Experimental study of the supercritical water oxidation of recalcitrant compounds under hydrothermal flames using tubular reactors

Water Research

Volumn 45, Issue 8, 2011, Pages 2485-2495

  Cabeza, Pablo ^a   Bermejo, M Dolores ^a   Jiménez, Cristina ^a   Cocero, M José ^a  

^a UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

Acetic acid; Ammonia; Autoignition; Industrial waste; Tubular reactor; Wastewater treatment

Indexed keywords

ACETIC ACID; AMMONIA; INDUSTRIAL WASTES; INDUSTRIAL WATER TREATMENT; MIXTURES; PH; WASTE INCINERATION;

ALCOHOL CONCENTRATIONS; AUTOIGNITIONS; HYDROTHERMAL FLAME; ISOPROPYL ALCOHOLS; OXIDATION REACTIONS; RECALCITRANT COMPOUNDS; RESIDENCE TIME; SUPERCRITICAL WATER OXIDATION; TOC REMOVAL; TUBULAR REACTORS;

WASTEWATER TREATMENT;

2 PROPANOL; ACETIC ACID; AMMONIA; NITROGEN; OXYGEN; WATER;

ACETIC ACID; AMMONIA; COMBUSTION; CONCENTRATION (COMPOSITION); EXPERIMENTAL STUDY; INDUSTRIAL WASTE; MINERALIZATION; OXIDATION; POLLUTANT REMOVAL; RESIDENCE TIME; STREAMWATER; TOTAL ORGANIC CARBON; WASTEWATER; WATER TREATMENT;

ARTICLE; EXPERIMENTAL STUDY; INDUSTRIAL WASTE; MEAN RESIDENCE TIME; OXIDATION; PRIORITY JOURNAL; TEMPERATURE; TUBULAR REACTOR;

EID: 79953163210     PISSN: 00431354     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.watres.2011.01.029     Document Type: Article

References (27)

1. Al-Duri B., Pinto L., Ashraf-Ball N.H., Santos R.C.D. Thermal abatement of nitrogen-containing hydrocarbons by non-catalytic supercritical water oxidation (SCWO). Journal of Materials Science 2008, 43(4):1421-1428.
2. Augustine C., Tester J.W. Hydrothermal flames: from phenomenological experimental demonstrations to quantitative understanding. Journal of Supercritical Fluids 2009, 47(3):415-430.
3. Bermejo M.D., Cocero M.J. Supercritical water oxidation: a technical review. Aiche Journal 2006, 52(11):3933-3951.
4. Bermejo M.D., Fdez-Polanco E., Cocero M.J. Experimental study of the operational parameters of a transpiring wall reactor for supercritical water oxidation. Journal of Supercritical Fluids 2006, 39(1):70-79.
5. Bermejo M.D., Cantero F., Cocero M.J. Supercritical water oxidation of feeds with high ammonia concentrations: pilot plant experimental results and modeling. Chemical Engineering Journal 2008, 137(3):542-549.
6. Bermejo M.D., Cabeza P., Bahr M., Fernandez R., Rios V., Jimenez C., Cocero M.J. Experimental study of hydrothermal flames initiation using different static mixer configurations. Journal of Supercritical Fluids 2009, 50(3):240-249.
7. Bermejo M.D., Cabeza P., Queiroz J.P.S., Jiménez C., Cocero M.J. Analysis of the scale up of a transpiring wall reactor with a hydrothermal flame as a heat source for the supercritical water oxidation. The Journal of Supercritical Fluids 2011, 56(1):21-32.
8. Boock L.T., Klein M.T. Lumping strategy for modeling the oxidation of c1-c3 alcohols and acetic-acid in high-temperature water. Industrial & Engineering Chemistry Research 1993, 32(11):2464-2473.
9. Brunner G. Near and supercritical water. Part II: oxidative processes. Journal of Supercritical Fluids 2009, 47(3):382-390.
10. Cocero M.J., Alonso E., Torio R., Vallelado D., Fdz-Polanco F. Supercritical water oxidation in a pilot plant of nitrogenous compounds: 2-propanol mixtures in the temperature range 500-750 degrees C. Industrial & Engineering Chemistry Research 2000, 39(10):3707-3716.
11. Goto M., Nada T., Kodama A., Hirose T. Kinetic analysis for destruction of municipal sewage sludge and alcohol distillery wastewater by supercritical water oxidation. Industrial & Engineering Chemistry Research 1999, 38(5):1863-1865.
12. O'Regan J., Preston S., Dune A. Supercritical Water Oxidation of Sewage Sludge-An Update, in SCFI 2010.
13. Killilea W.R., Swallow K.C., Hong G.T. The fate of nitrogen in supercritical water oxidation. Journal of Supercritical Fluids 1992, 5(1):72-78.
14. Leybros A., Roubaud A., Guichardon P., Boutin O. Ion exchange resins destruction in a stirred supercritical water oxidation reactor. The Journal of Supercritical Fluids 2010, 51:369-375.
15. Li L., Chen P., Gloyna E.F. Generalized kinetic-model for wet oxidation of organic-compounds. Aiche Journal 1991, 37(11):1687-1697.
16. Magoulas D.T.C. Thermophysical properties of n-alkanes from C1 to C26 and their prediction for higher ones. Fluid Phase Equilibria 1990, 56:119-140.
17. Mateos D., Portela J.R., Mercadier J., Marias F., Marraud C., Cansell F. New approach for kinetic parameters determination for hydrothermal oxidation reaction. Journal of Supercritical Fluids 2005, 34(1):63-70.
18. Meyer J.C., Marrone P.A., Tester J.W. Acetic-acid oxidation and hydrolysis in supercritical water. Aiche Journal 1995, 41(9):2108-2121.
19. Oh C.H., Kochan R.J., Charlton T.R., Bourhis A.L. Thermal-hydraulic modeling of supercritical water oxidation of ethanol. Energy & Fuels 1996, 10(2):326-332.
20. Ploeger J.M., Madlinger A.C., Tester J.W. Revised global kinetic measurements of ammonia oxidation in supercritical water. Industrial & Engineering Chemistry Research 2006, 45(20):6842-6845.
21. Pohsner G.M., Franck E.U. Spectra and temperatures of diffusion flames at high-pressures to 1000 bar. Berichte Der Bunsen-Gesellschaft-Physical Chemistry Chemical Physics 1994, 98(8):1082-1090.
22. Savage P.E., Smith M.A. Kinetics of acetic-acid oxidation in supercritical water. Environmental Science & Technology 1995, 29(1):216-221.
23. Segond N., Matsumura Y., Yamamoto K. Determination of ammonia oxidation rate in sub- and supercritical water. Industrial & Engineering Chemistry Research 2002, 41(24):6020-6027.
24. Serikawa R.M., Usui T., Nishimura T., Sato H., Hamada S., Sekino H. Hydrothermal flames in supercritical water oxidation: investigation in a pilot scale continuous reactor. Fuel 2002, 81(9):1147-1159.
25. Wightman T.J. Studies in Supercriticalair Oxidation 1981, Berkeley, CA.
26. Vogel F., Blanchard J.L.D., Marrone P.A., Rice S.F., Webley P.A., Peters W.A., Smith K.A., Tester J.W. Critical review of kinetic data for the oxidation of methanol in supercritical water. Journal of Supercritical Fluids 2005, 34(3):249-286.
27. Wellig B., Weber M., Lieball K., Prikopsky K., von Rohr P.R. Hydrothermal methanol diffusion flame as internal heat source in a SCWO reactor. Journal of Supercritical Fluids 2009, 49(1):59-70.