Study of the removal of dichlorvos and dimethoate in a titanium dioxide mediated photocatalytic process through the examination of intermediates and the reaction mechanism

Journal of Hazardous Materials

Volumn 137, Issue 2, 2006, Pages 1056-1064

  Evgenidou, E ^a   Konstantinou, I ^b   Fytianos, K ^a   Albanis, T ^b  

^a ARISTOTLE UNIVERSITY OF THESSALONIKI   (Greece)

^b UNIVERSITY OF IOANNINA   (Greece)

Author keywords

Degradation products; Dichlorvos; Dimethoate; Photocatalysis

Indexed keywords

DEALKYLATION; DEGRADATION PRODUCTS; DICHLORVOS; DIMETHOATES;

GAS CHROMATOGRAPHY; MASS SPECTROMETRY; OXIDATION; PHOTOCATALYSIS; REACTION KINETICS; SLURRIES; TITANIUM OXIDES;

INSECTICIDES;

DICHLORVOS; DIMETHOATE; DISULFIDE; ORGANOPHOSPHATE INSECTICIDE; TITANIUM DIOXIDE;

GAS CHROMATOGRAPHY; INSECTICIDES; MASS SPECTROMETRY; OXIDATION; PHOTOCATALYSIS; REACTION KINETICS; SLURRIES; TITANIUM OXIDES;

CATALYSIS; GAS CHROMATOGRAPHY; INSECTICIDE; MASS SPECTROMETRY; ORGANOPHOSPHATE; OXIDATION; SLURRY; TITANIUM;

ARTICLE; DEALKYLATION; DEGRADATION; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; OXIDATION; PHOTOCATALYSIS; REACTION ANALYSIS; SOLID PHASE EXTRACTION;

CATALYSIS; DICHLORVOS; DIMETHOATE; LIGHT; TITANIUM; ULTRAVIOLET RAYS;

EID: 33748427049     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2006.03.042     Document Type: Article

References (48)

