride) composites J. Appl. Polym. Sci. 2001, 80, 1063-1070
23. Feng, J. Y.; Chan, C. M. Carbon black-filled immiscible blends of poly(vinylidene fluoride) and high density polyethylene: The relationship between morphology and positive and negative temperature coefficient effects Polym. Eng. Sci. 1999, 39, 1207-1215
24. Mironi-Harpaz, I.; Narkis, M. Electrical behavior and structure of polypropylene/ultrahigh molecular weight polyethylene/carbon black immiscible blends J. Appl. Polym. Sci. 2001, 81, 104-115
25. Mironi-Harpaz, I.; Narkis, M. Thermo-electric behavior (PTC) of carbon black-containing PVDF/UHMWPE and PVDF/XL-UHMWPE blends Polym. Eng. Sci. 2001, 41, 205-221
26. Xu, H. P.; Dang, Z. M.; Jiang, M. J.; Yao, S. H.; Bai, J. Enhanced dielectric properties and positive temperature coefficient effect in the binary polymer composites with surface modified carbon black J. Mater. Chem. 2008, 18, 229-234
27. Xu, H. P.; Dang, Z. M.; Yao, S. H.; Jiang, M. J.; Wang, D. Y. Exploration of unusual electrical properties in carbon black/binary-polymer nanocomposites Appl. Phys. Lett. 2007, 90
28. Zhao, Z. D.; Yu, W. X.; He, X. J.; Chen, X. F. The conduction mechanism of carbon black-filled poly(vinylidene fluoride) composite Mater. Lett. 2003, 57, 3082-3088
29. Wang, Y. J.; Pan, Y.; Zhang, X. W.; Tan, K. Impedance spectra of carbon black filled high-density polyethylene composites J. Appl. Polym. Sci. 2005, 98, 1344-1350
30. Bin, Y.; Yamanaka, A.; Chen, Q. Y.; Xi, Y.; Jiang, X. W.; Matsuo, M. Morphological, electrical and mechanical properties of ultrahigh molecular weight polyethylene and multi-wall carbon nanotube composites prepared in decalin and paraffin Polym. J. 2007, 39, 598-609
31. Mago, G.; Fisher, F. T.; Kalyon, D. M. Deformation-Induced Crystallization and Associated Morphology Development of Carbon Nanotube-PVDF Nanocomposites J. Nanosci. Nanotechnol. 2009, 9, 3330-3340
32. Yuan, J. K.; Yao, S. H.; Dang, Z. M.; Sylvestre, A.; Genestoux, M.; Bai, J. B. Giant Dielectric Permittivity Nanocomposites: Realizing True Potential of Pristine Carbon Nanotubes in Polyvinylidene Fluoride Matrix through an Enhanced Interfacial Interaction J. Phys. Chem. C 2011, 115, 5515-5521
33. Ke, K.; Wen, R.; Wang, Y.; Yang, W.; Xie, B. H.; Yang, M. B. Crystallization behavior of poly (vinylidene fluoride)/multi-walled carbon nanotubes nanocomposites J. Mater. Sci. 2011, 46, 1542-1550
34. He, L. H.; Sun, J.; Zheng, X. L.; Xu, Q.; Song, R. Effect of Multiwalled Carbon Nanotubes on Crystallization Behavior of Poly(vinylidene fluoride) in Different Solvents J. Appl. Polym. Sci. 2011, 119, 1905-1913
35. He, L. X.; Tjong, S. C. Effect of Temperature on Electrical Conduction Behavior of Polyvinylidene Fluoride Nanocomposites with Carbon Nanotubes and Nanofibers Curr. Nanosci. 2011, 6, 520-524
