Catalytic oxidation of CO on platinum: Thermochemical approach

Journal of Thermal Analysis and Calorimetry

Volumn 111, Issue 1, 2013, Pages 145-154

  L'Vov, Boris V ^a   Galwey, Andrew K ^b  

^a PETER THE GREAT ST PETERSBURG POLYTECHNIC UNIVERSITY   (Russian Federation)

^b RHODES UNIVERSITY   (South Africa)

Author keywords

Catalytic CO oxidation on Pt; Congruent decomposition of PtO2; Enthalpy for CO oxidation on Pt catalyst; Limited Pt losses during CO oxidation; Mechanism of PtO2 restoration in CO oxidation; Thermochemistry of heterogeneous catalysis

Indexed keywords

ARRHENIUS; BULK OXIDES; CO OXIDATION; CONGRUENT DECOMPOSITION OF PTO2; E PARAMETERS; EFFECT OF CO; KINETIC FEATURES; LANGMUIRS; LITERATURE DATA; MARS-VAN KREVELEN; QUASI-EQUILIBRIUM; REACTION ENTHALPIES; THERMAL DECOMPOSITIONS OF SOLIDS;

CARBON DIOXIDE; CATALYST REGENERATION; CATALYTIC OXIDATION; DECOMPOSITION; ENTHALPY; KINETICS; OXIDATION; REACTION KINETICS; RESTORATION; THERMOCHEMISTRY;

PLATINUM;

EID: 84872485943     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-012-2241-6     Document Type: Article

References (53)

