Precise synthesis of new triblock co- and terpolymers by a methodology combining living anionic polymers with a specially designed linking reaction

Macromolecular Symposia

Volumn 323, Issue 1, 2013, Pages 26-36

  Matsuo, Yuri ^a   Oie, Toshiyuki ^a   Goseki, Raita ^a   Ishizone, Takashi ^a   Sugiyama, Kenji ^b   Hirao, Akira ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b HOSEI UNIVERSITY   (Japan)

Author keywords

linking reaction; living anionic polymers, triblock copolymers, triblock terpolymers

Indexed keywords

ANIONIC POLYMERS; CONTROLLED MOLECULAR WEIGHT; LINKING REACTION; METHYLSTYRENE; MOLECULAR ASYMMETRY; NARROW MOLECULAR WEIGHT DISTRIBUTIONS; NUCLEOPHILICITIES; POLY(2-HYDROXYETHYL METHACRYLATE); POLY(2-VINYLPYRIDINE) (P2VP); POLY(4-VINYL PYRIDINE); REACTION SITES; SEQUENTIAL POLYMERIZATION; TRIBLOCK TERPOLYMERS; TRIBLOCKS; WELL-DEFINED STRUCTURES;

ACRYLIC MONOMERS; BLOCK COPOLYMERS; ESTERS; PHEMA; POLYMERIZATION; POLYSTYRENES; STEREOCHEMISTRY; TERPOLYMERS;

POLYMERS;

EID: 84872710792     PISSN: 10221360     EISSN: 15213900     Source Type: Journal    
DOI: 10.1002/masy.201100102     Document Type: Article

References (36)

1. H. Watanabe, in: " Rheology of Multiphase Polymeric Materials. Structure and Properties of Multiphase Polymeric Materials ", T. Araki, T. Qui, M. Shibayama, Eds., Marcel Dekker, New York 1998, Chapter 9.
2. W. Hamly, in " The Physics of Block Copolymers ", Oxford University Press, New York 1998.
3. C. Park, J. Yoon, E. L. Thomas, Polymer, 2003, 44, 6724.
4. H. Mori, A. H. E. Müller, Prog. Polym. Sci. 2003, 28, 1403.
5. R. Adhikari, G. H. Micher, Prog. Polym. Sci. 2004, 29, 949.
6. N. Hadjichristidis, H. Iatrou, M. Pitsikalis, S. Pispas, A. Avgeropoulos, Prog. Polym. Sci. 2005, 30, 725.
7. F. J. M. Hoeben, P. Jonkheijm, E. W. Meijer, A. P. J. H. Schenning, Chem. Rev. 2005, 105, 1491.
8. V. Abetz, P. F. W. Simon, Adv. Polym. Sci. 2005, 189, 125.
9. N. Hadjichristidis, A. Hirao, Y. Tezuka, F. Du Prez, in: " Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly ", John Wiley & Sons (Asia), Singapore 2011.
10. R. I. Spontak, S. D. Smith, J. Polym. Sci. Part B: Polym. Phys. 2001, 39, 947.
11. M. E. Vigild, C. Chu, M. Sugiyama, K. A. Chaffin, F. S. Bates, Macromolecules 2001, 34, 951.
12. Y. Mori, L. S. Lim, F. S. Bates, Macromolecules 2003, 36, 9879.
13. R. Nap, I. Erukhimovich, G. T. Bricke, Macromolecules 2004, 37, 4296.
14. Y. Nagata, J. Matsuda, A. Noro, D. Cho, A. Takano, Y. Matsushita, Macromolecules 2005, 38, 10220.
15. L. Wu, T. P. Lodge, F. S. Bates, Macromolecules 2006, 39, 294.
16. R. Nap, N. Sushko, I. Erukhimovich, G. T. Bricke, Macromolecules 2006, 39, 6770.
17. H. Watanabe, Y. Matsumiya, T. Sawada, T. Iwamoto, Macromolecules 2007, 40, 6885.
18. Y. Matsushita, Macromolecules 2007, 40, 771.
19. R. Stadler, C. Austrra, J. Beckmann, U. Krappe, I. Voit-Martin, L. Leibler, Macromolecules 1995, 28, 3080.
20. E. Giebeler, R. Stadler, Macromol. Chem. Phys. 1997, 198, 3815.
21. S. Ludwig, A. Böker, V. Abetz, A. H. E. Müller, G. Krausch, Polymer 2003, 44, 6815.
22. S. Ludwig, A. Böker, A. Voronov, N. Rehse, R. Magerle, G. Krausch, Nature Mater. 2003, 2, 744.
23. F. H. Schacher, A. Walther, M. Ruppel, M. Drechsler, A. H. E. Müller, Macromolecules 2009, 42, 3540.
24. F. H. Schacher, J. Yuan, H. J. Schoberth, A. H. E. Müller, Polymer 2010, 51, 2021.
25. A. Sperschneider, H. F. Schacher, L. Tsarkova, A. Böker, V. Abetz, A. H. E. Müller, Macromolecules 2010, 43, 10213.
26. H. L. Hsieh, R. P. Quirk, in: " Anionic Polymerization: Principles and Applications " Marcel Dekker, New York 1996.
27. A. Hirao, Y. Matsuo, T. Oie, R. Goseki, T. Ishizone, K. Sugiyama, A. H. Gröschel, A. H. E. Müller, Macromolecles 2011, 44, 6345.
28. K. Sugiyama, T. Oie, A. A. El-Magd, A. Hirao, Macromolecules 2010, 43, 1403.
29. T. Hirano, H.-S. Yoo, Y. Ozama, A. A. El-Magd, K. Sugiyama, A. Hirao, J. Inorg. Organomet. Polym. Mater. 2010, 20, 445.
30. A. Hirao, R. Inushima, T. Nakayama, T. Watanabe, H.-S. Yoo, T. Ishizone, K. Sugiyama, T. Kakuchi, S. Carlotti, A. Deffieux, Eup. Polym. J. 2011, 47, 713.
31. The crossover polymerization was examined by the polymerization of either styrene or MMA with a living PS-b-P4VP, instead of a living 4VP insoluble in THF.
32. V. Bellas, H. Iatrou, N. Hadjichristidis, Macromolecules 2000, 33, 6993.
33. V. Bellas, H. Iatrou, E. N. Pitsinos, N. Hadjichristidis, Macromolecules 2001, 34, 5376.
34. P. G. Fragouli, H. Iatrou, N. Hadjichristidis, J. Polym. Sci. Part A: Polym. Chem. 2004, 42, 514.
35. P. G. Fragouli, H. Iatrou, D. J. Lohse, N. Hadjichristidis, J. Polym. Sci. Part A: Polym. Chem. 2008, 46, 3938.
36. A. Hirao, S. Loykulnant, T. Ishizone, Prog. Polym. Sci. 2002, 27, 1399.