36. Chang, C. M.; Liu, Y. L. Electrical Conductivity Enhancement of Polymer/Multiwalled Carbon Nanotube (MWCNT) Composites by Thermally-Induced Defunctionalization of MWCNTs ACS Appl. Mater. Interfaces 2011, 3, 2204-2208
37. Jiang, S. L.; Yu, Y.; Xie, J. J.; Wang, L. P.; Zeng, Y. K.; Fu, M.; Li, T. Positive Temperature Coefficient Properties of Multiwall Carbon Nanotubes/Poly(vinylidene fluoride) Nanocomposites J. Appl. Polym. Sci. 2010, 116, 838-842
38. Huang, W. W.; Edenzon, K.; Fernandez, L.; Razmpour, S.; Woodburn, J.; Cebe, P. Nanocomposites of Poly(vinylidene fluoride) with Multiwalled Carbon Nanotubes J. Appl. Polym. Sci. 2010, 115, 3238-3248
39. Bao, S. P.; Liang, G. D.; Tjong, S. C. Effect of mechanical stretching on electrical conductivity and positive temperature coefficient characteristics of poly(vinylidene fluoride)/carbon nanofiber composites prepared by non-solvent precipitation Carbon 2011, 49, 1758-1768
40. Xi, Y.; Bin, Y. Z.; Chiang, C. K.; Matsuo, M. Dielectric effects on positive temperature coefficient composites of polyethylene and short carbon fibers Carbon 2007, 45, 1302-1309
41. Sun, L. L.; Li, B.; Zhao, Y.; Zhong, W. H. Suppression of AC conductivity by crystalline transformation in poly(vinylidene fluoride)/carbon nanofiber composites Polymer 2010, 51, 3230-3237
42. Sun, L. L.; Li, B.; Zhao, Y.; Mitchell, G.; Zhong, W. H. Structure-induced high dielectric constant and low loss of CNF/PVDF composites with heterogeneous CNF distribution Nanotechnol. 2010, 21, 8
43. Sun, L. L.; Li, B.; Zhang, Z. G.; Zhong, W. H. Achieving very high fraction of beta-crystal PVDF and PVDF/CNF composites and their effect on AC conductivity and microstructure through a stretching process Eur. Polym. J. 2010, 46, 2112-2119
44. Ansari, S.; Giannelis, E. P. Functionalized Graphene Sheet- Poly(vinylidene fluoride) Conductive Nanocomposites J. Polym. Sci., Part B: Polym. Phys. 2009, 47, 888-897
45. Xu, H. P.; Dang, Z. M.; Shi, D. H.; Bai, J. B. Remarkable selective localization of modified nanoscaled carbon black and positive temperature coefficient effect in binary-polymer matrix composites J. Mater. Chem. 2008, 18, 2685-2690
46. Deng, H.; Skipa, T.; Zhang, R.; Lellinger, D.; Bilotti, E.; Alig, I.; Peijs, T. Effect of melting and crystallization on the conductive network in conductive polymer composites Polymer 2009, 50, 3747-3754
47. Huang, Z. M.; Zhang, Y. Z.; Kotaki, M.; Ramakrishna, S. A review on polymer nanofibers by electrospinning and their applications in nanocomposites Compos. Sci. Technol. 2003, 63, 2223-2253
48. BS2044 Methods for determination of resistivity of conductive and antistatic plastics and rubbers (laboratory methods), Method 2.; British Standards Institute, 1984.
