Nanopatterning of substrates by self-assembly in supramolecular block copolymer monolayer films

Science China Chemistry

Volumn 56, Issue 1, 2013, Pages 48-55

  Perepichka, Iryna I ^a   Chen, Ximin ^a   Bazuin, C Géraldine ^a  

^a UNIVERSITÉ DE MONTRÉAL   (Canada)

Author keywords

Langmuir Blodgett monolayer patterns; self assembly; supramolecular block copolymers; ultrathin films

Indexed keywords

4-VINYL PYRIDINE; AIR/WATER INTERFACES; BLOCK COPOLYMER SELF-ASSEMBLY; BLOCK COPOLYMER TEMPLATES; GOLD DEPOSITION; INTERNAL STRUCTURE; LANGMUIR BLODGETT TECHNIQUES; LANGMUIR-BLODGETT MONOLAYERS; MONOLAYER FILM; MORPHOLOGY FORMATION; NANO-SCALE PATTERNS; NANOPATTERNING; NANOSTRAND NETWORKS; TECHNOLOGICAL APPLICATIONS;

ACETONE; GOLD; LANGMUIR BLODGETT FILMS; MONOLAYERS; POLYSTYRENES; SELF ASSEMBLY; SUPRAMOLECULAR CHEMISTRY; ULTRATHIN FILMS;

BLOCK COPOLYMERS;

EID: 84872617740     PISSN: 16747291     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11426-012-4776-6     Document Type: Conference Paper

References (41)

