Facile synthesis of triblock co- and terpolymers of styrene, 2-vinylpyridine, and methyl methacrylate by a new methodology combining living anionic diblock copolymers with a specially designed linking reaction

Macromolecules

Volumn 44, Issue 16, 2011, Pages 6345-6355

  Hirao, Akira ^a   Matsuo, Yuri ^a   Oie, Toshiyuki ^a   Goseki, Raita ^a   Ishizone, Takashi ^a   Sugiyama, Kenji ^b   Gröschel, André H ^c   Müller, Axel H E ^b  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b HOSEI UNIVERSITY   (Japan)

^c UNIVERSITY OF BAYREUTH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

2-VINYLPYRIDINE; FACILE SYNTHESIS; LINKING REACTION; LIVING ANIONIC POLYMERIZATION; METHYL METHACRYLATES; MICROSCOPIC STUDY; NARROW MOLECULAR WEIGHT DISTRIBUTIONS; POLY(2-VINYLPYRIDINE) (P2VP); POLYMER STRUCTURE; PREDICTABLE MOLECULAR WEIGHT; SYNTHESIZED POLYMERS; TRANSMISSION ELECTRON; TRIBLOCK TERPOLYMERS; TRIBLOCKS; WELL-DEFINED STRUCTURES;

ACRYLIC MONOMERS; ANIONIC POLYMERIZATION; BLOCK COPOLYMERS; COPOLYMERIZATION; ESTERS; LIVING POLYMERIZATION; MOLECULAR WEIGHT DISTRIBUTION; MORPHOLOGY; POLYMERS; POLYSTYRENES; STYRENE; SYNTHESIS (CHEMICAL);

TERPOLYMERS;

EID: 80051769496     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma201352z     Document Type: Article

References (51)