1. 2O. Trans Faraday Soc. 1922;17:621-54.
2. Langmuir I. Chemical reactions on surfaces. Trans Faraday Soc. 1922;17:607-20.
3. Taylor HS. A theory of the catalytic surface. Proc Roy Soc Ser A. 1925;108:105-11.
4. Hinshelwood CN. Kinetics of chemical change. Oxford: Clarendon Press; 1940.
5. Eley DD, Rideal EK. Parahydrogen conversion over tungsten. Nature. 1940;146:401-2.
6. IUPAC. Compendium of chemical terminology. 2nd Ed. Oxford: Blackwell; 1997.
7. Mars P, van Krevelen DW. Oxidations carried out by means of vanadium oxide catalysts. Spec Suppl to Chem Eng Sci. 1954;3:41-57.
8. Hendriksen BLM, Frenken JWM. CO-oxidation on Pt(110): scanning tunneling microscopy inside a high-pressure flow reactor. Phys Rev Lett. 2002;89: 046101-1-4.
9. L'vov BV, Ryabchuk GN. Studies of the mechanism of sample atomization in electrothermal atomic absorption spectrometry by analysis of absolute process rates: oxygen-containing compounds. Zh Analit Khim. 1981;36:2085-96. (in Russian).
10. L'vov BV, Fernandes GHA. Regularities in thermal dissociation of oxides in graphite furnace for atomic absorption analysis. Zh Analit Khim. 1984;39:221-31. (in Russian).
11. L'vov BV. The mechanism of the thermal decomposition of metal nitrates in graphite furnaces for atomic absorption analysis. Zh Anal Khim. 1990;45:2144-53. (in Russian).
12. L'vov BV. Mechanism of the thermal decomposition of metal nitrates from graphite furnace mass spectrometry studies. Mikrochim Acta (Wien). 1991;II:299-308.
13. L'vov BV, Novichikhin AV. Mechanism of thermal decomposition of anhydrous metal nitrates. Spectrochim Acta Part B. 1995;50:1427-48.
14. L'vov BV, Novichikhin AV. Mechanism of thermal decomposition of hydrated copper nitrate in vacuo. Spectrochim Acta Part B. 1995;50:1459-68.
15. L'vov BV. Thermal decomposition of solids and melts, new thermochemical approach to the mechanism, kinetics and methodology. Berlin: Springer; 2007.
16. L'vov BV. Fundamental restrictions of the second-law and Arrhenius plot methods used in the determination of reaction enthalpies in decomposition kinetics. J Therm Anal Calorim. 2008;92:639-42.
17. L'vov BV. Role of vapour oversaturation in the thermal decomposition of solids. J Therm Anal Calorim. 2009;96:321-30.
18. L'vov BV. Thermochemical approach to solid-state decomposition reactions against the background of traditional theories. J Therm Anal Calorim. 2009;96:487-93.
19. L'vov BV. Impact of the gaseous environment on the kinetics of solid-state decompositions. J Therm Anal Calorim. 2010;100:967-75.
20. L'vov BV. The mechanism of solid-state decompositions in a retrospective. J Therm Anal Calorim. 2010;101:1175-82.
21. L'vov BV, Galwey AK. The mechanism and kinetics of NiO reduction by hydrogen: thermochemical approach. J Therm Anal Calorim. doi: 10.1007/s10973-011-2000-0.
22. Shumbera RB, Kan HH, Weaver JF. Oxidation of Pt(100)-hex-R0.7 by gas-phase oxygen atoms. Surf Sci. 2007;601:235-46.
23. Harano Y. The detection of atomic oxygen in the decomposition of some metallic oxides. Nippon Kagaku Zasshi. 1960;82:152-5. (in Japanese).
24. Ackermann MD. Operando SXRD: a new view on catalysis. Leiden: PhD Thesis. 2007. A digital version of this thesis is available at http://www.physics. leidenuniv.nl/sections/cm/ip.
25. Samsonov GV, editor. Physical-chemical properties of oxides. Reference book. Moscow: Metallurgiya; 1978. (in Russian).
26. Glushko VP, editor. Thermodynamic constants of individual substances. Reference book vol II book 2. Moscow: Nauka; 1979. (in Russian).
27. Schlichting H. Boundary-layer theory. 7th ed. New York: McGraw-Hill; 1979.
28. Cant NW, Hicks PC, Lennon BS. Steady-state oxidation of carbon monoxide over supported noble metals with particular reference to platinum. J Catal. 1978;54:372-83.
29. Oh SH, Cavendish JC. Transients of monolithic catalytic converters: response to step changes in feed stream temperature as related to controlling automobile emissions. Ind Engng Chem Prod Res Dev. 1982;21:29-37.
30. Herskowitz M, Kenny CN. Kinetics and multiple steady states. Can J Chem Engng. 1983;61:194-9.
31. Yu Yao Y-F. The oxidation of CO and hydrocarbons over noble metal catalysts. J Catal. 1984;87:152-62.
32. 2O system. Ind Engng Chem Prod Res Dev. 1985;24:512-6.
33. Berlowitz PJ, Peden CHF, Goodman DW. Kinetics of CO Oxidation on single-crystal Pd, Pt and Ir. J Phys Chem B. 1988;92:5213-21.
34. Muraki H, Matunaga S-I, Shinjoh H, Wainwright MS, Trimm DL. The effect of steam and hydrogen in promoting the oxidation of carbon monoxide over platinum on alumina catalyst. J Chem Tech Biotechnol. 1991;52:415-24.
35. Hardacre C, Ormerod RM, Lambert RM. Low-temperature carbon monoxide oxidation on Pt (111). Dependence of apparent activation energy on reactant gas composition. Chem Phys Lett. 1993;206:171-4.
36. 3(0001): evidence for structure sensitivity. J Catal. 1993;140:418-23.
37. 3 catalysts for the oxidation of carbon monoxide by oxidation: II. Influence of the pretreatment step on the oxidation mechanism. J Catal. 1993;141:9-20.
38. 2. J Catal. 1997;171:358-73.
39. 3. J Catal. 1997;171:93-105.
40. Kim DH, Lim MS. Kinetics of selective CO oxidation in hydrogen-rich mixtures on Pt/alumina catalysts. Appl Catal A General. 2002;224:27-38.
41. Burnett DJ, Capitano AT, Gabelnick AM, Marsh AL, Fischer DA, Gland JL. In situ soft X-ray studies of CO oxidation on the Pt(111) surface. Surf Sci. 2004;564:29-37.
42. 3 catalysts. Appl Catal B Environ. 2004;54:183-91.
43. Kapoor S, Belapurkar AD, Mittal JP, Mukherjee T. Catalytic oxidation of carbon monoxide over radiolytically prepared Pt nanoparticles supported on glass. Mater Res Bull. 2005;40:1654-61.
44. 2 model catalysts: bridging the material gap. Appl Surf Sci. 2006;253:1310-22.
45. 3. J Catal. 2006;241:268-75.
46. 3 catalyst in a micro-structured recycle reactor. Catal Today. 2009;145:90-100.
47. Liu L, Zhou F, Wang L, Qi X, Shi F, Deng Y. Low-temperature CO oxidation over supported Pt, Pd catalysts: particular role of FeOx support for oxygen supply during reactions. J Catal. 2010;274:1-10.
48. 2 on natural zeolites. Energy Fuels. 2003;17:571-6.
49. Ackermann MD, Pedersen TM, Hendriksen BLM, Robach O, Bobaru SC, Popa I, Quiros C, Kim H, Hammer B, Ferrer S, Frenken JWM. Structure and reactivity of surface oxides on Pt(110) during catalytic CO oxidation. Phys Rev Lett. 2005;95:255505-1-4.
50. x supported on air-oxidized activated carbon. Turk J Chem. 2009;33:580-98.
51. Galwey AK, Gray P, Griffiths JF, Hasko SM. Surface retexturing of Pt wires during the catalytic oxidation of CO. Nature. 1985;313:668-71.
52. Scott K, Griffiths JF, Galwey AK. Restructuring of catalyst surfaces during oscillatory reactions. In: Gray P, Nicolis G, Baras F, et al., editors. Spatial inhomogeneities and transient behaviour in chemical kinetics. Manchester: Manchester University Press; 1990. p. 579-92.
53. Gao F, Wang Y, Cai Y, Goodman DW. CO oxidation on Pt-group metals from ultrahigh vacuum to near atmospheric pressures. 2. Palladium and platinum. J Phys Chem C. 2009;113:174-81.