Kinetics and mechanism for omethoate degradation by catalytic ozonation with Fe(III)-loaded activated carbon in water

Chemosphere

Volumn 90, Issue 6, 2013, Pages 1966-1972

  Qiang, Zhimin ^a   Ling, Wencui ^a   Tian, Fang ^a  

^a RESEARCH CENTER FOR ECO ENVIRONMENTAL SCIENCES   (China)

Author keywords

Catalytic ozonation; Kinetics; Mechanism; Omethoate; Toxicity

Indexed keywords

ACTIVATED CARBON; ENZYME KINETICS; KINETICS; MECHANISMS; MOLECULAR WEIGHT; OXALIC ACID; OZONE; OZONE WATER TREATMENT; OZONIZATION; RATE CONSTANTS; SULFUR COMPOUNDS; TOXICITY;

CATALYTIC OZONATION; DEGRADATION BY-PRODUCTS; HIGH MOLECULAR WEIGHT; HYDROXYL RADICALS; KINETICS AND MECHANISM; LOW MOLECULAR WEIGHT ORGANIC ACID; OMETHOATE; PYRROLIDIN-2-ONES;

IRON COMPOUNDS;

2 (METHYLTHIO)ACETAMIDE; ACETAMIDE DERIVATIVE; ACETIC ACID; ACTIVATED CARBON; CARBOXYLIC ACID; DRINKING WATER; FERRIC ION; FORMIC ACID; HYDROXYL RADICAL; INORGANIC COMPOUND; N METHYL 2 (METHYLTHIO)ACETAMIDE; N METHYL 2 SULFANYLACETAMIDE; NITRATE; O,O,O TRIMETHYLPHOSPHORIC ESTER; OMETHOATE; OXALIC ACID; OZONE; PHOSPHATE; PHOSPHOROTHIOIC ACID DERIVATIVE; PYRROLIDIN 2 ONE; PYRROLIDINE DERIVATIVE; SULFATE; TRIMETHYLTHIOPHOSPHATE; UNCLASSIFIED DRUG; WATER;

ACTIVATED CARBON; CATALYSIS; HYDROXYL RADICAL; OZONE; PH; REACTION KINETICS; TOXICITY; WATER TREATMENT;

ANALYTIC METHOD; ARTICLE; CATALYSIS; CATALYST; CATALYTIC OZONATION; CHEMICAL ANALYSIS; CHEMICAL COMPOSITION; CHEMICAL REACTION KINETICS; DEGRADATION; EXTRACTION; MOLECULAR WEIGHT; OZONATION; PH; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; WATER TREATMENT;

EID: 84872687443     PISSN: 00456535     EISSN: 18791298     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2012.10.059     Document Type: Article

References (26)