49. Lange's Handbook of Chemistry, 15 th ed.; McGraw-Hill: New York, 1999.
50. Lovinger, A. J. Ferroelectric polymers Science 1983, 220, 1115-1121
51. Marand, H. L.; Stein, R. S.; Stack, G. M. Isotherm crystallization of poly(vinylidene fluoride) in the presence of high static electric fields 0.1. Primary nucleation phenomenon J. Polym. Sci., Part B: Polym. Phys. 1988, 26, 1361-1383
52. Liang, H.; Cooper, R.; Files, J. Phase transformation of poly (vinylidene difluoride) in energy harvesting J. Mater. Res. 2011, 26, 1-8
53. Davis, G. T.; McKinney, J. E.; Broadhurst, M. G.; Roth, S. C. Electric-field-induced phase-changes in poly(vinylidene fluoride) J. Appl. Phys. 1978, 49, 4998-5002
54. Naegele, D.; Yoon, D. Y.; Broadhurst, M. G. Formation of a new crystal form (alpha-P) of poly(vinylidene fluoride) under electric-field Macromolecules 1978, 11, 1297-1298
55. Doll, W. W.; Lando, J. B. Polymorphism of poly(vinylidene fluoride) 3. crystal structure of phase-II J. Macromol. Sci., Part B: Phys. 1970, B 4, 309
56. Hasegawa, R.; Takahashi, Y.; Tadokoro, H.; Chatani, Y. Crystal-structures of 3 crystalline forms of poly(vinylidene fluoride) Polym. J. 1972, 3, 600
57. Bachmann, M. A.; Lando, J. B. A reexamination of the crystal-structure of phase-II of poly(vinylidene fluoride) Macromolecules 1981, 14, 40-46
58. Lovinger, A. J. Unit cell of the gamma phase of poly(vinylidene fluoride) Macromolecules 1981, 14, 322-325
59. Takahashi, Y.; Tadokoro, H. Crystal structure of form-III of poly(vinylidene fluoride) Macromolecules 1980, 13, 1317-1318
60. Weinhold, S.; Litt, M. H.; Lando, J. B. The crystal-structure of the gamma phase of poly(vinylidene fluoride) Macromolecules 1980, 13, 1178-1183
61. Pramoda, K. P.; Mohamed, A.; Phang, I. Y.; Liu, T. X. Crystal transformation and thermomechanical properties of poly(vinylidene fluoride)/clay nanocomposites Polym. Int. 2005, 54, 226-232
62. Osaki, S.; Ishida, Y. Effects of annealing and isothermal crystallization upon crystalline forms of poly(vinylidene fluoride) J. Polym. Sci., Part B: Polym. Phys. 1975, 13, 1071-1083
63. Prest, W. M.; Luca, D. J. Morphology and thermal response of high-temperature crystallized poly(vinylidene fluoride) J. Appl. Phys. 1975, 46, 4136-4143
64. Lovinger, A. J.; Keith, H. D. Electron-diffraction investigation of a high temperature form of poly(vinylidene fluoride) Macromolecules 1979, 12, 919-924
65. Morra, B. S.; Stein, R. S. Melting studies of poly(vinylidene fluoride) and its blends with poly(methyl methacrylate) J. Polym. Sci., Part B: Polym. Phys. 1982, 20, 2243-2259
66. Welch, G. J.; Miller, R. L. Crystallization of poly(vinylidene fluoride)-equilibrium melting-point and heat of fusion of alpha-polymorph J. Polym. Sci., Part B: Polym. Phys. 1976, 14, 1683-1692
67. Mancarella, C.; Martuscelli, E. Crystallization kinetics of poly(vinylidene fluoride) Polymer 1977, 18, 1240-1242
68. Patro, T. U.; Mhalgi, M. V.; Khakhar, D. V.; Misra, A. Studies on poly(vinylidene fluoride)-clay nanocomposites: Effect of different clay modifiers Polymer 2008, 49, 3486-3499
69. Lanceros-Mendez, S.; Mano, J. F.; Costa, A. M.; Schmidt, V. H. FTIR and DSC studies of mechanically deformed beta-PVDF films J. Macromol. Sci., Part B:Phys. 2001, B40, 517-527
