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Volumn 19, Issue 5, 2013, Pages 1599-1606

Giant residual dipolar 13C-1H couplings in high-spin organoiron complexes: Elucidation of their structures in solution by 13C NMR spectroscopy

Author keywords

iron; magnetism; NMR spectroscopy; residual dipolar coupling; structure elucidation

Indexed keywords

ALIGNMENT TENSORS; ALKYL COMPLEXES; NMR SPECTRUM; ORGANOIRON COMPLEXES; PARTIAL ALIGNMENT; RESIDUAL DIPOLAR COUPLINGS; STRONG MAGNETIC FIELDS; STRUCTURAL REFINEMENT; STRUCTURE ELUCIDATION;

EID: 84872720401     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201203450     Document Type: Article
Times cited : (28)

References (129)
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    • A few similar iron-alkyl compounds with pincertype ligands have been reported, but not analyzed regarding the exact structure in solution
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    • CH throughout this work to prevent confusion with the temperature T.
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    • 13C NMR spectra have been recorded at 19.9 T by Peter Dvortsák at Bruker Biospin GmbH (Rheinstetten, Germany).
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    • MSpin can treat methyl groups as freely rotating, whereas PALES does not offer this function, but has several practical advantages.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.