1. Watanabe, H. Rheology of Multiphase Polymeric Materials. In Structure and Properties of Multiphase Polymeric Materials; Akaki, T., Qui, T., and Shibayama, M., Eds.; Marcel Dekker: New York, 1998; Chapter 9.
2. Hamly, W. In The Physics of Block Copolymers: Oxford University Press: New York, 1998.
3. Park, C.; Yoon, J.; Thomas, E. L. Polymer 2003, 44, 6724
4. Mori, H.; Müller, A. H. E. Prog. Polym. Sci. 2003, 28, 1403
5. Adhikari, R.; Michler, G. H. Prog. Polym. Sci. 2004, 29, 949
6. Hoeben, F. J. M.; Jonkheijm, P.; Meijer, E. W.; Schenning, A. P. H. J. Chem. Rev. 2005, 105, 1491-1546
7. Hadjichristidis, N.; Iatrou, H.; Pitsikalis, M.; Pispas, S.; Avgeropoulos, A. Prog. Polym. Sci. 2005, 30, 725
8. Abetz, V.; Simon, P. F. W. Adv. Polym. Sci. 2005, 189, 125
9. Hadjichristidis, N.; Hirao, A.; Tezuka, Y.; Du Prez, F. In Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly; John Wiley & Sons (Asia) Pte Ltd.: Singapore, 2011.
10. Hsieh, H, L.; Quirk, R, P. In Anionic Polymerization: Principles and Applications; Marcel Dekker: New York, 1996.
11. Phalip, P.; Favier, J. C.; Sigwalt, P. Polym. Bull. 1984, 12, 331
12. Matsushita, Y.; Mogi, Y.; Mukai, H.; Watanabe, J.; Noda, I. Polymer 1994, 35, 246
13. Spontak, R. I.; Smith, S. D. J. Polym. Sci., Part B: Polym. Phys. 2001, 39, 947
14. Vigild, M. E.; Chu, C.; Sugiyama, M.; Chaffin, K. A.; Bates, F. S. Macromolecules 2001, 34, 951
15. Hermel, T. J.; Hahn, S. F.; Chaffin, K. A.; Gerberich, W. W.; Bates, F. S. Macromolecules 2003, 36, 2190
16. Mori, Y.; Lim, L. S.; Bates, F. S. Macromolecules 2003, 36, 9879
17. Wu, L.; Cochran, E. W.; Lodge, T. P.; Bates, F. S. Macromolecules 2004, 37, 3360
18. Nap, R.; Erukhimovich, I.; Bricke, G. T. Macromolecules 2004, 37, 4296
19. Wu, L.; Lodge, T. P.; Bates, F. S. Macromolecules 2004, 37, 8184
20. Nagata, Y.; Matsuda, J.; Noro, A.; Cho, D.; Takano, A.; Matsushita, Y. Macromolecules 2005, 38, 10220
21. Wu, L.; Lodge, T. P.; Bates, F. S. Macromolecules 2006, 39, 294
22. Nap, R.; Sushko, N.; Erukhimovich, I.; Bricke, G. T. Macromolecules 2006, 39, 6770
23. Watanabe, H.; Matsumiya, Y.; Sawada, T.; Iwamoto, T. Macromolecules 2007, 40, 6885
24. Matsushita, Y. Macromolecules 2007, 40, 771
25. Mogi, Y.; Kotsuji, H.; Kaneko, Y.; Mori, K.; Matsushita, Y.; Noda, I. Macromolecules 1992, 25, 5408
26. Nakazawa, H.; Ohota, T. Macromolecules 1993, 26, 5503
27. Stadler, R.; Austrra, C.; Beckmann, J.; Krappe, U.; Voigt-Martin, I.; Leibler, L. Macromolecules 1995, 28, 3080
28. Matsen, M. W. J. Chem. Phys. 1998, 108, 785
29. Bates, F.; Fredrickson, G. H. Phys. Today 1999, 52, 38
30. Ishizone, T.; Sugiyama, K.; Sakano, Y.; Mori, H.; Hirao, A.; Nakahama, S. Polym. J. 1999, 31, 983
31. Tanaka, Y.; Hasegawa, H.; Hashimoto, T.; Ribbe, A.; Sugiyama, K.; Hirao, A.; Nakahama, S. Polym. J. 1999, 31, 989
32. Suzuki, J.; Seki, M.; Matsushita, Y. J. Chem. Phys. 2000, 112, 4862
33. Jiang, S.; Gopfert, A.; Abetz, V. Macromolecules 2003, 36, 6171
34. Matsushita, Y.; Takano, A.; Hayashida, K.; Asari, T.; Noro, A. Polymer 2009, 50, 2191
35. Hsieh, H. L.; Quirk, R. P. In Anionic Polymerization: Principles and Applications; Marcel Dekker: New York, 1996; Chapter 12, pp 307-331.
36. Giebeler, E.; Stadler, R. Macromol. Chem. Phys. 1997, 198, 3815
37. Ludwig, S.; Böker, A.; Abetz, V.; Müller, A. H. E.; Krausch, G. Polymer 2003, 44, 6815
38. Ludwig, S.; Böker, A.; Voronov, A.; Rehse, N.; Magerle, R.; Krausch, G. Nature Mater. 2003, 2, 744
39. Schacher, F.; Yuan, J.; Schoberth, H. G.; Müller, A. H. E. Polymer 2010, 51, 2021
40. Schacher, F.; Walther, A.; Ruppel, M.; Drechsler, M.; Müller, A. H. E. Macromolecules 2009, 42, 3540
41. Sperschneider, A.; Schacher, F. H.; Tsarkova, L.; Böker, A.; Müller, A. H. E. Macromolecules 2010, 43, 10213
42. Ekizoglou, N.; Hadjichristidis, N. J. Polym. Sci., Part A: Polym. Chem. 2001, 39, 1198
43. Ekizoglou, N.; Hadjichristidis, N. J. Polym. Sci., Part A: Polym. Chem. 2002, 40, 2166
44. Bellas, V.; Iatrou, H.; Hadjichristidis, N. Macromolecules 2000, 33, 6993
45. Bellas, V.; Iatrou, H.; Pitsinos, E. N.; Hadjichristidis, N. Macromolecules 2001, 34, 5376
46. Fragouli, P. G.; Iatrou, H.; Hadjichristidis, N. J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 514
47. Fragouli, P. G.; Iatrou, H.; Lohse, D. J.; Hadjichristidis, N. J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 3938
48. Sugiyama, K.; Oie, T.; El-Magd, A. A.; Hirao, A. Macromolecules 2010, 43, 1403
49. Xie, D.; Tomczak, S.; Hogen-Esch, T. E. J. Polym. Sci., Part A: Polym. Chem. 2001, 39, 1403
50. Hirao, A.; Murano, K.; Kurokawa, R.; Watanabe, T.; Sugiyama, K. Macromolecules 2009, 42, 7820
51. Hirao, A. Unpublished results.