70. Huang, X. Y.; Jiang, P. K.; Kim, C.; Liu, F.; Yin, Y. Influence of aspect ratio of carbon nanotubes on crystalline phases and dielectric properties of poly(vinylidene fluoride) Eur. Polym. J. 2009, 45, 377-386
71. Kobayashi, M.; Tashiro, K.; Tadokoro, H. Molecular vibrations of 3 crystal forms of poly(vinylidene fluoride) Macromolecules 1975, 8, 158-171
72. Weinhold, S.; Litt, M. H.; Lando, J. B. Oriented phase-III Poly(vinylidene fluoride) J. Polym. Sci., Part C: Polym. Lett. 1979, 17, 585-589
73. Betz, N.; Lemoel, A.; Balanzat, E.; Ramillon, J. M.; Lamotte, J.; Gallas, J. P.; Jaskierowicz, G. A FTIR study of PVDF irradiated by means of swift heavy ions J. Polym. Sci., Part B: Polym. Phys. 1994, 32, 1493-1502
74. Mattsson, B.; Ericson, H.; Torell, L. M.; Sundholm, F. Micro-Raman investigations of PVDF-based proton-conducting membranes J. Polym. Sci., Part A: Polym. Chem. 1999, 37, 3317-3327
75. Gregorio, R.; Capitao, R. C. Morphology and phase transition of high melt temperature crystallized poly(vinylidene fluoride) J. Mater. Sci. 2000, 35, 299-306
76. Boccaccio, T.; Bottino, A.; Capannelli, G.; Piaggio, P. Characterization of PVDF membranes by vibrational spectroscopy J. Membr. Sci. 2002, 210, 315-329
77. Salimi, A.; Yousefi, A. A. FTIR studies of beta-phase crystal formation in stretched PVDF films Polym. Test. 2003, 22, 699-704
78. Bormashenko, Y.; Pogreb, R.; Stanevsky, O.; Bormashenko, E. Vibrational spectrum of PVDF and its interpretation Polym. Test. 2004, 23, 791-796
79. Carmona, F.; Mouney, C. Temperature-dependent resistivity and conductivity mechanism in carbon particle-filled polymers J. Mater. Sci. 1992, 27, 1322-1326
80. Kawamoto, H.: In Carbon black-polymer Composites; Sichel, E., Ed.; Marcel Dekker: New York, 1982.
81. Meyer, J. Glass transition temperature as a guide to selection of polymers suitable for PTC materials Polym. Eng. Sci. 1973, 13, 462-468
82. Meyer, J. Stability of polymer composites as positive-temperature- coefficient resistors Polym. Eng. Sci. 1974, 14, 706-716
83. Sing, K. S. W.; Everett, D. H.; Haul, R. A. W.; Moscou, L.; Pierotti, R. A.; Rouquerol, J.; Siemieniewska, T. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) Pure Appl. Chem. 1985, 57, 603-619
84. 2 recovery from flue-gas by pressure swing adsorption Ind. Eng. Chem. Res. 1995, 34, 591-598
85. 2 on zeolite 13X and zeolite X/Activated carbon composite J. Chem. Eng. Data 2002, 47, 1237-1242
86. Ferreira, D.; Magalhaes, R.; Taveira, P.; Mendes, A. Effective Adsorption Equilibrium Isotherms and Breakthroughs of Water Vapor and Carbon Dioxide on Different Adsorbents Ind. Eng. Chem. Res. 2011, 50, 10201-10210
87. Wheeler, J.; Robell, A. J. Performance of Fixed-Bed Catalytic Reactors with Poison in the Feed J. Catal. 1969, 13, 299-305
88. Jonas, L. A.; Rehrmann, J. A. Predictive equations for gas adsorption kinetics Carbon 1973, 11, 59-64
89. Wood, G. O.; Stampfer, J. F. Adsorption rate coefficients for gases and vapors on activated carbons Carbon 1993, 31, 195-200
90. LeVan, M. D.: Asymptotic Fixed-bed Behavior: Proportionate and Constant Patterns. In Adsorption Science and Technology, NATO ASI Series E Applied Science; Rodriguez, A.E.; LeVan, M. D., Eds.; Kluwer: Dordrecht, The Netherlands, 1989; Vol. 158, pp 149-168.
