Impact of the gaseous environment on the kinetics of solid-state decompositions

Journal of Thermal Analysis and Calorimetry

Volumn 100, Issue 3, 2010, Pages 967-974

  L'vov, Boris V ^a  

^a PETER THE GREAT ST PETERSBURG POLYTECHNIC UNIVERSITY   (Russian Federation)

Author keywords

Decomposition equations; Decomposition modes; Diffusion restriction; Impact of gaseous environment; Thermochemical kinetics; Topley Smith effect; Zawadzki Bretsznajder effect

Indexed keywords

ARRHENIUS; DECOMPOSITION KINETICS; DIFFERENT MODES; GASEOUS ENVIRONMENTS; KEYPOINTS; KINETIC EQUATIONS; KNUDSEN; LANGMUIR APPROACH; MAIN EFFECT; REACTION MECHANISM; SOLID-STATE DECOMPOSITION; THEORETICAL APPROACH; THERMOCHEMICAL KINETICS;

INTEGRAL EQUATIONS; PROBLEM SOLVING;

DECOMPOSITION;

EID: 77954886488     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-009-0628-9     Document Type: Conference Paper

References (44)

1. Galwey AK, Brown ME. Thermal decomposition of ionic solids. Amsterdam: Elsevier; 1999.
2. Topley B, Smith ML. Function of water vapor in the dissociation of a salt hydrate. Nature. 1931;128:302.
3. Furnas CC. The rate of calcination of limestone. Ind Eng Chem. 1931;23:534-8.
4. gas. Z Elektrochem. 1935;41:215-23.
5. Gilbert I G F, Kitchener JA. The dissociation pressure of cadmium oxide. J Chem Soc. 1956;3919-21.
6. Hyatt EP, Cutler IB, Wadsworth ME. Calcium carbonate decomposition in carbon dioxide atmosphere. J Am Ceram Soc. 1958;41:70-4.
7. Mauras H. Étude cinétique isobare de la dissociation des systèmes solides (III). Dissociation du carbonate de calcium. Bull Soc Chim Fr. 1960;260-7.
8. Pavlyuchenko MM, Prodan EA. Heterogeneous chemical reactions. Minsk: Nauka Tekhnika; 1961 (in Russian).
9. Hashimoto H. The thermal decomposition of calcium carbonates (II). The effect of carbon dioxide. J Chem Soc Jpn. 1961;64:1162-6.
10. 2-Druck. Z Elektrochem. 1962;66:697-702.
11. Ingraham TR, Marier P. Kinetics studies on the thermal decomposition of calcium carbonates. Can J Chem Eng. 1963;8:170-3.
12. Somorjai GA, Jepsen DW. Evaporation mechanism of CdS single crystals. J Chem Phys. 1964;41:1389-93.
13. 2. Vesti AN BSSR Ser Khim. 1971;5:21-6 (in Russian).
14. Koloberdin VI, Blinichev VN, Strel'tsov VV. The kinetics of limestone calcination. Int Chem Eng. 1975;15:101-4.
15. Searcy AW, Beruto D. Kinetics of endothermic decomposition reactions. 2. Effects of the solid and gaseous products. J Phys Chem. 1978;82:163-7.
16. 2 pressure on the rate of decomposition of calcite. J Phys Chem. 1981;85:3971-4.
17. L'vov BV, Fernandes G H A. Regularities in thermal dissociation of oxides in graphite furnace for atomic absorption analysis. Zh Analit Khim. 1984;39:221-31 (in Russian).
18. Maciejewski M, Baldyga J. The influence of the pressure of the gaseous product on the reversible thermal decomposition of solids. Thermochim Acta. 1985;92:105-8.
19. 2 on the kinetics and extent of calcination of limestone and dolomite particles in fluidized beds. Chem Eng Sci. 1987;42:2361-72.
20. Rao TR, Gunn DJ, Bowen JH. Kinetics of calcium carbonate decomposition. Chem Eng Res Des. 1989;67:38-47.
21. 4. J Therm Anal Calorim. 1994;41:1109-17.
22. Wang Y, Thompson WJ. The effect of steam and carbon dioxide on calcite decomposition using dynamic X-ray diffraction. Chem Eng Sci. 1995;50:1373-82.
23. 2 pressure on the thermal decomposition kinetics of calcium carbonate. Thermochim Acta. 1995;254:121-7.
24. L'vov BV. Mechanism of thermal decomposition of alkalineearth carbonates. Thermochim Acta. 1997;303:161-70.
25. L'vov BV. The physical approach to the interpretation of the kinetics and mechanisms of thermal decomposition of solids: the state of the art. Thermochim Acta. 2001;373:97-104.
26. 2 as a proof of their primary dissociative evaporation. Thermochim Acta. 2004;410:47-55.
27. 4 in different gases as a potential kinetics standard in thermal analysis. J Therm Anal Calorim. doi:10.1007/s10973-009-0143-z.
28. Prodan EA, Pavlyuchenko MM, Prodan SA. Regularities of topochemical reactions. Minsk: Nauka Tekhnika; 1976 (in Russian).
29. L'vov BV, Novichikhin AV, Dyakov AO. Computer simulation of the Topley-Smith effect. Thermochim Acta. 1998;315:169-79.
30. Stern KH. High temperature properties and thermal decomposition of inorganic salts with oxyanions. Boca Raton: CRC Press; 2000.
31. Hertz H. Über die Verdunstung der Flüssigkeiten, insbesondere des Quecksilbers, im luftleeren Raume. Ann Phys Chem. 1882;17:177-200.
32. Knudsen M. Die Molekularströming der Gase durch Öffnungen und die Effusion. Ann Phys. 1909;28:999-1016.
33. Langmuir I. The vapor pressure of metallic tungsten. Phys Rev. 1913;2:329-42.
34. Langmuir I. The evaporation of small spheres. Phys Rev. 1918;12:368-70.
35. Mills I. Quantities, units and symbols in physical chemistry. Oxford: Blackwell Science Publications; 1988.
36. L'vov BV. Role of vapor oversaturation in the thermal decomposition of solids. J Therm Anal Calorim. 2009;96:321-30.
37. L'vov BV. Thermal decomposition of solid and liquid substances. St. Petersburg: Polytech University Publisher; 2006.
38. L'vov BV. Thermal decomposition of solids and melts. New thermochemical approach to the mechanism, kinetics and methodology. Berlin: Springer; 2007.
39. L'vov BV. Mechanism and kinetics of thermal decomposition of carbonates. Thermochim Acta. 2002;386:1-16.
40. L'vov BV, Ugolkov VL. Kinetics and mechanism of dehydration of kaolinite, muscovite and talc analyzed thermogravimetrically by the third-law method. J Therm Anal Calorim. 2005;82:15-22.
41. L'vov BV. Fundamental restrictions of the second-law and Arrhenius plot methods used in the determination of reaction enthalpies in decomposition kinetics. J Therm Anal Calorim. 2008;92:639-42.
42. L'vov BV, Ugolkov VL. The self-heating effect in the process of KMnO4 decomposition in vacuum. J Therm Anal Calorim. 2008;94:453-60.
43. L'vov BV, Ugolkov VL. Use of potassium permanganate as a possible kinetic standard in thermal analysis. Russ J Appl Chem. 2007;80:1289-94.
44. L'vov BV. The mechanism of solid-state decompositions in a retrospective. J Therm Anal Calorim. doi:10.1007/s10973-009-0579-1.