1. Hamley IW. Nanostructure fabrication using block copolymers. Nanotechnology, 2003, 14: R39-R54
2. Mendes PM, Preece JA. Precision chemical engineering: integrating nanolithography and nanoassembly. Curr Opin Coll Interf Sci, 2004, 9: 236-248
3. Li M, Coenjarts CA, Ober CK. Patternable block copolymers. Adv Polym Sci, 2005, 190: 183-226
4. Olson DA, Chen L, Hillmyer MA. Templating nanoporous polymers with ordered block copolymers. Chem Mater, 2008, 20: 869-890
5. van Zoelen W, ten Brinke G. Thin films of complexed block copolymers. Soft Matter, 2009, 5: 1568-1582
6. Marencic AP, Register RA. Controlling order in block copolymer thin films for nanopatterning applications. Annu Rev Chem Biomol Eng, 2010, 1: 277-297
7. Sidorenko A, Tokarev I, Minko S, Stamm M. J Am Chem Soc, 2003, 125: 12211-12216
8. Tokarev I, Krenek R, Burkov Y, Schmeisser D, Sidorenko A, Minko S, Stamm M. Microphase separation in thin films of poly(styrene-block-4-vinylpyridine) copolymer-2-(4′-hydroxybenzeneazo)benzoic acid assembly. Macromolecules, 2005, 38: 507-516
9. Roland S, Prud'homme RE, Bazuin CG. Morphology, thickness, and composition evolution in supramolecular block copolymer films over a wide range of dip-coating rates. ACS Macro Lett, 2012, 1: 973-976
10. Zhu J, Eisenberg A, Lennox RB. Interfacial behavior of block polyelectrolytes. 1. Evidence for novel surface micelle formation. J Am Chem Soc, 1991, 113: 5583-5588
11. Zhu J, Lennox RB, Eisenberg A. Interfacial behavior of block polyelectrolytes. 4. Polymorphism of (quasi) two-dimensional micelles. J Phys Chem, 1992, 96: 4727-4730
12. Zhu J, Eisenberg A, Lennox RB. Interfacial behavior of block polyelectrolytes. 5. Effect of varying block lengths on the properties of surface micelles. Macromolecules, 1992, 25: 6547-6555
13. Baker SM, Leach KA, Devereaux CE, Gragson DE. Controlled patterning of diblock copolymers by monolayer Langmuir-Blodgett deposition. Macromolecules, 2000, 33: 5432-5436
14. Devereaux CA, Baker SM. Surface features in Langmuir-Blodgett monolayers of predominantly hydrophobic poly(styrene)-poly(ethylene oxide) diblock copolymer. Macromolecules, 2002, 35: 1921-1927
15. Cheyne RB, Moffitt MG. Novel two-dimensional "ring and chain" morphologies in Langmuir-Blodgett monolayers of PS-b-PEO block copolymers: Effect of spreading solution concentration on self-assembly at the air-water interface. Langmuir, 2005, 21: 5453-5460
16. Cheyne RB, Moffitt MG. Self-assembly of polystyrene-block-poly(ethylene oxide) copolymers at the air-water interface: is dewetting the genesis of surface aggregate formation? Langmuir, 2006, 22: 8387-8396
17. Price EW, Guo Y, Wang CW, Moffitt MG. Block copolymer strands with internal microphase separation structure via self-assembly at the air-water interface. Langmuir, 2009, 25: 6398-6406
18. Harirchian-Saei S, Wang MCP, Gates BD, Moffitt MG. Patterning block copolymer aggregates via Langmuir-Blodgett transfer to microcontact-printed substrates. Langmuir, 2010, 26: 5998-6008
19. Perepichka II, Badia A, Bazuin CG. Nanostrand formation of block copolymers at the air/water interface. ACS Nano, 2010, 4: 6825-6835
20. Lu Q, Bazuin CG. Solvent-assisted formation of nanostrand networks from supramolecular diblock copolymer/surfactant complexes at the air/water interface. Nano Lett, 2005, 5: 1309-1314
21. Li S, Hanley S, Khan I, Varshney SK, Eisenberg A, Lennox RB. Surface micelle formation at the air/water interface from nonionic diblock copolymers. Langmuir, 1993, 9: 2243-2246
22. Li S, Clarke CJ, Lennox RB, Eisenberg A. Two-dimensional self assembly of polystyrene-b-poly(butyl-methacrylate) diblock copolymers. Colloids Surf A, 1998, 133: 191-203
23. Li S, Clarke CJ, Eisenberg A, Lennox RB. Langmuir films of polystyrene-b-poly(alkyl acrylate) diblock copolymers. Thin Solid Films, 1999, 354: 136-141
24. Cox JK, Yu K, Constantine B, Eisenberg A, Lennox RB. Polystyrenepoly(ethylene oxide) diblock copolymers form well-defined surface aggregates at the air/water interface. Langmuir, 1999, 15: 7714-7718
25. Cox JK, Yu K, Eisenberg A, Lennox RB. Compression of polystyrene- poly(ethylene oxide) surface aggregates at the air/water interface. Phys Chem Chem Phys, 1999, 1: 4417-4421
26. Perepichka II. Self-assembly of PS-PVP block copolymers and their complexes at the air/water interface. Dissertation for the Doctoral Degree. Montréal: Université de Montréal, 2011
27. Ruokolainen J, Mäkinen R, Torkkeli M, Mäkelä T, Serimaa R, ten Brinke G, Ikkala O. Switching supramolecular polymeric materials with multiple length scales. Science, 1998, 280: 557-560
28. Ruokolainen J, ten Brinke G, Ikkala O. Supramolecular polymeric materials with hierarchical structure-within-structure morphologies. Adv Mater, 1999, 11: 777-780
29. van Zoelen W, Asumaa T, Ruokolainen J, Ikkala O, ten Brinke G. Phase behavior of solvent vapor annealed thin films of PS-b-PVP(PDP) supramolecules. Macromolecules, 2008, 41: 3199-3208
30. van Zoelen W, Polushkin E, ten Brinke G. Hierarchical terrace formation in PS-b-PVP(PDP) supramolecular thin films. Macromolecules, 2008, 41: 8807-8814
31. Perepichka II, Lu Q, Badia A, Bazuin CG. Understanding and controlling morphology evolution in Langmuir-Blodgett block copolymer films using PS-P4VP and PS-P4VP/PDP. Submitted
32. Li Z, Zhao W, Quinn J, Rafailovich MH, Sokolov J, Lennox RB, Eisenberg A, Wu XZ, Kim MW, Sinha SK, Tolan M. X-ray reflectivity of diblock copolymer monolayers at the air/water interface. Langmuir, 1995, 11: 4785-4792
33. Shin K, Rafailovich MH, Sokolov J, Chang DM, Cox JK, Lennox RB, Eisenberg A, Gibaud A, Huang J, Hsu SL, Satija SK. Observation of surface ordering of alkyl side chains in polystyrene/polyelectrolyte diblock copolymer Langmuir films. Langmuir, 2001, 17: 4955-4961
34. Glagola CP, Miceli LM, Milchak MA, Halle EH, Logan JL. Polystyrenepoly(ethylene oxide) diblock copolymer: The effect of polystyrene and spreading concentration at the air/water interface. Langmuir, 2012, 28: 5048-5058
35. Perepichka II, Borozenko K, Badia A, Bazuin CG. Pressure-induced order transition in nanodot-forming diblock copolymers at the air/water interface. J Am Chem Soc, 2011, 133: 19702-19705
36. Chen X, Perepichka II, Bazuin CG. Patterning gold in double stripes using PS-P4VP/PDP Langmiur-Blodgett nanostrand templates. Submitted
37. Ruokolainen J, ten Brinke G, Ikkala O, Torkkeli M, Serimaa R. Mesomorphic structures in flexible polymer-surfactant systems due to hydrogen bonding: poly(4-vinylpyridine)-pentadecylphenol. Macromolecules, 1996, 29: 3409-3415
38. Tashmukhamedov SA, Tsagarayev ET, Tillayev RS, Usmanov KU. Eletron-microscope study of the structure of acetyl cellulose-polyvinyl pyridine graft copolymers. Vysokomol Soyed, 1973, A15: 2082-2085
39. Brandrup J, Immergut EH. Polymer Handbook. 2nd Ed. New York: Wiley Interscience, 1975
40. Sidorenko A, Minko S, Schenk-Meuser K, Duschner H, Stamm M. Switching of polymer brushes. Langmuir, 1999, 15: 8349-8355
41. Price EW, Harirchian-Saei S, Moffitt MG. Strands, networks, and continents from polystyrene dewetting at the air-water interface: Implications for amphiphilic block copolymer self-assembly. Langmuir, 2011, 27: 1364-1372