1. Konstantinou I.K., and Albanis T.A. Photocatalytic transformation of pesticides in aqueous titanium dioxide suspensions using artificial and solar light: intermediates and degradation pathways. Appl. Catal. B: Environ. 42 (2003) 319-335
2. Herrmann J.-M. Heterogeneous photocatalysis: fundamentals and applications to the removal of various types of aqueous pollutants. Catal. Today 53 (1999) 115-129
3. 2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: a review. Appl. Catal. B: Environ. 49 (2004) 1-14
4. Bhatkhande D.S., Pangarkar V.G., and ACM Beenackers A. Photocatalytic degradation for environmental applications-a review. J. Chem. Technol. Biotechnol. 77 (2001) 102-116
5. Hoffmann M.R., Martin S.T., Choi W., and Bahnemann D.W. Environmental applications of semiconductor photocatalysis. Chem. Rev. 95 (1995) 69-96
6. Chu W., and Wong C.C. Study of herbicide alachlor removal in a photocatalytic process through the examination of the reaction mechanism. Ind. Eng. Chem. Res. 43 (2004) 5027-5031
7. 2: toxicity of intermediates. Water Res. 31 (1997) 1728-1732
8. Chiron S., Fernandez-Alba A., Rodriguez A., and Garcia-Calvo E. Pesticide chemical oxidation: state-of-the-art. Water Res. 34 (2000) 366-377
9. 2 suspensions. Anal. Chim. Acta 467 (2002) 233-243
10. Ragnarsdottir K.V. Environmental fate and toxicology of organophosphate pesticides. J. Geol. Soc. 157 (2000) 859-876
11. Mileson B.E., Chambers J.E., Chen W.L., Dettbarn W., Ehrich M., Eldefrawi A.T., Gaylor D.W., Hamernik K., Hodgson E., Karczmar A.G., Padilla S., Pope C.N., Richardson R.J., Saunders D.R., Sheets L.P., Sultatos L.G., and Wallace K.B. Common mechanism of toxicity: a case study of organophosphorus pesticides. Toxicol. Sci. 41 (1998) 8-20
12. Albanis T.A., Hela D.G., Sakellarides T.M., and Konstantinou I.K. Monitoring of pesticide residues and their metabolites in surface and underground waters of Imathia (N. Greece) by means of solid-phase extraction disks and gas chromatography. J. Chromatogr. A 823 (1998) 59-71
13. Konstantinou I.K., Hela D.G., and Albanis T.A. The status of pesticide pollution in surface waters (rivers and lakes) of Greece. Part I. Review on occurence and levels. Environ. Pollut. 141 (2006) 555-570
14. Evgenidou E., Fytianos K., and Poulios I. Photocatalytic oxidation of dimethoate in aqueous solutions. J. Photochem. Photobiol. A: Chem. 175 (2005) 29-38
15. 2 and ZnO as catalysts. Appl. Catal. B: Environ. 59 (2005) 81-89
16. 2/beads by sunlight. Sol. Energy 79 (2005) 1-9
17. Naman S.A., Khammas Z.A.A., and Hussein F.M. Photo-oxidative degradation of insecticide dichlorvos by a combined semiconductors and organic sensitizers in aqueous media. J. Photochem. Photobiol. A: Chem. 153 (2002) 229-236
18. Dominguez C., Garcia J., Pedraz M.A., Torres A., and Galan M.A. Photocatalytic oxidation of organic pollutants in water. Catal. Today 40 (1998) 85-101
19. Oller I., Gernjak W., Maldonado M.I., Fernandez-Ibanez P., Blanco J., Sanchez-Perez J.A., and Malato S. Degradation of the insecticide dimethoate by solar photocatalysis at pilot plant scale. Environ. Chem. Lett. 3 (2005) 118-121
20. Nikolaki M.D., Oreopoulou A.G., and Philipopoulos C.J. Photo-fenton assisted reaction of dimethoate in aqueous solutions. J. Environ. Sci. Health 40 (2005) 233-246
21. 2 suspensions. Environ. Sci. Technol. 35 (2001) 398-405
22. Eto M. Organophosphorous Pesticides: Organic and Biological Chemistry (1974), CRC Press, Inc, Cleveland, Ohio
23. Kerzhentsev M., Guillard C., Herrmann J.M., and Pichat P. Photocatalytic pollutant removal in water at room temperature: case study of the total degradation of the insecticide fenitrothion (phosphorothioic acid O,O-dimethyl-O-(3-methyl-4-nitro-phenyl) ester). Catal. Today 27 (1996) 215-220
24. Andreozzi R., Ialongo G., Marotta R., and Sanchirico R. The thermal decomposition of dimethoate. J. Hazard. Mater. B 64 (1999) 283-294
25. Menzie C.M. Metabolism of Pesticides (1969), US Department of the Interior, Fish and Wildlife Service, Washington, DC pp. 160-166
26. Durand G., Mansour M., and Barcelo D. Identification and determination of fenithrothion photolysis products in water-methanol by gas chromatography-mass spectrometry. Anal. Chim. Acta 262 (1992) 167-178
27. Dannenberg A., and Pehkonen S.O. Investigation of the heterogeneously catalyzed hydrolysis of organophosphorus pesticides. J. Agric. Food Chem. 46 (1998) 325-334
28. Hong F., and Pehkonen S. Hydrolysis of phorate using simulated environmental conditions: rates, mechanisms and product analysis. J. Agric. Food Chem. 46 (1998) 1192-1199
29. 2 suspensions: identification of intermediates and the reaction pathway. Appl. Catal. B: Environ. 34 (2001) 227-239
30. 2-mediated photocatalytic oxidation of thioethers. Tetrahedron Lett. 31 (1990) 4533-4536
31. In: Oae S. (Ed). Organic Sulphur Chemistry: Structure and Mechanism (1991), CRC Press, Boca Raton 203
32. Vidal A., Dinya Z., Mogyorodi Jr. F., and Mogyorodi F. Photocatalytic degradation of thiocarbamate herbicide active ingredients in water. Appl. Catal. B: Environ. 21 (1999) 259-267
33. Wu Z.L., Ondruschka B., and Stark A. Ultrasonic cleavage of thioethers. J. Phys. Chem. A 109 (2005) 3762-3766
34. Herrmann J.M., Guillard C., Arguello M., Aguera A., Tejedor A., Piedra L., and Ferrnandez-Alba A. Photocatalytic degradation of pesticide pirimiphos-methyl: determination of the reaction pathway and identification of intermediate products by various analytical methods. Catal. Today 54 (1999) 353-367
35. Casida J.E., McBride L., and Niedrmeier R.P. Insecticide metabolism, metabolism of 2,2-dichlorovinyl dimethyl phosphate in relation to residues in milk and mammalian tissues. J. Agric. Food Chem. 10 (1962) 370-377
36. Obee T.N., and Satyapal S. Photocatalytic decomposition of DMMP on titania. J. Photochem. Photobiol. A: Chem. 118 (1998) 45-51
37. 2 suspensions. J. Photochem. Photobiol. A: Chem. 107 (1997) 221-226
38. Schramm J.D., and Hua I. Ultrasonic irradiation of dichlorvos: decomposition mechanism. Water Res. 35 (2001) 665-674
39. Vlyssides A., Barampouti E.M., Mai S., Arapoglou D., and Kotronarou A. Degradation of methyl parathion in aqueous solution by electrochemical oxidation. Environ. Sci. Technol. 38 (2004) 6125-6131
40. Atiqur Rahman M., and Muneer M. Photocatalysed degradation of two selected pesticide derivatives, dichlorvos and phosphamidon, in aqueous suspensions of titanium dioxide. Desalination 181 (2005) 161-172
41. Jokanovi M. Biotransformation of organophosphorus compounds. Toxicology 166 (2001) 139-160
42. Spencer W.F., Adams J.D., Shoup T.D., and Spear R.C. Conversion of parathion to paraoxon on soil dusts and clay minerals as affected by ozone and UV light. J. Agric. Food Chem. 28 (1980) 366-371
43. Galli R., Rich W.H., and Scholtz R. Toxicity of organophosphate insecticides and their metabolites to the water flea Daphnia magna, the Microtox test and an acetylocholinesterase inhibition test. Aquat. Toxicol. 30 (1994) 259-269
44. Thompson C.M. Preparation, analysis and toxicity of phosphorothiolates. In: Chambers J.E., and Levi P.E. (Eds). Organophosphates: Chemistry, Fate and Effects (1992), Academic Press Inc., San Diego, California 41-42
45. Oki K., Tsuchida S., Nishikiori H., Tanaka N., and Fujii T. Photocatalytic degradation of chlorinated ethenes. Int. J. Photoenergy 5 (2003) 11-15
46. Deneer J.W. Toxicity of mixtures of pesticides in aquatic systems. Pest Manag. Sci. 56 (2000) 516-520
47. Dzyadevych S.V., Soldatkin A.P., and Chovelon J.M. Assessment of the toxicity of methyl parathion and its photodegradation products in water samples using conductometric enzyme biosensors. Anal. Chim. Acta 459 (2002) 33-41
48. Lu M.C., Roam G.D., Chert J.N., and Huang C.P. Microtox bioassay of photodegradation products from photocatalytic oxidation of pesticides. Chemosphere 27 (1993) 1637-1647