Oxidation of Cu(II)-EDTA in supercritical water-Experimental results and modeling

Chemical Engineering Research and Design

Volumn 91, Issue 2, 2013, Pages 286-295

  Zhou, Lu ^a   Wang, Shuzhong ^a   Ma, Honghe ^a   Gong, Yanmeng ^a   Xu, Donghai ^a  

^a XI'AN JIAOTONG UNIVERSITY   (China)

Author keywords

Copper oxides; Cu(II) EDTA; Kinetics; Simulation; Supercritical water oxidation

Indexed keywords

ARRHENIUS KINETICS; CARBON-CONTAINING PRODUCTS; COMPOSITION PROFILE; CONTINUOUS TUBULAR REACTORS; COPPER COMPLEXES; CU EDTAS; ELEVATING TEMPERATURES; ETHYLENE DIAMINE TETRA-ACETIC ACID; EXPERIMENTAL STUDIES; KINETIC MODELS; OPERATING PARAMETERS; OXYGEN FLOW RATES; REACTION PATHWAYS; REACTION TEMPERATURE; RESIDENCE TIME; SIMULATION; SUPERCRITICAL; SUPERCRITICAL WATER; SUPERCRITICAL WATER OXIDATION; TUBULAR REACTORS;

CARBON DIOXIDE; COMPUTATIONAL FLUID DYNAMICS; COPPER; COPPER COMPOUNDS; COPPER OXIDES; ENZYME KINETICS; KINETIC THEORY; KINETICS; OXIDATION;

REACTION INTERMEDIATES;

EID: 84872809381     PISSN: 02638762     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cherd.2012.08.016     Document Type: Article

References (41)