91. 2O on zeolite 13X Korean J. Chem. Eng. 2001, 18, 525-530
92. Kim, J. H.; Lee, C. H.; Kim, W. S.; Lee, J. S.; Kim, J. T.; Suh, J. K.; Lee, J. M. Adsorption equilibria of water vapor on alumina, zeolite 13X, and a zeolite X/activated carbon composite J. Chem. Eng. Data 2003, 48, 137-141
93. Cortes, F. B.; Chejne, F.; Carrasco-Marin, F.; Moreno-Castilla, C.; Perez-Cadenas, A. F. Water adsorption on zeolite 13X: comparison of the two methods based on mass spectrometry and thermogravimetry Adsorption 2010, 16, 141-146
94. Ahn, H.; Lee, C. H. Effects of capillary condensation on adsorption and thermal desorption dynamics of water in zeolite 13X and layered beds Chem. Eng. Sci. 2004, 59, 2727-2743
95. Bell, J. G.; Zhao, X.; Uygur, Y.; Thomas, K. M. Adsorption of Chloroaromatic Models for Dioxins on Porous Carbons: The Influence of Adsorbate Structure and Surface Functional Groups on Surface Interactions and Adsorption Kinetics J. Phys. Chem. C 2011, 115, 2776-2789
96. Wang, Y.; Levan, M. D. Adsorption Equilibrium of Carbon Dioxide and Water Vapor on Zeolites 5A and 13X and Silica Gel: Pure Components J. Chem. Eng. Data 2009, 54, 2839-2844
97. 4 Metal-Organic Framework Materials Templated with Methanol and Ethanol: Structural Effects in Adsorption Kinetics J. Am. Chem. Soc. 2004, 126, 9750-9759
98. 2 Adsorption on a Mixed-Metal-Organic Framework Material J. Am. Chem. Soc. 2008, 130, 6411-6423
99. 2O on porous carbons J. Phys. Chem. C 2007, 111, 2107-2115
100. Fletcher, A. J.; Yuzak, Y.; Thomas, K. M. Adsorption and desorption kinetics for hydrophilic and hydrophobic vapors on activated carbon Carbon 2006, 44, 989-1004
101. 2 Quantum Molecular Sieving in Adsorption/Desorption on Porous Carbon Materials J. Phys. Chem. B 2006, 110, 9947-9955
102. Klafter, J.; Shlesinger, M. F. On the Relationship Among 3 Theories of Relaxation in Disordered-Systems Proc. Natl. Acad. Sci. U.S.A. 1986, 83, 848-851
103. Forster, T. Experimentelle und theoretische untersuchung des zwishcenmolekularen ubergangs von elecktronenanregungsenergie Z. Naturforsch. Teil A 1949, 4, 321-342
104. Palmer, R. G.; Stein, D. L.; Abrahams, E.; Anderson, P. W. Models of hierarchically constrained dynamics for glassy relaxation Phys. Rev. Lett. 1984, 53, 958-961
105. Glarum, S. H. Dielectric relaxation of polar liquids J. Chem. Phys. 1960, 33, 1371-1375
106. Bordewijk, P. Defect-diffusion models of dielectric-relaxation Chem. Phys. Lett. 1975, 32, 592-596
107. Shlesinger, M. F.; Montroll, E. W. On the Williams-Watts function of Dielectric-Relaxation Proc. Natl. Acad. Sci. U. S. A. 1984, 81, 1280-1283
108. Chen, Y.-D.; Yang, R. T. Surface and mesoporous diffusion with multilayer adsorption Carbon 1998, 36, 1525-1537
109. O'koye, I. P.; Benham, M.; Thomas, K. M. Adsorption of gases and vapours on carbon molecular sieves Langmuir 1997, 13, 4054-4059
110. Reid, C. R.; O'koye, I. P.; Thomas, K. M. Adsorption of gases on carbon molecular sieves used for air separation: Spherical adsorptives as probes for kinetic selectivity Langmuir 1998, 14, 2415-2425
111. Reid, C. R.; Thomas, K. M. Adsorption of gases on CMS used for air separation: Linear adsorptives as probes for kinetic selectivity Langmuir 1999, 15, 3206