1. Acero J.L., Haderlein S.B., Schmidt T.C., Suter M.J.F., von Gunten U. MTBE oxidation by conventional ozonation and the combination ozone/hydrogen peroxide: Efficiency of the processes and bromate formation. Environ. Sci. Technol. 2001, 35:4252-4259.
2. Andreozzi R., Ialongo G., Marotta R., Sanchirico R. The thermal decomposition of dimethoate. J. Hazard. Mater. 1999, 64:283-294.
3. Bader H., Hoigné J. Determination of ozone in water by the indigo method: a submitted standard method. Ozone Sci. Eng. 1982, 4:169-176.
4. 2 plasma treatment. J. Agric. Food Chem. 2009, 57:6238-6245.
5. Coupe R.H., Manning M.A., Foreman W.T., Goolsby D.A., Majewski M.S. Occurrence of pesticides in rain and air in urban and agricultural area of Mississippi, April-September 1995. Sci. Total Environ. 2000, 248:227-240.
6. Evgenidou E., Konstantinou I., Fytianos K., Albanis T. Study of the removal of dichlorvos and dimethoate in a titanium dioxide mediated photocatalytic process through the examination of intermediates and the reaction mechanism. J. Hazard. Mater. 2006, 137:1056-1064.
7. Hoigné J., Bader H. Rate constants of reactions of ozone with organic and inorganic compounds in water-I. Non-dissociating organic compounds. Water Res. 1983, 17:173-183.
8. Kim B.S., Fujita H., Sakai Y., Sakoda A., Suzuki M. Catalytic ozonation of an organophosphorus pesticide using microporous silicate and its effect on total toxicity reduction. Water Sci. Technol. 2002, 46:35-41.
9. Ku Y., Lin H.S. Decomposition of phorate in aqueous solution by photolytic ozonation. Water Res. 2002, 36:4155-4159.
10. 2. App. Catal. B: Environ. 2012, 113-114:290-295.
11. Li Y., Hong H., Wang X., Hong L., Ye C. Estimation of the sources of organophosphorous pesticides in Xiamen sea area. Acta Scientiae Circumstantiae 2005, 25:1071-1077. (in Chinese).
12. Ling W.C., Qiang Z.M., Shi Y.W., Zhang T., Dong B.Z. Fe(III)-loaded activated carbon as catalyst to improve omethoate degradation by ozone in water. J. Mol. Catal. A: Chem. 2011, 342-343:23-29.
13. Liu C., Qiang Z.M., Adams C., Tian F., Zhang T. Kinetics and mechanism for degradation of dichlorvos by permanganate in drinking water treatment. Water Res. 2009, 43:3435-3442.
14. Mallipudi N.M., Umetsu N., Toia R.F., Talcott R.E., Fukuto T.R. Toxicity of O,O,S-trimethyl and triethyl phosphorothioate to the rat. J. Agric. Food Chem. 1979, 27:463-466.
15. Meijers R.T., OderwaldMuller E.J., Nuhn P.A.N.M., Kruithof J.C. Degradation of pesticides by ozonation and advanced oxidation. Ozone Sci. Eng. 1995, 17:673-686.
16. Farm Chemicals Handbook 1991, Meister Publication Co., Willoughby, OH. R.T. Meister (Ed.).
17. NCILB, 1973. Progress Report for Contract No. NIH-NCI-E-C-72-3252. Litton Bionetics, Inc., Bethesda, MD.
18. Pope C., Karanth S., Liu J. Pharmacology and toxicology of cholinesterase inhibitors: uses and misuses of a common mechanism of action. Environ. Toxicol. Pharmacol. 2005, 19:433-446.
19. 2 advanced oxidation process. Chemosphere 2010, 78:517-526.
20. Sánchez-Polo M., Rovera-Utrilla J., Prados-Joya G., Ferro-García M.A., Bautista-Toledo I. Removal of pharmaceutical compounds, nitroimidazoles, from waters by using the ozone/carbon system. Water Res. 2008, 42:4163-4171.
21. Schipper P.N., Wissers M.J., van der Linden A.M. Pesticides in groundwater and drinking water wells: overview of the situation in the Netherlands. Water Sci. Technol. 2008, 57:1277-1286.
22. Sinclair C.J., Boxall A.B.A., Parsons S.A., Thomas M.R. Prioritization of pesticide environmental transformation products in drinking water supplies. Environ. Sci. Technol. 2006, 40:7283-7289.
23. von Gunten U. Ozonation of drinking water: Part I. Oxidation kinetics and product formation. Water Res. 2003, 37:1443-1467.
24. Wang L., Lee F.S.C., Yin Y., Xu X., Zhou W., Wang X. Organophosphate pesticides residue monitoring and risk assessment in the sea-water from Laizhou Bay. J. Saf. Environ. 2007, 7:83-85. (in Chinese).
25. Westerhoff P., Aiken G., Amy G., Debroux J. Relationships between the structure of natural organic matter and its reactivity towards molecular ozone and hydroxyl radicals. Water Res. 1999, 33:2265-2276.
26. Wu J.G., Lan C.Y., Chan G.Y.S. Organophosphorus pesticide ozonation and formation of oxon intermediates. Chemosphere 2009, 76:1308-1314.