1. Airton K., Patricio P.Z., Nelson D. Hydrogen peroxide assisted photochemical degradation of ethylenediaminetetraacetic acid. Adv. Environ. Res. 2002, 7:197-202.
2. Al-Duri B., Pinto L., Ashraf-Ball N.H., Santos R.C.D. Thermal abatement of nitrogen-containing hydrocarbons by non-catalytic supercritical water oxidation (SCWO). J. Mater. Sci. 2008, 43:1421-1428.
3. Abeln J., Kluth M., Böttcher M., Sengpiel W. Supercritical water oxidation (SCWO) using a transpiring wall reactor CFD simulations and experimental results of ethanol oxidation. Environ. Eng. Sci. 2004, 21:93-99.
4. Benjamin K.M., Savage P.E. Supercritical water oxidation of methylamine. Ind. Eng. Chem. Res. 2005, 44:5318-5324.
5. Bermejoa M.D., Martina á., Queiroz J.S., Bielsa I., Rios V., Cocero M.J. Computational fluid dynamics simulation of a transpiring wall reactor for supercritical water oxidation. Chem. Eng. J. 2010, 158:431-440.
6. Cabeza P., Bermejo M.D., Jimenez C., Cocero M.J. Experimental study of the supercritical water oxidation of recalcitrant compounds under hydrothermal flames using tubular reactors. Water Res. 2011, 45:2485-2495.
7. Chen J., Gao J.H., Wang X.Y. Thermal decomposition of ethylenediaminetetraacetic acid in the presence of 1,2-phenylenediamine and hydrochloric acid. J. Braz. Chem. Soc. 2006, 17:880-885.
8. Chitra S., Paramasivan K., Sinha P.K., Lal K.B. Ultrasonic treatment of liquid waste containing EDTA. J. Clean. Prod. 2004, 12:429-435.
9. 2 catalyst. Ind. Eng. Chem. Res. 1998, 37:1707-1716.
10. Goel S., Gautam A. Effect of chelating agents on mobilization of metal from waste catalyst. Hydrometallurgy 2010, 101:120-125.
11. Gadhe J.B., Gupta R.B. Hydrogen production by methanol reforming in supercritical water: catalysis by in situ-generated copper nanoparticles. Int. J. Hydrogen Energy 2007, 32:2374-2381.
12. Gilbert E., Hoffmann G.S. Ozonation of ethylenediaminetetraacetic acid (EDTA) in aqueous solution, influence of pH value and metal ions. Water Res. 1990, 24:39-44.
13. Helling R.K., Tester J.T. Oxidation kinetics of carbon monoxide in supercritical water. Energy Fuels 1987, 1:417-423.
14. Helling R.K., Tester J.W. Oxidation of simple compounds and mixtures in supercritical water: carbon monoxide, ammonia and ethanol. Enoiron. Sci. Technol. 1988, 22:1319.
15. Hirosak K., Koido K., Fukayama M. Experimental and numerical study of ethanol oxidation in sub-critical water. J. Supercrit. Fluids 2008, 44:347-355.
16. II'Chenko N.I. Catalytic oxidation of ammonia. Russ. Chem. Rev. 1976, 45:1119-1134.
17. Jin J., Li X.D., Chi Y., Yan J.H. Co-disposal of heavy metals containing waste water and medical waste incinerator fly ash by hydrothermal process with addition of sodium carbonate: a case study on Cu(II) removal. Water Air Soil Pollut. 2010, 209:391-400.
18. Knez Z. High pressure process technology-quo vadis. Chem. Eng. Res. Des. 2004, 82:1541-1548.
19. Krajnc M., Levec J. The role of catalyst in supercritical water oxidation of acetic acid. Appl. Catal. B: Environ. 1997, 13:93-103.
20. Lee H.C., Kim J.H., In J.H., Lee C.H. NaFeEDTA decomposition and hematite nanoparticle formation in supercritical water oxidation. Ind. Eng. Chem. Res. 2005, 44:6615-6621.
21. Lee H.C., In J.H., Hwang K.Y., Lee C.H. Decomposition of ethylenediaminetetraacetic acid by supercritical water oxidation. Ind. Eng. Chem. Res. 2004, 43:3223-3227.
22. Magnussen F.B. On the structure of turbulence and a generalized eddy dissipation concept for chemical reaction in turbulent flow. 19th American Institute of Aeronautics and Astronautics Aerospace Science Meeting 1981.
23. Nasibulin A.G., Kauppinen E.I., Brown D.P., Jokiniemi J.K. Nanoparticle formation via copper (II) acetylacetonate vapor decomposition in the presence of hydrogen and water. Phys. Chem. B 2001, 105:11067-11075.
24. Narayanana C., Frouzakisa C., Boulouchos K., PRóIKOPSKó K., Wlling B., Rudolf R.P. Numerical modeling of a supercritical water oxidation reactor containing a hydrothermal flame. J. Supercrit. Fluids 2008, 46:149-155.
25. NIST Chemistry WebBook, http://webbook.nist.gov/chemistry/.
26. Oe T., Suzugaki H., Naruse I., Quitain A.T., Daimon H., Fujie K. Role of methanol in supercritical water oxidation of ammonia. Ind. Eng. Chem. Res. 2007, 46:3566-3573.
27. Pallares S.J., Santos P.M.T., Serna G.J., Castro F., Cocero M.J. Numerical modeling of hydrothermal flames. Micromixing effects over turbulent reaction rates. J. Supercrit. Fluids 2009, 50:146-154.
28. Repoa E., Kurniawana T.A., Warchol J.K., Sillanpää M.E.T. Removal of Co(II) and Ni(II) ions from contaminated water using silica gel functionalized with EDTA and/or DTPA as chelating agents. J. Hazard Mater. 2009, 171:1071-1080.
29. Sato H., Hamada S., Sertkawa R.M., Nishimura T., Usui T., Sekino H. Continuous flame oxidation in supercritical water. High Pressure Res. 2001, 20:403-413.
30. Smart J.P., Roberts P.A., Soete G.G. The formation of nitrous oxide in large-scale pulverised-coal flames. J. Inst. Energy 1990, 63:131-135.
31. Shin Y.H., Lee H.S., Lee Y.H., Kim J., Kim J.D., Lee Y.W. Synergetic effect of copper-plating wastewater as a catalyst for the destruction of acrylonitrile wastewater in supercritical water oxidation. J. Hazard Mater. 2009, 167:824-829.
32. 3, NiO, and CuO nanoparticles by super rapid heating using a T-type micro mixer at 673K and 30MPa. Chem. Eng. J. 2011, 166:947-953.
33. Sue K., Suzuki M., Arai K., Ohashi T., Ura H., Matsui K., Hakuta Y., Hayashi H., Watanabe M., Hiaki T. Size-controlled synthesis of metal oxide nanoparticles with a flow-through supercritical water method. Green Chem. 2006, 8:634-638.
34. Sue K., Hakuta Y., Smith R.L., Adschiri T., Arai K. Solubility of lead (II) oxide and copper (II) oxide in subcritical and supercritical water. Chem. Eng. Data 1999, 44:1422-1426.
35. Webley P.A., Ester, Tester J.T., Holgate H.R. Oxidation kinetics of ammonia and ammonia-methanol mixtures in supercritical water in the temperature range 530-700°C at 246bar. Ind. Eng. Chem. Res. 1991, 30:1745-1754.
36. Webley P.A., Tester J.T. Fundamental kinetics of methanol oxidation in supercritical water. Supercrit. Fluid Sci. Technol. 1989, 17:259-275.
37. Wang L., Wang S.Z., Zhang Q.M., Shen L.H., Duan B.Q. Reaction mechanism and kinetics of oil-bearing sewage disposal by supercritical water oxidation. J. Xi'an Jiaotong Univ. 2006, 40:115-119.
38. Wang S.Z., Guo Y., Chen C.M., Zhang J., Gong Y.M., Wang Y.Z. Supercritical water oxidation of landfill leachate. Waste Manage. 2011, 31:2027-2035.
39. Wellig B., Weber M., Lieball K., Prikopsky, Ph.Rudolf von Rohr K. Hydrothermal methanol diffusion flame as internal heat source in a SCWO reactor. J. Supercrit. Fluids 2009, 49:59-70.
40. 2: mechanisms. Environ. Sci. Technol. 2000, 34:3796-3801.
41. Yeh R.S., Wang Y.Y., Wan C.C. Removal of Cu-EDTA compounds via electrochemical process with coagulation. Water Res. 1995, 29:597-599.